Journal of Korean Society for Atmospheric Environment
/
v.3
no.2
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pp.46-52
/
1987
There are many factors such as airtighteness and high density of merchandises or passengers that contaminate indoor air in underground commercial floor. So it is very important to know air quality and quantity of contamination in underground market increasing in number lately. It was from these viewpoints that gaseous pollutants, dusts and mutagenicity of organic compounds extracted from dusts in an underground market were investigatd. Organic ompounds (tar) were extracted by Soxhlet extractor with benzene as a solvent. Mutagenicities of these extracts were evaluated by the preincubation method using Salmonella typhimurium TA 100 and TA 98 strains with and without S9mix. The results obtained were as follows: It seemed to be under the influence of outdoor air that the concentrations of $CO, CO_2, NO, NO_2$ and dusts were higher in winter than summer. The concentration of $CO_2$ was higher in indoor than outdoor, but the concentration of NOx was similar in both sampling areas. Metal contents in dusts attached to the ventilation ducts were as follows showing in order of high concentration : Fe (9000-22000ppm), Zn(1200-2300ppm) and Pb (280-590ppm). The contents of tar were 6-33% of dusts, and higher than those from dusts collected by high volume air sampler. The extracts from dusts attached to the inlet duct exhibited lower mutagenicity than those from dusts attached to the outlet duct. This finding seemed to suggest that mutagenic substances were in creasing in underground. There was no seasonal difference of mutagenicity toward TA 98. Toward TA 100 in the presence of S9mix, the mutagenicity was about 3 fold higher in winter than summer. The mutagenicities of tar extracted from dusts collected by high volume air sampler were different from those attached to the ventilation ducts. The former showed 2-3 fold higher mutagenicity than the latter toward TA 100. However no difference showed between the former and the latter toward TA 98 in the absence of S9mix, but the former was 4-5 fold higher than the latter in the presence of S9mix.
Vehicle occupant exposure to volatile organic compounds (VOCs) has been a subject of concern In recent years because of higher levels of VOCs Inside vehicles as compared to the surrounding ambient atmosphere and because of the toxicity of VOCs. The effectiveness of two commercial ACDs for the removal of selected VOCs in the interior of automobiles was evaluated on 115 commutes throegh urban (Taegu) commutes by two cars and 9 idles. The idling and commuting studios conducted under four different driving conditions showed that the ho commercial ACDs were not effective for the removal of VOCs in the interior of vehicles. The concentrations of all target VOCs except benzene were significantly higher (p<0.05) in the interior of older car than of newer cu. The mean levels of benzene and toluene measured in thins study were well excess of earlier other studios In the United States, besides Los Angeles with which was comparable. It was reported that the in-vehicle exposure to benzene and corresponding upper-bound cancel risk were about 8 times higher than those for outdoor environment, while they were about half of those from Indoor environment.
Journal of Korean Society of Environmental Engineers
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v.31
no.1
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pp.42-50
/
2009
Samples of subway dust were collected by the air filter system of 30 subway stations on Daegu subway line 1 in January 2008. Samples were sieved below 100 ${\mu}m$, and 14 elements were analyzed using ICP after acid extraction. Results obtained from the source assessment of trace elements using enrichment factor showed that Ca, Fe, K, Mg, Mn, Na, V were influenced by natural sources such as weathered rock and resuspended soil, while Cd, Cr, Cu, Ni, Pb and Zn were influenced by anthropogenic sources such as fuel combustion and waste incineration. Concentrations were remarkably higher in components from natural sources than in components from anthropogenic sources. Anthropogenic sources were significantly affected by indoor dusts than outdoor dusts. Results of pollution indices of heavy metals indicated that indoor dusts were more contaminated with heavy metal ions than outdoor dusts. The correlation analysis among trace elements indicated that components were much correlated in the order of natural sources-anthropogenic sources, anthropogenic sources-anthropogenic sources, natural sources-natural sources in both indoor and outdoor dusts. Trace element components of outdoor dusts were largely correlated than those of indoor dusts. In addition, indoor dusts were significantly affected by outdoor dusts rather than depth from the surface or the average daily number of subway passengers.
