• Title/Summary/Keyword: In(III)

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One-Dimensional Eu(III) and Tb(III)-Doped Gd Oxide Nanorods

  • Kim, Wonjoo;Sohn, Youngku
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.664-664
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    • 2013
  • Red europium(III) and green terbium(III) activating phosphors have been doped and co-doped in gadolinium oxide supports by a hydrothermal method. Scanning electron microscope images reveal that they are one-dimensional nanorods of 40~50 wide and 250~300 nm long. The gadolinium oxide supports show Gd(OH)3 of hexagonal phase and Gd2O3 of cubic crystal structure before and after a thermal annealing, respectively based on X-ray diffraction analysis. Their physicochemical characteristics have further been examined by photoluminescence spectroscopy, FT-IR, UV-visible absorption, and optical microscope. The emission colors are characterized by CIE coordinates. In addition, the emissions from Eu(III) and Tb(III) are assigned to $5D0{\rightarrow}7FJ$ (J=0,1,2,3,4) and $5D4{\rightarrow}FJ$ (J=6,5,4,3), respectively.

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Gait Implementation of Biped Walking Robot(IWR-III) for continuous trunk motion (이족보행로봇(IWR-III)의 지속적인 몸체 추진을 위한 걸음새 구현)

  • Jang, Chung-Ryoul;Choi, Young-Ha;Choi, Sang-Ho;Kim, Jin-Geol
    • Proceedings of the KIEE Conference
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    • 1998.11b
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    • pp.549-551
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    • 1998
  • This paper deals with the new gait implementation of biped walking robot(IWR-III). In the case of using old gait. The trunk should be stopped during the phase changing time. But using new gait, the trunk moves continuously for all walking time. As a result, IWR-III has a walking gait similar to human being, and the motion of balancing joints can be reduced by the trunk ahead effect in the double support phase, moreover, ZMP tracking is improved, therefore the stability of IWR-III is improved. The trajectory is planned with a 5th order spline interpolation and stability of IWR-III is certified with a biped simulator.

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KSR- III 외피 단열에 대한 연구

  • Lee, Joon-Ho;Oh, Bum-Seok
    • Aerospace Engineering and Technology
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    • v.1 no.1
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    • pp.128-134
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    • 2002
  • Outer surfaces of KSR-III are insulated to protect outer structure and inner payloads from the aerodynamic heating. The characteristics of insulation material (BMS 10-102), selected through careful tests and thermal analyses, are low heat transfer rate and low density. It is applied in a wet and continuous spray pattern for outer surfaces of KSR-III. In the present study, the honeycomb sandwich structure of nose fairing, which is one of the typical multi-layer structures of KSR-III, is thermally analyzed with insulation.

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Electrochemical and Spectrofluorometric Studies of Europium(III)-Pyridine Dicarboxylic Acid Complexes (Eu(III)-Pyridine Dicarboxylic Acid 착물에 관한 전기화학적 거동 및 형광분광학적 연구)

  • Kim, Yong-Ryul;Chae, Won-Seok
    • Journal of the Korean Applied Science and Technology
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    • v.18 no.1
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    • pp.12-19
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    • 2001
  • Eu(III) exhibits one electron-transfer reduction at $E_{1/2}$ = -0.564 V(vs. Ag/AgCl) and the hypersensitive peak at 615 ㎚ corresponding to $^{5}D_{0}{\rightarrow}^{7}F_{2}$ transition in 0.1 M $LiClO_{4}$ aqueous solution. Upon the addition of 2,6-pyridine dicarboxylic acid(PDA) to the Eu(III) aqueous soultion, the reduction potential shifts negatively and the PDA, and the Eu(III)-PDA complex emits great fluorescence than free-Eu(III) ion at 615 nm. The results are interpreted in term of the electrochemical and spectrofluorometric studies.

