• 제목/요약/키워드: In-situ precipitation

검색결과 72건 처리시간 0.031초

대청호에서 장기간 수질변동 및 인위적 Enclosure 영양염 투여실험에 따른 제한 영양염류 평가 (Long-term Water Quality Fluctuations in Daechung Reservoir and the Limiting Nutrient Evaluations Using In Situ Enclosure Nutrient Enrichment Bioassays (NEBs))

  • 박향미;안광국
    • 한국물환경학회지
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    • 제28권4호
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    • pp.551-560
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    • 2012
  • The objectives of this study were to elucidate spatio-temporal heterogeneity of water chemistry and develop empirical models using trophic variables in Daechung Reservoir during 2005-2010 along with in situ tests of nutrient enrichment bioassays (NEB). The relations of water quality parameters in regard to precipitation showed that seasonal and interannual fluctuations of biological oxygen demand (BOD), total nitrogen (TN) and pH were minor, whereas conductivity, suspended solids (SS), and total phosphorus (TP) were largely varied in response to the magnitude of rainfall. The CHL maxima occurred immediately after the spate of TP during the high flow, indicating that phytoplankton growth was directly controlled by phosphorus. Empirical linear models of CHL-TP indicated that the variation of CHL in premonsoon was accounted 60% ($R^2$ = 0.60, p < 0.05, n = 54) by TP. In the mean time, empirical models of annual CHL-TN showed that the variation of CHL was weakly accounted ($R^2$ = 0.16, p < 0.001) by TN and more strongly ($R^2$ = 0.44, p < 0.001) by TP. Thus, the variation of CHL was more explained by the variation of TP than TN. In situ tests of Nutrient Enrichment Bioassays (NEBs) showed that the growth of CHL was greater in the P-treatments (as $PO_4-P$) than the control and N-treatment (as $NO_3-P$). Overall, our results suggest that phosphorus was aprimary limiting nutrient controlling the seasonal phytoplankton growth, based on the in situ experiments of NEBs.

풍화토 사면에서 강우로 인한 간극수압 변화에 대한 실험연구 (In-situ Monitoring of Matric Suctions in a Weathered Soil Slope)

  • 이인모;조우성;김영욱;성상규
    • 한국지반공학회논문집
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    • 제19권1호
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    • pp.41-49
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    • 2003
  • 우리나라에서 흔히 볼 수 있는 화강풍화토 사면에서 강우침투로 인한 사면파괴는 통상 지하수위 위쪽의 얕은 깊이에서 발생한다. 지하수위 위쪽 지반의 간극수압은 대기압에 대하여 음의 값을 갖는다. 이러한 모관흡수력의 존재와 크기는 사면의 안정성에 크게 기여하는 것으로 밝혀졌다. 따라서, 계절적 강우에 의한 풍화토 사면의 얕은 파괴기구(failure mechanism)를 규명하기 위해서는 비포화대에서의 모관흡수력 분포를 예측하는 것이 필수적이다. 이 연구에서는 2001년 6월부터 8월까지 화강풍화토 사면에서 모관흡수력 및 체적함수비를 현장 모니터링 하였으며, 대상지반에 대한 투수해석을 수행하였다. 현장 모니터링 결과, 기후조건의 영향력은 깊이에 따라 감소하는 경향을 보였으며 강우침투에 의한 지반내 모관흡수력의 감소는 강우량 및 강우지속시간 뿐만 아니라 강우직전의 모관흡수력 분포에도 큰 영향을 받고 있는 것으로 나타났다. 모니터링된 모관흡수력과 체적함수비를 이용하여 현장 흙-수분특성을 얻을 수 있었는데 습윤경로(wetting path)에 가까운 분포를 보였다.

침전법과 착체중합법을 이용한 Ga2O3 분말의 합성 및 결정구조 분석 (Synthesis and Crystal Structure Characterization of Ga2O3 Powder by Precipitation and Polymerized Complex Methods)

  • 정종열;김상훈;강은태;한규성;김진호;황광택;조우석
    • 한국세라믹학회지
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    • 제51권3호
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    • pp.156-161
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    • 2014
  • Gallium oxide ($Ga_2O_3$) powders were synthesized using a precipitation method and a polymerized complex method. TG-DSC, SEM, and XRD were performed to investigate the phase and morphology of the $Ga_2O_3$. In situ high-temperature XRD analysis revealed the crystal structure of $Ga_2O_3$ at different temperatures. The $Ga_2O_3$ obtained using the precipitation method and polymerized complex method were generally spherical-shaped particles and their average particle size was approximately 80 nm and $1{\mu}m$, respectively. The crystal structure of the $Ga_2O_3$ prepared by the precipitation method was changed from rhombohedral to monoclinic at $700^{\circ}C$, while monoclinic $Ga_2O_3$ was obtained directly from the precursor by the polymerized complex method.

