• Title/Summary/Keyword: In$(OTf)_{3}$

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Airborne GPS/INS Integration Processing Module Development

  • KANG, Joon-Mook;YUN, Hee-Cheon
    • Korean Journal of Geomatics
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    • v.3 no.2
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    • pp.99-106
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    • 2004
  • In order to meet the users' demand, who needs faster and more accurate data in geographic information, it is necessary to obtain and process the data more effectively. Now more effective data obtainments about geographic information is possible through the development of integration technology, which is applied to the field of geographic information, as well as through the development of hardware and software engineering. With the fast and precise correction and update, the development of integrate technology can bring the reduction of the time and money. To obtain fast and precise geographic information using Aerial Photogrammetry method, it is necessary to develop Airborne GPS/INS integration system, which makes GCP to the minimum. For this reason, this study has tried to develop a system which could unite and process both GPS and INS data. For this matter, code-processing module for DGPS and OTF initializaion module, which can decide integer ambiguity even in motion, have been developed. And also, continuous kinematic carrier-processing module has been developed to calculate the location at the moment of filming. In addition, this study suggests a possibility of using a module, which can unite GPS and INS, using Kalman filtering, and also shows the INS navigation theory.

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Relative Reactivity of Various Al-substituted-dialkylalans in Reduction of Carbonyl Compounds: A Theoretical Study on Substituent Effect

  • Nahm, Keepyung;Cha, Jin Soon
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2335-2339
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    • 2013
  • Relative reactivity of various Al-substituted dialkylalans ($AlR_2(X)$) in reduction of acetone has been studied with density functional theory and MP2 method. Formation of the alan dimers and the alan-acetone adduct, and the transition state for the Meerwein-Ponndorf-Verley (MPV) type reduction of the adduct were calculated to figure out the energy profile. Formation of dimeric alans is highly exothermic. Both the relative free energies for acetone-alan adduct formation and the TS barriers for the MPV type reduction with respect to alan dimers and acetone were calculated and they show the same trend. Based on these energetic data, relative reactivity of alans is expected to be; $AlR_2(Cl)$ > $AlR_2(OTf)$ > $AlR_2(O_2CCF_3)$ > $AlR_2(F)$ > $AlR_2(OMs)$ > $AlR_2(OAc)$ > $AlR_2(OMe)$ > $AlR_2(NMe_2)$. The energy profile is relatively well correlated with the experimental order of the reactivity of Al-substituted dialkylalans. It is noted that the substituents of alans have initial effects on the relative free energies for the carbonyl-adduct formation. Therefore, an $AlR_2(X)$ which forms a more stable carbonyl-adduct is more reactive in carbonyl reduction.

Evaluation of Accuracy and Effectiveness of Real-Time Kinematic GPS Surveying Technology Using Carrier Phase Observations (반송파 위상관측을 이용한 실시간 Kinematic GPS 측량기법의 정확도와 효용성 평가)

  • 이진덕;정한상
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.17 no.3
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    • pp.301-309
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    • 1999
  • Real-time kinematic (RTK) GPS surveying which allows centimeter level accuracy of three-dimensional coordinates without post-processing has become recognized as a major advance in GPS technology. Employing On-The-Fly initialization technique, the RTK system can escape from cycle slip problems that have affected as a main obstacle factor in traditional kinematic and static approaches. The objective of this research was to evaluate accuracy and effectiveness of the RTK-GPS surveying. First, the continuous RTK observation of a base line was conducted for the purpose of finding out the repeatability of the RTK surveying and the results which were then compared against results from static surveying showed RMS errors of $\pm{3mm}\;and\;\pm{13mm}$ for their respective horizontal and vertical components. On a test network of 30 stations covering the small area, the results of RTK testing were compared against those from not only post-processing kinematic and rapid-static surveyings but conventional surveyings and also the efficiency of RTK were analyzed. In addition, geoid heights which were derived by combination of GPS and spirit leveling about all of the points within the network were compared against those derived by the PNU95 and EGM96 models respectively.