Preparation and Analysis of High Functional Silicone Hydrogel Lens Containing Metal Oxide Nanoparticles by Photopolymerizaion

  • Heo, Ji-Won;Sung, A-Young
    • Korean Journal of Materials Research
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    • v.32 no.4
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    • pp.193-199
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    • 2022
  • In this study, lenses are fabricated using various nanomaterials as additives to a silicone polymer made with an optimum mixing ratio and short polymerization time. In addition, PVP is added at a ratio of 1 % to investigate the physical properties according to the degree of dispersion, and the compatibility with hydrophobic silicone and the possibility of application as a functional lens material are confirmed. The main materials are SIU as a silicone monomer, DMA, a hydrophilic copolymer, EGDMA as a crosslinking agent, and 2H2M as a photoinitiator. Holmium (III) oxide, Europium (III) oxide, aluminum oxide, and PVP are used. When Holmium (III) oxide and Europium (III) oxide are added based on the Ref sample, the characteristics of the lens tend to be similar overall, and the aluminum oxide shows a tendency slightly different from the previous two oxides. This material can be used as a silicone lens material with various nano oxides and polyvinylpyrrolidone (PVP) acting as a dispersant.

Experimental Study on the Effect of Transforming Growth $Factor-{\beta}$ to Periodontal Regeneration in Class III Furcation Defects (3급 치근분지부 골결손에서 transforming growth $factor-{\beta}$가 치주조직의 재생에 미치는 영향에 관한 시험적 연구)

  • Kim, Young-Joon
    • Journal of Periodontal and Implant Science
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    • v.31 no.2
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    • pp.421-436
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    • 2001
  • Transforming growth $factor-{\beta}(TGF-{\beta})$is a polypeptide biologic mediator considered to play a role in promoting bone formation in bony defect area. The purpose of this study was to examine the effect of $TGF-{\beta}$ to the periodontal regeneration of class III furcation defect in dogs. Classs III furcation defects were surgically created on the third and the fourth premolars bilaterally in the mandibles of eight mongrel dogs. Experimental periodontitis were induced by placing small cotton pellets into the created defects for 3 weeks. Experimental sites were divided into 4 groups according to the treatment modalities: Group I-Surgical debridement only; Group II-allogenic demineralized freeze dried bone grafting; Group III-allogenic demineralized freeze dried bone soaked in $TGF-{\beta}(4ng/10{\mu}l)$grafting; Group IV-allogenic demineralized freeze dried bone soaked in $TGF-{\beta}(20ng/10{\mu}l)$ grafting. The animals were sacrificed in the 8th week after periodontal surgery and the decalcified and undecalcified specimens were for histological and histometric examination. Although no significant differences was seen in the length of epitheial growth and connective attachment, group III showed the least apical migration among treatment groups. The amount of bone repair was significantly greater in group III, IV compared to group I and group II. New attachment formation was significantly greater in group III and group IV compared to group I and group II. These results suggest the allogenic demineralized freeze dried bone with $TGF-{\beta}$ in class III furcation defect has the potentiality of promoting alveolar bone formation and periodontal regeneration.

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A Study on the Fireproof Characteristic and the Extinguishment by NAF S-III on a Molded Transformer in Substation (변전실용 몰드변압기의 난연성과 NAF S-III 소화에 관한 연구)

  • 이수경;신효섭
    • Fire Science and Engineering
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    • v.15 no.4
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    • pp.78-85
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    • 2001
  • This dissertation is research on the fireproof characteristic of molded transformer and the extinguishable characteristics of the NAF S-III. As the research method, a theoretical examination has been made for the combustion process of epoxy resin, which was the main material of molded transformer, and extinguishing process of NAF S-III, which has recently been used in the clean extinguishable chemicals. Furthermore, for its proof, the experiments on combustion and extin-guishment on molded transformer has been performed. By installing the actual molded transformer in and artificial the horizontal heating furnace which has similar conditions with the electrical substation, and after subsequently ignited, the extinguishing process has been observed by classifying it into the natural extinguishment of the ignited transformer, and extinguishable chemical in NAF S-III has been injected. The volume of injected extinguishable chemical was the economical amount which was equipped with the extinguishable capability on the molded transformer under combustion, and it was calculated with the Announcement of the Ministry of Government Administration and Home Affairs as the basis. With the injection of the calculated extinguishable chemicals, the ignited transformer has completely extinguished within one minute.