열분석법에 의한 Mg-8.5Li-4.5Al합금의 시효거동 연구 (A Study on the Aging Behavior of a Mg-8.5Li-4.5Al alloy by Differential Scanning Calorimetry)

  • 김영우;황영하;박태원;김도향;홍준표
    • 열처리공학회지
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    • 제10권4호
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    • pp.255-265
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    • 1997
  • Precipitation and strengthening mechanisms in squeeze cast Mg-8.5wt%Li-4.5wt%Al have been investigated by differential scanning calorimetry(DSC), scanning electron microscopy(SEM), in-situ and ex-situ X-ray diffraction analysis and hardness measurement. Special emphasis was placed on the investigation of the precipitation behavior by the DSC technique. Microstructural and calorimetric analysis showed that ${\theta}$ and ${\delta}$ precipitates in the b.c.c. ${\beta}$ phase matrix, forming two exothermic peaks at the temperature ranges of $130^{\circ}C{\sim}180^{\circ}C$ and $236^{\circ}C{\sim}280^{\circ}C$. ${\theta}$ and ${\delta}$ dissolve into the matrix forming an endothermic peak at the temperature range of $280^{\circ}C{\sim}352^{\circ}C$. The as-cast microstructure consists of ${\alpha}$, ${\beta}$ and ${\delta}$. Peak strength was obtained after aging for 1 hour at $50^{\circ}C$. The aging time required for the peak strength decreased as the aging temperature increases. The hardness decrease during overaging was due to the coarsening of ${\theta}$ precipitates. Microhardness measurement showed that variation of the hardness of ${\beta}$ matrix was more pronounced than that of the ${\alpha}$ phase, indicating that the ${\beta}$ phase is more responsible for the strengthening of the Mg-8.5wt%Li-4.5wt%Al alloy.

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MODIS 광학 영상 자료를 통한 한반도 GPM 강우 자료의 상세화 기법 (Downscaling GPM Precipitation Using Finer-scale MODIS Based Optical Image in Korean Peninsula)

  • 오승철;정재환;이슬찬;최민하
    • 대한원격탐사학회지
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    • 제36권5_1호
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    • pp.749-762
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    • 2020
  • 강우는 유출, 증발산 등 여러 수문 현상들과 밀접한 연관이 있으며, 직관적인 측정이 가능하기 때문에 다양한 현상을 해석하고 분석하는데 빈번하게 활용되어 왔다. 한반도에서는 강우 관측소의 운영과 레이더를 활용한 측정이 주를 이루고 있으며, 정확하고 정밀한 측정이 가능한 연구수준을 보유하고 있다. 하지만 이는 인프라가 구축되지 않은 미계측 유역에서의 강우를 측정하기에는 적합하지 않으므로, 위성을 활용한 정확한 강우 분석에 대한 연구가 요구되고 있다. 위성 기반 강우자료는 10 km, 25 km 정도의 낮은 공간해상도를 갖고 있으며, 정확도에 있어서 지점 자료에 비해 신뢰도가 낮다는 인식이 있어 활용범위가 제한적이다. 본 연구에서는 이러한 공간 해상도의 한계를 극복하고 지점 자료와의 정확도를 높이고자, 10 km의 공간해상도를 갖는 전지구관측 위성(GPM) 기반 강우 자료를 1 km까지 상세화하였다. 특히, 미계측 유역 등 지점 자료가 부족한 곳에서의 위성 영상 활용도를 제고하기 위해, 상세화 과정에서 지점 자료를 사용하지 않고 MODIS 기반의 구름 인자를 활용하였다. 상세화 된 강우 자료는 빌딩 등 복잡한 환경적 특성을 지닌 서울 지역에서 지점 강우 자료와 검증함으로써, 위성 기반 고해상도 강우자료의 활용 가능성을 평가하였다. 상세화가 적용된 강우 자료의 상관성은 봄에는 0.08만큼 감소하였고, 여름에는 같은 값을 가지며, 가을에는 0.01만큼 감소하였고, 겨울에는 0,04만큼 증가하였다. 지점 자료를 사용하지 않고 위성기반 강우 자료를 상세화 하는 기술은 추후 인프라의 구축이 충분하지 않은 해외 지역이나 지점 관측에 한계가 있는 미계측 유역의 강우를 분석하는 데 유용하게 사용될 수 있을 것으로 판단된다.