This study was carried out to evaluate student exposures to dust in classroom of middle schools. A total of four schools, such as two in an urban and two in a rural area, were selected for this study. In this study, airborne dust concentrations were measured during a period from July 8 to July 18, 1986. Additional measurements of dust concentrations were conducted from November 4 to 7, 1986 to compare the results by seasonal variation. The results of this study were as follows. 1. Respirable dust concentrations were measured by both filtration method (C mg/m$^3$) and Digital Aerosol Monitor (cpm) to calculate anexchange factor K. K- value was 0.159 as follows. $K=\frac{c}{cpm} = \frac{2.71}{17.09} = 0.159$ 2. In summer when windows were opened, the concentrations of airborne respirable dusts measured by filter sampling method were 0.54-1.37 mg/m$^3$ in the morning and 0.79-1.75 mg/m$^3$ in the afternoon. Thus, higher levels were indicated in the afternoon. Meanwhile, the concentrations of airborne respirable dusts measured in winter were approximately twice as high as those in summer. 3. The highest dust concentrations were determined in School D which is a coeducational school with classroom of concrete floor. Walking roads in School D were not paved and students did not wear indoor-shoes. Dust levels in School D were approximately twice as high as levels in School B. All of the measured dust levels in four schools exceeded Korean Standard for outdoor air, 0.3 mg/m$^3$ for 24 hours. Results by Digital Aerosol Monitor indicated that there was no significant difference in dust levels among grades. The concentration of airborne dusts in the classroom was 1.5-3.0 times higher than that in the hall way. The concentration of airborne dusts during recess was 1.3-1.6 times higher than that during class. In winter, the dust concentrations during clean-up exceeded the permissible exposure limit, 10 mg/m$^3$ (as total dusts), for occupational exposures. 4. The concentrations of total dusts measured in winter were 1.5-2.4 times higher than those of respirable dusts measured simultaneously.
Byeon, Sang-Hoon;Stock, Thomas H.;Morandi, Maria T.;Afshar, Masoud;Cross, Jay
Journal of Korean Society of Occupational and Environmental Hygiene
/
v.11
no.1
/
pp.34-41
/
2001
Passive samplers have been used for personal, indoor, and outdoor air monitoring of VOCs at ppb concentrations in community and office environments. The path length of modified passive sampler was shortened, so it was intended to increase an uptake rate. The performance of the modified 3M 3500 organic vapor monitor(OVM) as a tool for assessing exposures to toxic air pollutants in nonoccupational community environments was evaluated using combined controlled test atmospheres of six selected target volatile organic compounds(VOCs): benzene, methyl tert-butyl ether(MTBE), chloroform, 1,4-dichlorobenzene, tetrachloroethylene, and toluene. The experiments were conducted by exposing the dosimeters to concentrations of $50{\sim}100{\mu}g/m^3$ on six face velocity(0.00, 0.02, 0.06, 0.12, 0.20, 0.30 m/sec) for 24 hours. If the uptake rate was increased, that means that we could use the passive sampler more effectively. The uptake rates were increased linearly according to reduce the path length. Although the diffusion path length was shortened, the change of uptake rate was within ${\pm}25%$ of theoretical value, indicating that the modified passive sampler(TM) can be effectively used over the range of concentrations and environmental conditions tested with a 24-h sampling period if the face velocities were over 0.12 m/s for 6 components of VOCs. But when the face velocities were less than 0.12 m/s, uptake rates were reduced more than expected values. So, the passive sampler with the shortened path length should be used at indoor or outdoor environment where the face velocity should be over about 0.10 m/s. If the path length was shortened more, the uptake rate was more effected by starvation.