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A Study About the Factors Concerned with Death of ICU patients by the APACHE III tool (중환자실 환자의 사망 관련 요인에 관한 연구 - APACHE III 도구를 중심으로 -)

  • Koo, Mi-Jee;Kim, Myung-Hee
    • Korean Journal of Adult Nursing
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    • v.14 no.1
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    • pp.93-101
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    • 2002
  • Using the APCHE III tool, this study was about the factors related to the death of ICU-patients. From 1999. 12. 1 to 2000. 9. 30, the 284 patients admitted to ICU at P university who were over 15 years of age were selected for the subjets. The data was analyzed through SPSS WIN program for frequency, percentile, $x^2$-test, t-test and logistic regression. The results are summarized as follows: 1) Of the 284 patients, 88died. The mortality is 31.0 percent. The average APACHE III point was $48.62{\pm}32.32$. The average point of non-survivors was higher than that of survivors. 2) There are the significant difference between APACHE III marks and mortality. The mortality rate were over 50 percent 60 points of the mark. When the marks were over 100 points, the mortality were over 90 percent. Below 40 points, the mortality was below 10 percent. Among the variables in the APACHE III, the most significant variables in explaining death were neurologic abnormalities, pulse, $PaO_2$/$AaDO_2$, creatinine, sodium, glucose, chronic health state and age. According to the variables, the models explained the 42.43 percent of the variance in patient's death. In conclusion, the APACHE III tool can be used to predict the progress of ICU patients, and can also be used for the selection of patients for ICU admission/discharge criteria.

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THE TREATMENT OF CLASS III MALOCCLUSION USING FR-III (FR-III를 이용한 3급 부정교합 환자의 치험례)

  • Kwak, Ah-Ram;Park, Jae-Hong;Choi, Sung-Chul;Kim, Kwang-Chul
    • Journal of the korean academy of Pediatric Dentistry
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    • v.35 no.2
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    • pp.345-350
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    • 2008
  • In children with Class III malocclusion, it is important to identify whether the etiology is functional, dental, skeletal. FR-III developed by Rolf Frankel in 1970, has been used during deciduous, mixed, and early permanent dentition to correct class III malocclusion characterized by maxillary skeletal retrusion. According Frankel, the vestibular shields and upper labial pads act to counteract the forces of the surrounding musculature that restrict forward maxillary development and cause a retrusion in maxillary tooth position. This can achieve favorable developments with the basal bone, teeth and alveolar bone. We report FR-III that can be applicated in cases of early mixed dentition with mild maxillary deficiency and deepbite before the eruption of permanent maxillary incisor.

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A Solid-Contact Indium(III) Sensor based on a Thiosulfinate Ionophore Derived from Omeprazole

  • Abbas, Mohammad Nooredeen;Amer, Hend Samy
    • Bulletin of the Korean Chemical Society
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    • v.34 no.4
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    • pp.1153-1159
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    • 2013
  • A novel solid-contact indium(III)-selective sensor based on bis-(1H-benzimidazole-5-methoxy-2-[(4-methoxy-3, 5-dimethyl-1-pyridinyl) 2-methyl]) thiosulfinate, known as an omeprazole dimer (OD) and a neutral ionophore, was constructed, and its performance characteristics were evaluated. The sensor was prepared by applying a membrane cocktail containing the ionophore to a graphite rod pre-coated with polyethylene dioxythiophene (PEDOT) conducting polymer as the ion-to-electron transducer. The membrane contained 3.6% OD, 2.3% oleic acid (OA) and 62% dioctyl phthalate (DOP) as the solvent mediator in PVC and produced a good potentiometric response to indium(III) ions with a Nernstian slope of 19.09 mV/decade. The constructed sensor possessed a linear concentration range from $3{\times}10^{-7}$ to $1{\times}10^{-2}$ M and a lower detection limit (LDL) of $1{\times}10^{-7}$ M indium(III) over a pH range of 4.0-7.0. It also displayed a fast response time and good selectivity for indium(III) over several other ions. The sensor can be used for longer than three months without any considerable divergence in potential. The sensor was utilized for direct and flow injection potentiometric (FIP) determination of indium(III) in alloys. The parameters that control the flow injection method were optimized. Indium(III) was quantitatively recovered, and the results agreed with those obtained using atomic absorption spectrophotometry, as confirmed by the f and t values. The sensor was also utilized as an indicator electrode for the potentiometric titration of fluoride in the presence of chloride, bromide, iodide and thiocyanate ions using indium(III) nitrate as the titrant.