in situ법(法)에 의한 Cu-Fe계(系) 다섬유상(多纖維狀) 복합재료제조(複合材料製造)에 관한 연구(硏究) (A Study on Cu-Fe Multifilamentary Composites Produced by in situ Process)

  • 서수정;박현순
    • 열처리공학회지
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    • 제4권2호
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    • pp.9-18
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    • 1991
  • Among the many maunfactured processes of producing multi filamentary composites, in situ process is widely used owing tv its simplicity and easyness of mass production. In this study, the mechanical and electromagnetic properties of Cu-Fe composite materials was investigated. The tensile strength of the Cu-Fe wires increased as the Fe content and reduction ratio were increased. The Cu-30 wt%Fe composites had the best properties in terms of figure merits compared to the other Cu-Fe composites made in this study or the commercially manufactured 6/1 ACSR cables of Cu cable. The coercivity was decreased by increasing Fe content, but the squareness was increased greatly. As increasing reduction ratio, the coercivity and squareness increased up to the maximum points, and then decreased. For example, the maximum values were obtained at $0.09mm{\phi}$ for Cu-30 wt%Fe composites and at $0.066mm{\phi}$ for Cu-45 wt%Fe composites. The magnetic property of Cu-Fe wires produced by precipitation treatment was higher than that of Cu-Fe wires produced by thermomechanical treatment. By annealing Cu-Fe wires after drawing process, the coercivity, remanence and squareness were improved.

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TOWARDS A SAFER ENVIRONMENT: 3) PHOSPHATIC CLAYS AS SOLUTION FOR REMOVING PB2+ FROM WASTEWATER

  • ABDALLAH SAMY MOHAMED
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2005년도 학술발표회(2)
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    • pp.1179-1180
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    • 2005
  • To immobilize the pollutants from wastewater in situ, two phosphatic clays collected from different areas in Egypt (eastern and western Sebaia, Aswan-Isna, Upper Egypt) used to remove contaminant ions from industrial wastewater. Obtained results confirmed the strong relationship between phosphatic clay and Pb elimination from wastewater. The sensitivity classification of phosphatic clay toward ions retained as described in three categories: highly sensitive to retain Pb , Al and Cr ; moderately sensitive for Mn; and weakly sensitive for Band Zn. Data suggested that large fraction of Pb removed by phosphatic clays stayed intact under a wide variation in extracting solution pH (3-11). In situ immobilization is considered a promising technique that has the potential to remove contaminant ions from wastewater. Two important factors need to be considered when applying this technique: The first, is the clay must be effective and selective under different composition of wastewater. The second, is the immobilized ions should be stable and non-leacheable under varying water conditions. Phosphatic clays with $Pb^{2+}$ were suitable to achieve these two factors. Possible mechanism for removal $Pb^{2+}$ by phosphatic clays is the formation of fluoropyromorphite through the dissolution of fluoro and hydroxyl apatite by its precipitation from solution, beside, Pb complexation at phosphatic clay surface at P-OH sites.

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Landsat 시계열 영상을 이용한 한강 수계 호수 수온과 계절적 성충 현상 분석 (Analysis of Lake Water Temperature and Seasonal Stratification in the Han River System from Time-Series of Landsat Images)