Roh, Young-Man;Lee, Cheol Min;Kim, Yoon Shin;Kim, Seok Won;Kim, Chi-Nyon;Kim, Hyun-Wook;Cho, Kee Hong;Choi, Ho Chun;Kim, Jung Man
Journal of Korean Society of Occupational and Environmental Hygiene
/
v.16
no.1
/
pp.54-67
/
2006
This study was performed to deduct the extension possibility of the standards establishment for $NO_2$, $O_3$, Asbestos, Radon, total volatile organic compounds (TVOC) excluded in the indoor air part of Industrial Safety Acts in Korea. The air pollutants were sampled for 30 office buildings from August to September, 2005 in the metropolitan area. The airborne concentrations of $NO_2$, $O_3$, Radon and TVOC were 0.0092 ppm, 0.0035 ppm, 0.57 pCi/L and $423{\mu}g/m^3$, respectively. The management plan and reduction methods is required in the aspect of indoor air quality(IAQ) because the emission sources of those also exist in indoor as well as outdoor even though those were not exceeded the standards of the Ministry of Environment in Korea. The standard for TVOC in the new and remodeling office has to be established based on the risk assessment when hazard index exceeded "1" in the worst case scenario. In the state of art, the management of each volatile organic compounds has a difficulty due to not enough data for toxicological reference. Therefore, it is suggested that first of all, the standard for TVOC be established and then expanded to each materials for decision-making of improvement of IAQ in office.
Objectives: The purpose of this study is to investigate the mass concentration of nanoparticles and understand the characteristics of elements of heavy metal concentrations within nanoparticles in the air using Micro-Orifice Uniform Deposit Impactor Model-110 (MOUDI-110), based on indoor and outdoor air. Methods: This Study sampled nanoparticles using MOUDI-110 indoors (office) and outdoors at S University in Asan, Korea in order to reveal the concentration of nanoparticles in the air. Sampling continued for nine months (10 times indoors and 14 times outdoors) from March to November 2010. Mass concentrations of nanoparticle and concentrations of heavy metals (Al, Mn, Zn, Ni, Cu, Cr, Pb) were analyzed. Results: Indoors, geometric mean concentration of nanoparticles ranged in size from 0.056 ${\mu}m$ to 0.10 ${\mu}m$ and those of 0.056 ${\mu}m$ or less recorded 0.929 ${\mu}g/m^3$ and 1.002 ${\mu}g/m^3$, respectively. On the other hand, the levels were lower outdoors with 0.819 ${\mu}g/m^3$ and 0.597 ${\mu}g/m^3$. Mann-Whitney U tests showed that the difference between the indoors and the outdoors was statistically meaningful in terms of particles of 0.056 ${\mu}m$ or less (p<0.05) in size. These results are possibly influenced by the use of printers and duplicators as the factor that increased the concentration of nanoparticles. In seasonal concentration distribution, the level was higher during the summer compared to in the autumn. Those of 0.056 ${\mu}m$ or less in size presented a statistically meaningful difference during the summer (p<0.05). These results may be influenced by photochemical event as the factor that makes the levels high. Regarding zinc, among the other heavy metals, the fine particles ranged in size from 0.056 ${\mu}m$ to 0.10 ${\mu}m$ and those of 0.056 ${\mu}m$ or less recorded 1.699 $ng/m^3$ and 1.189 $ng/m^3$ in the outdoors. In the indoors, the levels were lower, with 0.745 $ng/m^3$ and 0.617 $ng/m^3$. Cr and Ni at the size of 0.056 ${\mu}m$ or less, both of which have been known to pose severe health effects, recorded higher concentrations indoors with 0.736 $ng/m^3$ and 0.177 $ng/m^3$, compared to 0.444 $ng/m^3$ and 0.091 $ng/m^3$ outdoors. By season, Zn, Ni, Cu and Pb posted a high level of indoor concentration during the fall. As for Cr, the level of concentration indoors was higher than outdoors both during the summer and the autumn. Conclusion: This study indicates the result of an examination of nano-sized particles and heavy metal concentrations. It will provide useful data for the determination of basic nanoparticle standards in the future.
