• 한국전기전자재료학회논문지
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• 제15권8호
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• pp.708-712
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• 2002

The crystallization of amorphous $\alpha$-Fe$_2$O$_3$/$\alpha$-AI$_2$O$_3$(0001) thin films during thermal annealing in air has been studied using real-time synchrotron x-ray scattering. The well aligned (0.02$^{\circ}$/ FWHM) $\alpha$-Fe$_2$O$_3$and Fe$_3$O$_4$interfacial crystallites (50- -thick) coexist on the $\alpha$-AI$_2$O$_3$(0001) in the sputter-grown amorphous films at room temperature. The amorphous precursor is crystallized to the epitaxial $\alpha$-Fe$_2$O$_3$grains in three steps with annealing temperature; i ) the growth of the well aligned $\alpha$-Fe$_2$O$_3$interfacial crystallites, together with the transformation of the Fe$_3$O$_4$crystallites to the $\alpha$-Fe$_2$O$_3$ crystallites, ii ) the growth of the less aligned (3.08$^{\circ}$ FWHM)$\alpha$-Fe$_2$O$_3$grains on the well aligned grains (＞40$0^{\circ}C$), and iii) the nucleation of the other less aligned (1.39$^{\circ}$ FWHM) $\alpha$-Fe$_2$O$_3$grains directly on the $\alpha$-AI$_2$O$_3$substrate (＞$600^{\circ}C$). The effective thickness thinner than 230 may be very useful for enhancing the epitaxial quality of $\alpha$-Fe$_2$O$_3$/AI$_2$O$_3$(0001) thin films.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.543-544
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• 2006

The effect of the additives, $Y_2O_3$ and MgO, on the sintering and properties of $Al_2O_3-TiC$ composites was investigated. It is known that MgO is used as additive for improving densification and $Y_2O_3$ is applied as sintering aid. In this study, the amounts of TiC were varied in the range of 30-47 wt%. The 0.5 wt% MgO and also varied amounts of $Y_2O_3$ from 0.3 to 1 wt% were added into the composites. The sintering of $Al_2O_3-TiC$ composites was performed in a graphite-heating element furnace at different sintering temperature, 1700 and $1900\;^{\circ}C$, for 2 hr under an argon atmosphere. The results demonstrated that the properties of the composites sintered at $1700\;^{\circ}C$ were much better than those sintered at $1900\;^{\circ}C$. The comparisons on physical properties, mechanical properties and microstructure of composites with and without additives were reported. Comparing with other samples, $Al_2O_3-30wt%TiC$ composites with 0.5wt% MgO and $1\;wt%Y_2O_3$ exhibited the highest density of approximately 98% of theoretical and flexural strength of 302 MPa.

• 공업화학
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• 제8권3호
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• pp.382-388
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• 1997

본 연구는 펄스 반응기 및 고정층 연속반응기를 사용하여 ${\gamma}$-알루미나에 담지된 니켈촉매상에서 이산화탄소에 의한 프로판의 개질반응 특성을 고찰한 것이다 Ni/${\gamma}$-$A1_2O_3$촉매가 NiO/${\gamma}$-$A1_2O_3$촉매보다 $CO_2$의 해리능력과 프로판의 개질 능력이 우수한 것으로 나타났다. 프로판과 $CO_2$의 혼합물에 산소를 추가한 결과 프로판의 전환율이 증가하였고 표면의 탄소침적도 감소함을 알 수 있었다. Ni/${\gamma}$-$A1_2O_3$와 $Ga_2O_3$의 기계적 혼합 촉매는 Ni/${\gamma}$-$A1_2O_3$자체보다 촉매의 활성이 오래 유지되었고 두 상의 협동에 의한 상승효과(synergistic effect)가 관찰되었다.

• 자원환경지질
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• 제32권3호
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• pp.247-260
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• 1999

