• 화약ㆍ발파
• /
• 제34권1호
• /
• pp.1-10
• /
• 2016

2015년 8월 12일 중국 텐진항에서는 두 번의 대규모 폭발이 발생하였다. 두 번의 폭발은 TNT 3톤, TNT 21톤 규모로 추정되었다. 현재까지 폭발의 정확한 원인은 공표되지 않고 있으며 원인에 대한 몇 가지 추정이 제시되고 있다. 그중 하나는 화재진압을 위해 뿌려진 물과 탄산칼슘의 화학반응에 의해 폭발성 아세틸렌 가스가 발생하고 이 가스의 폭발이 800톤의 질산암모늄의 폭발을 야기했을 것이라는 것이다. 본 연구에서는 이러한 폭발 시나리오에 대한 폭발에너지 분석을 통해 화학적 반응에 의해 텐진항 폭발 사고와 같은 대규모 폭발이 발생 가능한지를 평가하였다.

• Journal of Biosystems Engineering
• /
• 제24권6호
• /
• pp.487-492
• /
• 1999

One of effective utilization method of rice husk is to utilize it as culture material by carbonizing the rice husk. As a second part of a series to investigate the effective and continuous production of carbonized rice husk by a cyclone combustor, a non-slagging vertical cyclone combustor without vortex collector pocket was introduced. Isothermal and mixed firing with LPG and rice husk were undertaken in order to characterize the system. Inert rice husk was used during the isothermal test to find mass of rice husk collected. It was impossible to ignite rice husk itself over the experimental conditions considered in this experiment. Cyclone combustor was operated at temperatures of 1,273~1,473K. Detailed combustion data were obtained from a pilot unit with the air flow rate of 70m$^3$/h and rice husk feed of 2kg. The equivalence ratio ranged from 0.66 to 3.48. The auxiliary gas flow rate was varied from 3.22 to 12.86$\ell$/min. The weight reduction, pH and particle size distribution of carbonized rice husk were measured to evaluate the quality of carbonized rice husk. An analysis of exhaust gas emission was conducted to characterize the combustor. The required carbonized rice husk could be obtained at equivalence ratio of 1.68~2.17, combustor temperature of 1,273~1,373K and auxiliary gas flow rate of 3.22~6.43$\ell$/min. A method to reduce CO emissions should be employed.

• 한국안전학회지
• /
• 제16권1호
• /
• pp.48-52
• /
• 2001

This study was undertaken to investigate fire risk characteristics of the plastics foam that is used an insulating materials in workplaces. The ignition characteristics and combustion gas of the plastics foam were carried out using the ISO self-Ignition tester, the Cone Calorimeter, and NES combustion analyzer. The experimental materials used were commercial samples and their composition is not disclosed by the manufacturer. As the experimental results, the self-ignition temperature of the plastics foam ranges from $410^{\circ}C$ to $510^{\circ}C$, and the flash-ignition temperature of plastics foam ranges from $370^{\circ}C$ to $450^{\circ}C$. The difference of ignition temperature on density with plastics foam type was smaller since the amount of combustible gas to ignite is not caused enough. The time to ignition of the polyethylene foam in samples of the plastics foam was shorter, and its of polyethylene foam was longer. The concentration of carbon dioxide of the polyethylene foam shows higher in samples of the plastics foam. It is found that the concentration values of carbon monoxide of the plastics foam show very fatality on people during exposure of 30 minutes in fire.

• 한국안전학회지
• /
• 제21권3호
• /
• pp.45-52
• /
• 2006

The AITs(autoignition temperatures) describe the minimum temperature to which a substance must be heated, without the application of a flame or spark, which will cause that substance to ignite. The AITs are often used as a factor in determining the upper temperature limit for processing operations and conditions for handling, storage and transportation, and in determining potential fire hazard from accidental contact with hot surfaces. The measurement AITs are dependent upon many factors, namely initial temperature, pressure, volume, fuel/air stoichiometry, catalyst material, concentration of vapor, time lag. Therefore, the AITs reported by different ignition conditions are sometimes significantly different. This study measured the AITs of benzene, toluene and xylene isomers from time lag using AS1M E659-78 apparatus. The experimental ignition delay times were a good agreement with the calculated ignition delay times by the proposed equations wtih a few A.A.D.(average absolute deviation). Also The experimental AITs of benzene, toluene, o-xylene, m-xylene and p-xylene were $583^{\circ}C,\;547^{\circ}C,\;480^{\circ}C,\;587^{\circ}C,\;and\;557^{\circ}C$, respectively.

• 한국안전학회지
• /
• 제9권3호
• /
• pp.53-59
• /
• 1994

Hydrogen(H$_2$) is used in the semiconductor industries, and some oxidizing gases such as fluoride(F$_2$) and chlorine trifluoride(CIF$_3$) are also used. As F$_2$and CIF$_3$are highly oxidizing gases, it were supposed to react vigorously with H$_2$. In this study, the flammability limit of F$_2$/$H_2$/Ar and CIF$_3$/$H_2$/Ar mixtures were investigated experimentally. As a result, it was found that the diluted F$_2$gas could be spontaneously ignited as compared to CIF$_3$mixture gas while being mixed with the diluted H$_2$gas. However, CIF$_3$diluted gas was not able to ignite spontaneously except for an electric spark. And the combustion characteristics and reaction kinetics were shown at the different diluted gases by the flammability diagram analyses between the F$_2$/$H_2$/Ar and CIF$_3$/$H_2$/Ar.