  • 한향선;이훈열
    • 대한원격탐사학회지
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    • 제21권4호
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    • pp.253-271
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    • 2005
  • Landsat 시계열 영상과 실측수온자료를 이용하여 한강 수계 댐호들의 표면수온과 계절적 성층현상을 분석하였다. 1994년에서 2004년까지 29회에 걸쳐 얻어진 Landsat-5, 7 열적외선 영상으로부터 NASA 경험식을 이용하여 호수의 표면수온을 추출하였고, 이를 하천형 댐호인 파로호, 춘천호, 의암호, 청평호, 팔당호의 표층수온, 그리고 호소형 댐호인 소양호의 상층수온(수심 10m) 자료와 비교하였다. 십 수 년간 매월 1회 측정된 수온자료를 위성관측 날짜에 보간하여 사용하였음에도 불구하고, 하천형 댐호들에서는 수온오차(위성관측수온-실측보간수온)의 표준 편차가 $2^{\circ}C$ 이하인 영상이 94개로서, 새로운 통계적 대기보정을 적용할 수 있었다. 실측보간수온과 위성관측수온의 상관계수는 소양호가 0.915 (대기보정 후 0.950), 다른 호수는 0.951-0.980 (대기보정 후 0.979-0.997)로서, 높은 상관성을 보여주었다. 이는 수심이 얕고 인위적인 물의 유입과 유출이 연중 계속되는 하천형 댐호의 표층에는 혼합층이 상시 존재하고 수온의 일변화 및 월변화가 비교적 연속적이기 때문인 것으로 해석되었다. 그러나 소양호에서는 4-7월에 위성관측수온이 실측보간수온보다 $3-5^{\circ}C$ 더 높게 나타나는 이상 수온오차가 관찰되었다. 한강 수계의 최상류에 위치하며 수심이 깊고 자연적인 유입량만이 존재하는 소양호에서 이 시기는 상층수의 물리적 혼합현상이 없이 매우 안정적이고, 일조량 증가에 따라 호수 상층부에 수온약층이 발달하기 때문에, 수심 10m에서 측정된 실측수온보다 위성으로 관측된 표면수온이 연중 비교적 건조한 이 시기에 더 높게 나타나는 것으로 밝혀졌다.

침전법을 활용한 Co-Ni 전극의 제조와 용융탄산염 연료전지의 그 적용 (Preparation of Co-Ni Electrode by Precipitation Method and it's Application for Molten Carbonate Fuel Cell or Optimization of Co-Ni Electrode's Fabrication and it's Application for Molten Carbonate Fuel Cell)

  • 김시열;;류보현;함형철;한종희;윤성필;남석우;임태훈;이호인
    • 신재생에너지
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    • 제4권1호
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    • pp.11-18
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    • 2008
  • In-situ lithiated NiO has been manufactured as a conventional cathode material of molten carbonate fuel cell (MCFC), however this material has a weakness for commercialization of MCFC because NiO is spontaneously dissolved into the electrolyte under MCFC operating conditions, resulting in short circuit between cathode and anode. In this research, therefore, $Co(OH)_2$-coated Ni powder was prepared by precipitation method with controlling pH at low temperature and atmospheric pressure. Modified cathode was fabricated by a conventional tape casting method and sintered at 700$^{\circ}C$ in a $H_2/N_2$ atmosphere, Based on characterization result, Pore size distribution and porosity was suitable for the cathode of MCFC. According to the result of dissolution, Ni solubility of modified cathode was 33% lower than that of conventional cathode. In addition, modified electrode showed a good performance from the single cell operation.

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Rapid Climate Change During the Deglaciation of Lake Hovsgol, Mongolia

  • Chun, Jong-Hwa;Cheong, Dae-Kyo
    • 한국제4기학회지
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    • 제19권2호
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    • pp.55-58
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    • 2005
  • A 120-cm core recovered from Lake Hovsgol, the northern Mongolia provides evidence for climate variability since the Marine Isotope Stage 3, representing a sharp lithological change. The lowermost part of the core consists of diatom-barren calcareous silty clay without coarse sands, framboidal pyrite, and biogenic components deposited during the MIS 3. Following the last glacial maximum, in-situ moss is included in the sediments, as lake-level was retreated by cold and dry environment with low precipitation. The AMS radiocarbon ages of the plant fragments match a marked lithologic boundary between 14,060 and 14,325 $^{14}C$ yr BP. The contents of coarse sands abruptly increase, indicating probably wind-derived sandy dust or coarse grains contributed from floating icebergs. And abundant framboidal pyrite grains were deposited in an anoxic environment, as reflected by high accumulation of organic matters at a low lake stand. During the deglaciation, quantities of coarse sands, ostracod, shell fragments, framboidal pyrite, and diatom markedly varies by regional and global scale climate regimes. Some allochthonous coarse sands were probably ice-rafted debris derived from floating icebergs. A rapid increase in diatom productivity probably marked the onset of Bolling-Allerod warming. Subsequent high concentration of framboidal pyrite probably represents a dry and cold condition, such as Younger Drays events. Consistent warm period with high precipitation at Holocene is documented by diatomaceous clayey ooze without framboidal pyrite, coarse sands, and ostracod.

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