Geochermical characteristics of the fluvial sediments deprnding on particle size distribution size were investigated in the respect of majir, minor and rare eath element chemisitry. Ratios of $Al_{2}O_{3}/Na_{2}O$ and $K_{2}O/Na_{2}O$ of the sediments show the homogeneous valus, and partly positive correlation with $SiO_{2}/Al_{2}O_{3}$, respecively. Characteristics of minor element ratios (V/Ni, Cr/V, Ni/Co and Zr/Hf)are within the lower and narrow range. Thesesuggested that sediment sources may be acidic to intermediate granitic rock, and may be explained by simple weathering and sedimentation. With increasing SiO2 contents, concentrations of $Al_{2}O_{3}$, $Fe_{2}O_{3}$, CaO and MgO decreased, but those of $K_{2}O$ and $Na_{2}O$ increased, Concentrations of Ba, Be, Cs, Cu, Li, Ni, Sr, V and Zr show comparatively normal negative and some positive trends. Compared with the mean composition of granite, concentrations of $Al_{2}O_{3}$, $Fe_{2}O_{3}$, MnO, CaO and MgO in the sediments of the study area were highly enriced. Among some minor and rare earth elements, concentrations of As, Cd, Cu, and V were enriched, but those of Be, Ce, Rb, Sc, Sr and Zn were depleted when compared with average composition of granite. By decreasing of particle size fractions, SiO2, Rb and Sr conterts decreased, but concentrations of $Al_{2}O_{3}$, $Fe_{2}O_{3}$, CaO, MgO, $TiO_{2}$, MgO, $P_{2}O_{5}$, Be, Cu, Hf, Pb, V and Zr increased. From the correlations between particle size fractions and element concenreations, some elements of $Fe_{2}O_{3}$, CaO, MgO, $P_{2}O_{5}$, Cu, Ni, Zn and Zr showed typical trends in the secondary contramination sediments. These trends are typically shown under 100 mesh fractions. It indicates that the fraction of minus 100 mesh is the optimum size fraction for geochemical and environmental survey.

• 한국세라믹학회지
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• 제44권3호
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• pp.137-141
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• 2007

$La_{2}O_{3}-TiO_{2}-SiO_{2}$ glass, a type that could not obtained so far by the conventional melting method, was prepared successfully using a sol gel process. Glass derived with the sol-gel process has compositions of $5La_{2}O_{3}-5TiO_{2}-90SiO_{2},\;5La_{2}O_{3}-10TiO_{2}-85SiO_{2}$, and $5La_{2}O_{3}-20TiO_{2}75SiO_{2}$. The UV-visible absorption edge of all glass compositions was below 400 nm. The measured density is in the range of 2.55-2.89, and was nearly identical to the calculated density and the refractive index of the glasses derived from the sol-gel ranges from 1.545 to 1.645. The molar additive coefficient of $TiO_{2}$ measured in this ternary system is lower than the calculated value, while the value of $La_{2}O_{3}$ is higher.

• 대한화학회지
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• 제38권4호
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• pp.309-318
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• 1994

La$_2O_3$-변형 BaTi$O_3$의 안정한 결함구조와 단일상 영역을 X-선 회절분석기와 주사전자현미경을 사용하여 연구하였다. La$_2O_3$-변형 BaTi$O_3$의 안정한 결함구조는 La$^{3+}$ 이온이 격자구조내의 Ba$^{3+}$ 이온을 치환하고 Ti빈자리가 전하 불균형을 보상하기 위한 결함으로 생성된 [($Ba^x_{Ba})_{1-2x}(La{\cdot}_{Ba})_{2x}][Ti^x_{Ti})_{1-x/2}(V""_{Ti})_{x/2}]O_3$이다. 안정한 결함구조가 형성되도록 BaTi$O_3$에 La$_2O_3{\cdot}3/2TiO_3$를 혼입할 때 단위격자는 약 3 mol%가 혼입될 때부터 정방정에서 입방정으로 변하였고, 고용한계는 약 14 mol%이었다. La2$O_3{\cdot}3/2TiO_2$를 고용한계 이상으로 혼입할 때는 이차상으로 La_4Ba_2Ti_5O){18}$가 생성되었다. La$_2O_3$-변형 BaTi$O_3$ 조성에서 BaO가 과량 존재하면 소결성이 나쁘지만, Ti$O_2$가 과량으로 존재하면 액상소결에 의하여 소결성이 좋아짐을 확인할 수 있다.

• Bulletin of the Korean Chemical Society
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• 제18권8호
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• pp.831-840
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• 1997