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Filaments and Dense Cores in Perseus Molecular Cloud

  • Chung, Eun Jung;Lee, Chang Won
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.2
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    • pp.38.2-38.2
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    • 2016
  • How dense cores and filaments in molecular clouds form is one of key questions in star formation. To challenge this issue we started to make a systematic mapping survey of nearby molecular clouds in various environments with TRAO 14m telescope equipped with 16 beam array, in high ($N_2H^+$, $HCO^+$ 1-0) and low ($C^{18}O$, $^{13}CO$ 1-0) density tracers (TRAO Multi-beam Legacy Survey of Nearby Filamentary Molecular Clouds, PI: C. W. Lee). We pursue to dynamically and chemically understand how filaments, dense cores, and stars form under different environments. We have performed On-The-Fly (OTF) mapping observations toward L1251, southern part of Perseus molecular cloud, and Serpens main molecular cloud from January to May, 2016. In total, ~3.5 square degree area map of $^{13}CO$ and $C^{18}O$ was simultaneously obtained with S/N of >10 in a velocity resolution of ~0.2 km/s. Dense core regions of ~1.7 square degree area where $C^{18}O$ 1-0 line is strongly detected were also mapped in $N_2H^+$ 1-0 and $HCO^+$ 1-0. The L1251 and Perseus MC are known to be low- to intermediate-mass star-forming clouds, while the Serpens MC is an active low-mass star-forming cloud. The observed molecular filaments will help to understand how the filaments, cores and eventually stars form in a low- and/or intermediate-mass star-forming environment. In this talk, I'll give a brief report on the observation and show preliminary results of Perseus MC.

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Analysis of Topography by Real-Time Kinematic GPS Positioning (실시간 동적 GPS 측량에 의한 지형 해석)

  • 신상철;김정동;박운용
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.19 no.3
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    • pp.263-272
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    • 2001
  • For a high resolution real-time kinematic GPS surveying using carrier phase, positioning accuracy according to the OTF initialization was better than 1 cm with more than 5-minute initialization within 20 km baseline. Also, it is recommended that measurements be carried out when PDOP and RDOP can be kept less than 4.0 since the geometrical layout of satellites has a great influence on the positioning accuracy. After considering the initial conditions and measuring time zone for real-time kinematic GPS. post-processed continuous kinematic GPS and real-time kinematic GPS measurements have been carried out. A new system has been proposed to store measured data by using a program developed to store GPS data in real time and to monitor the satellite condition through controller at the time of measurement. As a result, it has been revealed that possible noise in surveying could be corrected and the accuracy could be improved.

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Consecutive automated production of carbon-11 labeled radiopharmaceuticals by sharing 11C-methylation reagent from one 11C-synthetic module

  • Park, Hyun Sik;Lee, Hong Jin;An, Hyun Ho;Moon, Byung Seok;Lee, Byung Chul;Kim, Sang Eun
    • Journal of Radiopharmaceuticals and Molecular Probes
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    • v.2 no.2
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    • pp.123-131
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    • 2016
  • Increasing clinical demand for carbon-11 labeled radiopharmaceuticals has triggered technological advances in fields of radiochemistry and automated modules. Even though carbon-11 has a short half-life ($t_{1/2}=20.4min$), the consecutive second production of carbon-11 labeled radiopharmaceutical in one $^{11}C$-synthetic module should be delayed at least over 4 h to avoid the high radiation exposure. We herein aimed to produce two different carbon-11 labeled radiopharmaceuticals ([$^{11}C$]PIB and [$^{11}C$]methionine) by sharing of [$^{11}C$]methylation source in one $^{11}C$-synthetic module. The synthesis of $^{11}C$-labeling reagents ($[^{11}C]CH_3I$ or $[^{11}C]CH_3OTf$) is fully automated using the commercial TRACERlab $FX_{C-pro}$ module and is readily adaptable to $^{11}C$-labeling reactor for [$^{11}C$]PIB as well as another $^{11}C$-labeling apparatus for [$^{11}C$]methionine via the three-way valve. After completing the [$^{11}C$]PIB production, the re-synthesized $[^{11}C]CH_3I$ was passed through the three-way valve connected the polyetheretherketone (PEEK) line and loaded into the C18 Sep-Pak cartridge including the methionine precursor. The labeled product [^${11}C$]methionine was purified by a simple cartridge separation and reformulated into saline. The radiochemical yield of [$^{11}C$]PIB and [$^{11}C$]methionine were $5.3{\pm}0.6%$ and $18.7{\pm}0.8%$ (n.d.c.), respectively, with over 97% of radiochemical purity. The specific activity of [$^{11}C$]PIB was over $110GBq/{\mu}mol$. Total production time of two radiopharmaceuticals needs about 2 h from $1^{st}$ beam irradiation including quality control tests. Final [$^{11}C$]PIB and [$^{11}C$]methionine were satisfied all quality control test standards.

