• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2012.05a
• /
• pp.106-109
• /
• 2012

It was designed and tested ignition that an oxidizer rich preburner for a staged combustion cycle liquid rocket engine propelled by kerosene and LOx. Operation conditions of the preburner are about 60 of OF ratio and 20 MPa of combustion pressure. Ignition characteristics were compared by propellants flowrate. As the results, the higher propellants flowrate, the shorter the ignition delay time and the higher ignition stiffness. The ignition delay time was affected by incoming the oxidizer flowrate through the refrigerative cooling channels. The oxidizer flowrate from the cooling channels decreased by inflow of combustion gas during initial ignition. The oxidizer flowrate of the cooling channels increases, it is rapid recovery by cooling effect, eventually the ignition delay time decreases.

• Journal of the Korean Institute of Gas
• /
• v.17 no.2
• /
• pp.21-27
• /
• 2013

The lowest values of the AITs(Autoignition temperatures) in the literature were normally used fire and explosion protection. In this study, the AITs of n-Propanol+n-Octane system were measured from ignition delay time(time lag) by using ASTM E659 apparatus. The AITs of n-Propanol and n-Octane which constituted binary systems were $435^{\circ}C$ and $218^{\circ}C$, respectively. The experimental ignition delay time of n-Propanol+n-Octane system were a good agreement with the calculated ignition delay time by the proposed equations with a few A.A.D.(average absolute deviation).

• Fire Science and Engineering
• /
• v.21 no.3
• /
• pp.33-40
• /
• 2007

The values of the AITs(Autoignition temperatures) for fire and explosion protection are normally the lowest reported. This study measured the AITs of ethylbenzene+n-hexanol and ethylbenzene+n-propionic acid Systems from ignition delay time(time lag) by using ASTM E659-78 apparatus. The AITs of ethylbenzene, n-hexanol and n-propionic acid which constituted binary systems were $475^{\circ}C,\;275^{\circ}C\;and\;511^{\circ}C$, respectively. The experimental ignition delay time of ethylbenzene+n-hexanol and ethylbenzene+n-propionic acid systems were a good agreement with the calculated ignition delay time by the proposed equations with a few A.A.D.(average absolute deviation).

• 한국연소학회:학술대회논문집
• /
• 2013.06a
• /
• pp.25-28
• /
• 2013

This study presents both experimental and numerical investigation of ignition characteristics of n-heptane and n-butanol mixture. The $O_2$ concentration was fixed to 9-10% to make high exhaust gas recirculation(EGR) rate condition. Experiments were performed using a rapid compression machine. In addition, a numerical study of the ignition delay time was performed using CHEMKIN codes to validate experimental results and predict chemical species after combustion process. The results showed that the ignition delay time increased with increasing n-butanol ratio and the reactivity decreased by low $O_2$ concentration.

• 한국연소학회:학술대회논문집
• /
• 2012.04a
• /
• pp.279-281
• /
• 2012

A short chemical mechanism was developed with the chemical model reduction strategy based on the use of Simulation Error Minimization Connectivity Method(SEM-CM). We examined the accuracy resulting from using this mechanism, as compared with the full mechanism, for premixed flames and auto-ignition of methane-air mixture under high pressures. These comparisons are in good agreement, but it has a little divergence to predict the ignition delay time at high pressure conditions as compared with experiment results.

• Journal of ILASS-Korea
• /
• v.3 no.1
• /
• pp.19-26
• /
• 1998

The effect of mixture component makes a nelay time and a long total combustion period $\tau_{p\;max}$. The flame propagation delay $\tau_{df}$ was determined by the record of current ion. The pressure release delay $\tau_{dp}$ and $\tau_{p\;max}$ were determined by the indicated pressure diagram in constant volume of the combustion chamber. The results are as follows: 1) The ignition delay $\tau_t$ time takes the minimum value around $\Phi=1.15$. 2) $\tau_{df}$ and $\tau_t$ time increased according to the increases of the concentrated dilution gases, because the adiabatic flame temperature decreased due to the increases of the heat capacity. But dilution gases have little effect on flame nucleus formation delay 3) The relation between $\tau_t$ time and reciprocal laminar burning velocity is almost linear. 4) The increase of the propagation length is accompanied with increased ratio of the $\tau_{df},\;\tau_{dp},\;\tau_{t},\;\tau_{p\;max}$.

• Journal of the Korean Society of Combustion
• /
• v.18 no.2
• /
• pp.32-41
• /
• 2013

This study presents both experimental and numerical investigation of ignition delay time of n-heptane and n-butanol binary fuel. The $O_2$ concentration in the mixture was set to 9-10% to make high exhaust gas recirculation( EGR) rate condition which leads low NOx and soot emission. Experiments were performed using a rapid compression machine(RCM) at compressed pressure 20bar, several compressed temperature and three equivalence ratios(0.4, 1.0, 1.5). In addition, a numerical study on the ignition delay time was performed using CHEMKIN codes to validate experimental results and predict chemical species in the combustion process. The results showed that the ignition delay time increased with increasing the n-butanol fraction due to a decrease of oxidation of n-heptane at the low temperature. Moreover, all of the binary fuel mixtures showed the combustion characteristics of n-heptane such as cool flame mode at low temperature and negative-temperature-coefficient(NTC) behavior. Due to the effect of high EGR rate condition, the operating region is reduced at lean condition and the ignition delay time sharply increased compared with no EGR condition.

• Journal of the Korean Chemical Society
• /
• v.48 no.1
• /
• pp.12-16
• /
• 2004

The ignition of ethanol-oxygen-argon mixture was studied in reflected shock waves over the temperature range of 1281-1625 K and the pressure range of 0.69-1.06 bar. The ignition delay time was measured by the sudden increase of pressure profile and the radiation emitted by OH radicals. The relationship between the ignition delay time and the concentrations of ethanol and oxygen was determined in the form of mass-action expressions with an Arrhenius temperature dependence. In contrast to the behavior observed in methanol, ethanol acts to inhibit rather than accelerate its own ignition. Several kinetic mechanisms proposed for ethanol oxidation at high temperatures have been tested by the computer simulation.

• Proceedings of the KSME Conference
• /
• 2004.11a
• /
• pp.1704-1709
• /
• 2004

New reduced chemical kinetic mechanism for prediction of autoignition process of HSDI diesel engine was investigated. For precise prediction of the ignition characteristics of diesel fuel, mechanism coefficients were fitted by the experimental results of ignition delay of diesel spray in a constant volume vessel. Ignition delay of diesel engine on various operation condition was calculated based on the new reduced chemical mechanism. The calculation results agreed well with experimental data.

• Fire Science and Engineering
• /
• v.31 no.5
• /
• pp.1-6
• /
• 2017

The fire and explosion properties of combustible materials are necessary for the safe handling, storage, transportation and disposal. Typical combustion characteristics for process safety include auto ignition temperature(AIT). The AIT is an important index for the safe handling of combustible liquids. The AIT is the lowest temperature at which the material will spontaneously ignite. In this study, the AITs and ignition delay times of n-pentanol and p-xylene mixture were measured by using ASTM E659 apparatus. The AITs of n-pentanol and p-xylene which constituted binary system were $285^{\circ}C$ and $557^{\circ}C$, respectively. The experimental AITs and ignition delay times of n-pentanol and p-xylene mixture were a good agreement with the calculated AITs and ignition delay times by the proposed equations with a few A.A.D. (average absolute deviation). Therefore, it is possible to estimate the AITs and ignition delay times in other compositions of n-pentanol and p-xylene mixture by using the predictive equations which presented in this study.