• Title/Summary/Keyword: Im-PPO

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Studies of Characteristics of Polyphenol Oxidase in Yan and Antimutagenic effect of Enzymatic Browning Reaction Products (마의 Polyphenol oxidase의 특성과 효소갈변생성물의 항돌연변이 효과)

  • Jeong, Seung-Hee;Lee, Im-Sun;Koo, Sung-Ja
    • Korean journal of food and cookery science
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    • v.10 no.4
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    • pp.339-345
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    • 1994
  • Polyphenol oxidase in Yam was partially purified through ammonium sulfate fractionation, DEAE-cellulose column chromatography. The specific activity of purified PPO was 138.22 unit/mg protein. The optimum pH and temperature of purified PPO were respectively 7.0 and 30$^{\circ}C$. The heat treatment at 80$^{\circ}C$ for 6 min, decreased PPO activity to 50%. The enzyme showed high substrate specificity toward catechol. The Km value for catechol was 5 mM. In the Ames test using S. typhimurium TA98 and TA100 catechol-YEBRP, pyrogallol-YEBRP, chlorogenic-YEBRP showed strong antimutagenicity on sodium azide and MECF excepting hydroquinone-YEBRP showed killing effect on both strains.

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Synthesis and Characterization of Ion Exchange Particles for Application of Anion Exchange Membrane (음이온교환막 적용을 위한 이온교환입자의 합성 및 특성평가)

  • Dong Jun Lee;Kwang Seop Im;Ka Yeon Ryu;Sang Yong Nam
    • Membrane Journal
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    • v.33 no.3
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    • pp.137-147
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    • 2023
  • In this study, Br-PPO was developed by applying additive organic particles through a suspension polymerization synthesis method. The anion exchange membrane fuel cell system performance was evaluated using it to an anion exchange membrane. To improve the performance, organic ion exchange particles were prepared and added to the anion exchange membrane. Chemical structure analysis and synthesis were determined through FT-IR and NMR, and tensile strength and thermal stability were measured through TGA and UTM to determine whether it could be driven. Before the anion exchange membrane fuel cell test, the performance was evaluated by measuring the ion conductivity and ion exchange capacity. Finally, the Br-PPO-TMA-SDV (0.7%) anion exchange membrane with excellent ion conductivity and ion exchange capacity was introduced into the fuel cell system. Its performance was compared with FAA-3-50, a commercial membrane, to determine whether it could be introduced into a fuel cell system.

Spectra Responsibility of Quantum Dot Doped Organic Liquid Scintillation Dosimeter for Radiation Therapy

  • Kim, Sung-woo;Cho, Byungchul;Cho, Sangeun;Im, Hyunsik;Hwang, Ui-jung;Lim, Young Kyoung;Cha, SeungNam;Jeong, Chiyoung;Song, Si Yeol;Lee, Sang-wook;Kwak, Jungwon
    • Progress in Medical Physics
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    • v.28 no.4
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    • pp.226-231
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    • 2017
  • The aim is to investigate the spectra responsibilities of QD (Quantum Dot) for the innovation of new dosimetry application for therapeutic Megavoltage X-ray range. The unique electrical and optical properties of QD are expected to make it a good sensing material for dosimeter. This study shows the spectra responsibility of toluene based ZnCd QD and PPO (2.5-diphenyloxazol) mixed liquid scintillator. The QDs of 4 sizes corresponding to an emission wavelength (ZnCdSe/ZnS:$440{\pm}5nm$, ZnCdSeS:470, 500, $570{\pm}5nm$) were utilized. A liquid scintillator for control sample was made of toluene, PPO. The Composition of QD loaded scintillators are about 99 wt% Toluene as solvent, 1 wt% of PPO as primary scintillator and 0.05, 0.1, 0.2 and 0.4 wt% of QDs as solute. For the spectra responsibility of QD scintillation, they were irradiated for 30 second with 6 MV beam from a LINAC ($Infinity^{TM}$, Elekta). With the guidance of 1.0 mm core diameter optical fiber, scintillation spectrums were measured by a compact CCD spectrometer which could measure 200~1,000 nm wavelength range (CCS200, Thorlabs). We measured the spectra responsibilities of QD loaded organic liquid scintillators in two scintillation mechanisms. First was the direct transfer and second was using wave shifter. The emission peaks from the direct transfer were measured to be much smaller luminescent intensity than based on the wavelength shift from the PPO to QDs. The emission peak was shifted from PPO emission wavelength 380 nm to each emission wavelength of loaded QD. In both mechanisms, 500 nm QD loaded samples were observed to radiate in the highest luminescence intensity. We observed the spectra responsibility of QD doped toluene based liquid scintillator in order to innovate QD dosimetry applicator. The liquid scintillator loading 0.2 wt% of 500 nm emission wavelength QD has most superior responsibility at 6 MV photon beam. In this study we observed the spectra responsibilities for therapeutic X-ray range. It would be the first step of innovating new radiation dosimetric methods for radiation treatment.

Flight Trajectory Simulation via Reinforcement Learning in Virtual Environment (가상 환경에서의 강화학습을 이용한 비행궤적 시뮬레이션)

  • Lee, Jae-Hoon;Kim, Tae-Rim;Song, Jong-Gyu;Im, Hyun-Jae
    • Journal of the Korea Society for Simulation
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    • v.27 no.4
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    • pp.1-8
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    • 2018
  • The most common way to control a target point using artificial intelligence is through reinforcement learning. However, it had to process complicated calculations that were difficult to implement in order to process reinforcement learning. In this paper, the enhanced Proximal Policy Optimization (PPO) algorithm was used to simulate finding the planned flight trajectory to reach the target point in the virtual environment. In this paper, we simulated how this problem was used to find the planned flight trajectory to reach the target point in the virtual environment using the enhanced Proximal Policy Optimization(PPO) algorithm. In addition, variables such as changes in trajectory, effects of rewards, and external winds are added to determine the zero conditions of external environmental factors on flight trajectory learning, and the effects on trajectory learning performance and learning speed are compared. From this result, the simulation results have shown that the agent can find the optimal trajectory in spite of changes in the various external environments, which will be applicable to the actual vehicle.

Preparation and Gas Characterization of Poly(phenylene oxide) Containing Imidazolium (이미다졸륨을 포함하는 폴리페닐렌옥사이드 고분자 제조 및 기체 특성평가)

  • Son, Tae Yang;Jo, Jin Woo;Kim, Ji Hyeon;Kim, Tae Hyun;Tocci, Elena;Nam, Sang Yong
    • Membrane Journal
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    • v.27 no.6
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    • pp.528-535
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    • 2017
  • In this study, halogen element was introduced into polyphenylene oxide polymer using bromination reaction, and then halogen element was replaced with imidazolium. Imidazolium corporated polyphenylene oxide polymer was synthesized and the synthesis was confirmed by various instrumental characterization. In addition, gas permeation properties of $O_2$, $N_2$, $CO_2$ were studied with different imidazolium contents. As the content of imidazolium increased, the ion exchange capacity increased and the mechanical strength decreased. The gas permeance showed a tendency to decrease slightly with increaing imidazolium contents. Whereas, it was confirmed that the tendency of $CO_2/N_2$ ideal selectivity increased as the imidazolium contents increased.