The Rate and Morphology of Mycorrhizal Infection in the Wild Ginseng (Panax ginseng C.A. Meyer) Collected from Various Locations in Korea (한국내 각지에서 채집된 산삼의 균근(菌根) 형태와 감염율)

  • Lee, Kyu-Hwa;Lee, Kyung-Joon;Park, Hoon;Budi Sri Wilarso
    • Journal of Ginseng Research
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    • v.30 no.4
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    • pp.206-211
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    • 2006
  • To investigate mycorrhizal infection by arbuscular mycorrhizal fungi(AMF), samples of fine lateral roots were taken from the wild ginseng(Panax ginseng C.A. Meyer) naturally growing at various locations in Korea. Mycorrhiazal infections were studied by cleaning the root samples and staining fungal hyphae with frypan blue. Wild ginsengs for this study were graded by an appraisal committee consisting of 12 experts of Korea Mountain Ginseng Association. Following five quality groups were recognized: Heaven group(pure natural), Earth group (from seeding of wild ginseng), Man group(from seeding or seedlings of wild ginseng with slight environmental modification), unmarketable, and imported wild ginseng. Morphology of AMF was typical Paris-type which shows intracellular hyphal coils with rare vesicles and lack of arbuscules. Average infection rate of individual wild ginsengs was 58.3% and showed no differences among five quality groups. When portions of fine roots were quantified for mycorrhizal infection, 18.7% of the total length of the primary and secondary roots were infected by AMF. Wild ginsengs from Gyeonggi Province(84.2%), and from mountains lower than 1,200 meters above sea level(about 70%) showed higher infection rate, while the ginseng from Gyeongbuk Province(27.8%) had lower rate. Wild ginsengs at older age showed lower infection rates.

Facile [11C]PIB Synthesis Using an On-cartridge Methylation and Purification Showed Higher Specific Activity than Conventional Method Using Loop and High Performance Liquid Chromatography Purification (Loop와 HPLC Purification 방법보다 더 높은 비방사능을 보여주는 카트리지 Methylation과 Purification을 이용한 손쉬운 [ 11C]PIB 합성)

  • Lee, Yong-Seok;Cho, Yong-Hyun;Lee, Hong-Jae;Lee, Yun-Sang;Jeong, Jae Min
    • The Korean Journal of Nuclear Medicine Technology
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    • v.22 no.2
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    • pp.67-73
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    • 2018
  • $[^{11}C]PIB$ synthesis has been performed by a loop-methylation and HPLC purification in our lab. However, this method is time-consuming and requires complicated systems. Thus, we developed an on-cartridge method which simplified the synthetic procedure and reduced time greatly by removing HPLC purification step. We compared 6 different cartridges and evaluated the $[^{11}C]PIB$ production yields and specific activities. $[^{11}C]MeOTf$ was synthesized by using TRACERlab FXC Pro and was transferred into the cartridge by blowing with helium gas for 3 min. To remove byproducts and impurities, cartridges were washed out by 20 mL of 30% EtOH in 0.5 M $NaH_2PO_4$ solution (pH 5.1) and 10 mL of distilled water. And then, $[^{11}C]PIB$ was eluted by 5 mL of 30% EtOH in 0.5 M $NaH_2PO_4$ into the collecting vial containing 10 mL saline. Among the 6 cartridges, only tC18 environmental cartridge could remove impurities and byproducts from $[^{11}C]PIB$ completely and showed higher specific activity than traditional HPLC purification method. This method took only 8 ~ 9 min from methylation to formulation. For the tC18 environmental cartridge and conventional HPLC loop methods, the radiochemical yields were $12.3{\pm}2.2%$ and $13.9{\pm}4.4%$, respectively, and the molar activities were $420.6{\pm}20.4GBq/{\mu}mol$ (n=3) and $78.7{\pm}39.7GBq/{\mu}mol$ (n=41), respectively. We successfully developed a facile on-cartridge methylation method for $[^{11}C]PIB$ synthesis which enabled the procedure more simple and rapid, and showed higher molar radio-activity than HPLC purification method.