• 전기학회논문지P
• /
• 제63권3호
• /
• pp.183-188
• /
• 2014

Power conversion systems used in large gas turbine power plant can be divided into two main part. Because of the initial start-up characteristic of the gas turbine combustor, the gas turbine must be accelerated by starting device(LCI : Load Commutated Inverter) up to 10%~20% of rated speed to ignite it. In addition, the ECS(Excitation Control system) is used to control the rotor field current and reactive power in grid-connected synchronous generator. These two large power conversion systems are located in the same space(container) because of coordination control. Recently, many manufactures develop high speed controller based on function block available in the LCI and ECS with the newest power semiconductor. We also developed high speed controller based on function block to be using these two system and it meets the international standard IEC61131 as using real-time OS(VxWorks) and ISaGRAF. In order to install easily these systems at power plant, main controller, special module and IO module are used with high speed communication line other than electric wire line. Before initial product is installed on the site, prototype is produced and tests are conducted for it. The performance results of Integrated controller and application program(SFC, ECS) were described in this paper. The test results will be considered as the important resources for the application in future.

• 한국자동차공학회논문집
• /
• 제7권6호
• /
• pp.8-16
• /
• 1999

In this study, a new type of laser-induced ignition using a conical cavity has been developed to utilize all the available incident laser energy. In the method, it is possibile to ignite combustible methane/air mixtures by directing a laser beam of a constant small diameter into a small conical cavity, without focusing the laser beam. Shadow graphs for the early stage of combustion process show that a hot gas jet is ejected from the cavity, especially with lean mixture. After a very show time, the hot gas jet finishes issuing and the flame behavior is quite similar to flame propagation initiated by a conventional spark ignition. The combustion process using the new method exhibits more rapid pressure increase and a higher maximum pressure rise than that of the center ignition using laser-induced spark, with significant decrease in the combustion time. Also, the new ignition method is numerically modeled to simulate the flame kernel development and subsequent combustion process using the KIVA-IIcode. The calculated results show satisfactory agreement with experimental results.

• 한국자동차공학회논문집
• /
• 제11권3호
• /
• pp.92-98
• /
• 2003

An LPG engine for heavy-duty vehicles has been developed using liquid phase LPG injection (hereafter LPLi) system which has regarded as one of the next generation LPG fuel supply systems. In this wort to investigate the lean bum characteristics of heavy-duty LPLi engine, various injection timing (SOI, start of injection) and double ignition method were tested. The results showed that lean misfire limit of LPLi engine could be extended. by 0.2 $\lambda$ value, using the optimal SOI timing in LPLi system. Double ignition method test was carried out by installing the second spark plug and modified ignition circuit to ignite two spark plugs simultaneously. Double ignition resulted in the stable combustion under ultra lean bum condition, below $\lambda=1.7$, and extension of lean misfire limit compare to ordinary case. Therefore, LPLi engine with optimal SOI and double ignition method could be normally operated at around $\lambda=1.9$ and showed higher engine performance.

• 한국자동차공학회논문집
• /
• 제22권1호
• /
• pp.157-164
• /
• 2014

Dual fuel combustion strategy with di-methl ether (DME) and gasoline was tested in a compression ignition engine. Characteristics of combustion and emissions were analyzed with the variation of engine operating parameters such as fuel proportion, DME injection timing, intake oxygen concentration, DME injection pressure and so forth. Gasoline was injected into the intake manifold to form the homogeneous mixture with intake charge and DME was injected directly into the cylinder at the late compression stroke to ignite the homogeneous gasoline-air mixture. Dual fuel combustion strategy was advantageous in achievement of higher thermal efficiency and low NOx emission compared with DME single fuel combustion. Higher thermal efficiency was attributed to the lower heat tranfer loss from the decreased combustion temperature since the amount of lean premixed combustion was increased with the larger amount of gasoline proportion. Lower NOx emissions were also possible by lowering the combustion temperature.

• 한국분말재료학회지
• /
• 제5권4호
• /
• pp.250-257
• /
• 1998

The synthesis of titanium silicides ($Ti_3Si$, $TiSi_2$, $Ti_5Si_4$, $Ti_5Si_3$ and TiSi) by mechanical alloying has been investigated. Rapid, self-propagating high-temperature synthesis (SHS) reactions were observed to produce the last three phases during room-temperature high-energy ball milling of elemental powders. Such reactions appeared to be ignited by mechanical impact in an intimate, fine powder mixture formed after a critical milling period. During the high-energy ball milling, the repeated impact at contact points leads to a local concentration of energy which may ignite a self-propagating reaction. From in-situ thermal analysis, each critical milling period for the formation of $Ti_5Si_4$, $Ti_5Si_3$ and TiSi was observed to be 22, 35.5 and 53.5 min, respectively. $Ti_3Si$ and $TiSi_2$, however, have not been produced even till the milling period of 360 min due to lack of the homogeneity of the powder mixtures. The formation of titanium silicides by mechanical alloying and the relevant reaction rates appeared to depend upon the critical milling period, the homogeneity of the powder mixtures, and the heat of formation of the products involved.