Core/shell structured composite metal oxides of Fe2O3/MgO were prepared by thermal decomposition of Fe(acac)3 adsorbed on the surface of MgO cores. The morphology of the composites conformed to that of the MgO used as the cores. Broad powder X-ray diffraction peaks shifted toward larger d, large BET surface area (∼350 m2/g), and the size of crystalline domains in nano range (4 nm), all corroborate to the nanocrystallinity of the Fe2O3/MgO composite which was prepared by using nanocrystalline MgO as the core. By use of microcrystalline MgO as the core, microcrystalline Fe2O3/MgO composite was prepared, and it had small BET surface area of less than 35 m2/g. AFM measurements on nanocrystalline Fe2O3/MgO showed a collection of spherical aggregates (∼80 nm dia) with a very rough surface. On the contrary, microcrystalline Fe2O3/MgO was a collection of plate-like flat crystallites with a smooth surface. The nitrogen adsorption-desorption behavior indicated that microcrystalline Fe2O3/MgO was nonporous, whereas nanocrystalline Fe2O3/MgO was mesoporous. Bimodal distribution of the pore size became unimodal as the layer of Fe2O3 was applied to nanocrystalline MgO. The macropores in a wide distribution which the nanocrystalline MgO had were absent in the nanocrystalline Fe2O3/MgO. The decomposition of CCl4 was largily enhanced by the overlayer of Fe2O3 on nanocrystalline MgO making the reaction between nanocrystalline Fe2O3/MgO and CCl4 be nearly stoichiometric. The reaction products were environmentally benign MgCl2 and CO2. Such an enhancement was not attainable with the microcrystalline samples. Even for the nanocrystalline MgO, the enhancement was not attained, if not with the Fe2O3 layer. Without the layer of Fe2O3, it was observed that the nanocrystalline domain of the MgO transformed into microcrystalline one as the decomposition of CCl4 proceeded on its surface. It appeared that the layer of Fe2O3 on the particles of nanocrystalline Fe2O3/MgO blocked the transformation of the nanocrystalline domain into microcrystalline one. Therefore, in order to attain stoichiometric reaction between CCl4 and Fe2O3/MgO core/shell structured composite metal oxide, the morphology of the core MgO has to be nanocrystalline, and also the nanocrystalline domains has to be sustained until the core was exhausted into MgCl2.

• 방사성폐기물학회지
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• 제15권1호
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• pp.83-90
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• 2017

사용후핵연료 파이로프로세싱에서는 방사성 희토류 염화물($RECl_3$)을 함유한 LiCl-KCl 공융염폐기물이 발생되며, 핫셀시설에서 운영을 목적으로 단순한 형태의 공융염폐기물 처리공정을 개발하는 것이 필요하다. 본 연구에서는, LiCl-KCl 공융염폐기물 내 희토류 핵종 분리/고화공정의 단순화를 목적으로 $Li_2O-Al_2O_3-SiO_2-B_2O_3$계의 무기합성매질을 이용하여 LiCl-KCl 공융염 내 희토류 핵종(Nd)을 분리한 후 분리생성물을 바로 고화하는 시험을 실시하였다. 공융염 내 희토류 염화물($NdCl_3$) 대비 0.67의 무게비에 해당하는 무기합성매질의 양으로도 Nd 핵종을 98wt% 이상 분리할 수 있었고, 이 때 얻은 희토류 핵종 포집생성물은 약 50wt% 수준의 희토류 산화물 함량을 보유하고 있었으며, 이 포집생성물을 화학적 내구성이 우수한 단일상의 균질한 유리고화체로 제조할 수 있었다. 이 결과들은 LiCl-KCl 공융염폐기물 내 희토류 핵종의 분리/고화공정을 단순화하기 위한 방안수립에 활용될 수 있을 것이다.

• 한국세라믹학회지
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• 제36권12호
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• pp.1350-1355
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• 1999

Sintering characteristics and dielectric properties of low temperature sinterable Glass/Ceramic dielectric materials were investigated. The dielectric materials which were developed for microwave frequency applications consist of SiO2-TiO2-Bi2O3-RO system(RO:BaO-CaO-SrO) crystallizable glass and Al2O3 as a ceramic filler. Sintering experiments showed that no more densification occurred above 80$0^{\circ}C$ and bulk density and shrinkage depended on Al2O3 content only. Results of dielectric measurements showed that $\varepsilon$r Q$\times$f and $\tau$f of the material containing 30wt% Al2O3 were 17.3, 600 and +23 ppm respectively. Those values for 45 and 60wt% Al2O3 samples were 11.6, 1400, +0.7 ppm and 7.2, 2000, -8.5 ppm, repectively. The results clearly showed that the Glas/Ceramic materials of present experiment decreased in $\varepsilon$r and increased in $\times$f value and changed from positive to negative value in $\tau$f value with the increasement of Al2O3 content.

• 한국세라믹학회지
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• 제30권10호
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• pp.811-818
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• 1993

Al2O3/ZrO2-Spinel composites were prepared by infiltrating magnesium sulfate solution into the porous preform made from Al2O3-20wt% ZrO2 composite powders derived through an emulsion route. The microstructure and composition of the modified composites could be controlled by manipulating the presingtering temperature of the preform, infiltration time, and so on. It was found that spinel phases were concentrated near the surface than in the interior of the Al2O3/ZrO2-Spinel composites infiltrated for 6hrs, while spinel phases were uniformly distributed in the comosites infiltrated for 2 days. The relative density and fracture toughness of the composite infiltrated for 6 hrs were 98.6% and 7.2MN/m3/2, respectively.