Lee, Hye-Won;Lim, Hui Been;Lee, Kwi-Bok;Park, So Yeon;Jeon, Jeong In;Lee, Cheol Min
Journal of Environmental Science International
/
v.29
no.6
/
pp.673-682
/
2020
This study investigates the concentration distribution of aldehydes and volatile organic compounds (VOCs) in the archive of the National Library in Korea and evaluates the health risks to workers from hazardous chemicals. Acetaldehyde had the highest concentration among the nine species of aldehydes present in the archive and the concentration of toluene was the highest among the six species of VOCs. Most of the detected substances showed that their indoor concentrations were higher than the outdoor ones, suggesting the possibility of indoor sources of aldehydes and VOCs. The evaluation of health risks for workers based on these measurement results showed that not all substances were hazardous to the human body. However, considering the possibility of the presence of indoor sources and the potential limits of our study owing its short period, it is necessary to conduct long-term studies on the concentration distribution of indoor pollutants in the archive environment.
Park, Hae-Dong;Park, Hyun-Hee;Shin, Jung-Ah;Kim, Tae-Ho
Journal of Environmental Health Sciences
/
v.36
no.5
/
pp.402-410
/
2010
The objectives of this study were to evaluate the air quality surrounding an indoor swimming pool, to estimate the cancer risk based on the airborne exposure to trihalomethanes (THMs), and to examine the ventilation efficiency by Computational Fluid Dynamics (CFD). Chlorine and THMs were measured poolside, and in the staff room and reception area. The indoor swimming pool was modeled using the Airpak program, with ventilation drawings and actual survey data. Temperature, flow and mean age of the air were analyzed. Levels of chlorine poolside, and in the staff room, and reception area were $203\;{\mu}g/m^3$, $5\;{\mu}g/m^3$, and $10\;{\mu}g/m^3$, respectively. Chloroform was the dominant THM in all sampling sites and mean concentrations were $16.30\;{\mu}g/m^3$, $0.51\;{\mu}g/m^3$, and $0.06\;{\mu}g/m^3$ poolside, in the staff room and reception area, respectively. Bromodichloromethane and Dibromochloromethane levels were respectively estimated as $10.3\;{\mu}g/m^3$ and $1.7\;{\mu}g/m^3$ poolside, $1.3\;{\mu}g/m^3$ and $0.1\;{\mu}g/m^3$ in the staff room, and were not detected in the reception area. The cancer risks from inhalation exposure to THMs were estimated between $3.37{\times}10^{-7}$ and $1.84{\times}10^{-5}$. A short circulation phenomenon was observed from the supply air vents to the exhaust air vents located in the ceiling. A high temperature layer was formed within one meter of the ceiling, and a low temperature layer was formed under this layer due to the low velocity and high temperature of the supply air, and the improper locations of the supply air vents and exhaust air vents. The stagnation was evident at the above adult pool and the mean age of the air was 22 minutes. Disinfection by-products in the indoor swimming pool were present in higher concentrations than in the outdoor air. In order to increase the removal of pollutants, adjustment was required of the supply air volume and the supply/exhaust position.
Proceedings of the Korean Environmental Health Society Conference
/
2002.04a
/
pp.1.1-2
/
2002
Ultimate objective of industrial hygiene is the prevention of health impairment that may result from exposure to chemicals at workplaces. This implies the definition of permissible levels of exposure, that is, levels that according to the present status of knowledge are estimated to cause no adverse health effects during the lifetime of the workers, and the regular assessment of the possible health risk associated with exposure by comparing the current or the integrated exposure with the permissible exposure limits. Workers in solvent thinner-using occupation environment might be highly exposed to VOCs(volatile organic compounds) because solvent thinner has been used extensively such as painting, spraying, degreasing, coating and so on in Korea. The purpose of this study was to recognize, evaluate and propose the alternative control the VOCs from solvent thinner-using workplace.
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