• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.280-280
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• 2012

We examined ammonia diffusion on the surface of amorphous ice film through the measurement of decreasing residual quantity of $NH_3$ molecules compared to $H_2O$. The populations of $NH_3$ molecules on the surface of amorphous ice were monitored by using the techniques of temperature programmed reactive ion scattering (TPRIS) method. The ratio of intensity between ammonia and water was examined as a function of time at controlled temperature. When ammonia molecules were externally added onto an ice film at a temperature of 80 K, ammonia coverage with regard to ice was 0.12-0.16 ML. The intensity of ammonia molecules on the surface of ice decreased as time increased and the extent of decreased intensity of ammonia increased as controlled temperature increased. Moreover, energy barrier was estimated to be $51kJmol^{-1}$ on amorphous ice film. The results of the experiment indicate that ammonia molecules have a property of vertical diffusion into amorphous ice and the energy barrier of ammonia diffusion into bulk of ice is higher than that of hydrogen bonding.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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• pp.263-263
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• 2013

This work examines the dynamic properties of ice surfaces in vacuum for the temperature range of 140~180 K, which extends over the onset temperatures for ice sublimation and the phase transition from amorphous to crystallization ice. In particular, the study focuses on the transport processes of excess protons and chloride ions in ice and their segregative behavior to the ice surface. These phenomena were studied by conducting experiments with a relatively thick (~100 BL) ice film constructed with a bottom $H_2O$ layer and an upper $D_2O$ layer, with excess hydronium and chloride ions trapped at the $H_2O$/$D_2O$ interface as they were generated by the ionization of hydrogen chloride. The migration of protons, chloride ions, and water molecules to the ice film surface and their H/D exchange reactions were measured as a function of temperature using the methods of low energy sputtering (LES) and Cs+ reactive ion scattering (RIS). Temperature programmed desorption (TPD) experiments monitored the desorption of water and hydrogen chloride from the surface. Our observations indicated that both hydronium and chloride ions migrated from the interfacial layer to segregate to the surface at high temperature. Hydrogen chloride gas desorbs via recombination reaction of hydronium and chloride ions floating on the surface. Surface segregation of these species is driven by thermodynamic potential gradient present near the ice surface, whereas in the bulk, their transport is facilitated by thermal diffusion process. The finding suggests that chlorine activation reactions of hydrogen chloride for polar stratospheric ice particles occur at the surface of ice within a depth of at most a few molecular layers, rather than in the bulk phase.

• 대기
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• 제31권5호
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• pp.525-537
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• 2021

Black ices on road surfaces in winter tend to cause severe and terrible accidents. It is very difficult to detect black ice events in advance due to their localities as well as sensitivities to surface and upper meteorological variables. This study develops a methodology to detect the road sections vulnerable to black ice with the use of road surface temperature data obtained from a mobile road weather observation vehicle. The 7 experiments were conducted on the route from Nam-Wonju IC to Nam-Andong IC (132.5 km) on the Jungang Expressway during the period from December 2020 to February 2021. Firstly, temporal road surface temperature data were converted to the spatial data with a 50 m resolution. Then, the spatial road surface temperature was normalized with zero mean and one standard deviation using a simple normalization, a linear de-trend and normalization, and a low-pass filter and normalization. The resulting road thermal map was calculated in terms of road surface temperature differences. A road ice index was suggested using the normalized road temperatures and their horizontal differences. Road sections vulnerable to black ice were derived from road ice indices and verified with respect to road geometry and sky view, etc. It was found that black ice could occur not only over bridges, but also roads with a low sky view factor. These results are expected to be applicable to the alarm service for black ice to drivers.

• 대기
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• 제32권4호
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• pp.297-306
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• 2022

We examined potential seasonal prediction of the Korean surface temperature using the relationships between the Arctic Sea Ice Area (SIA) in autumn and the temperature in the following July and February at 850 hPa in East Asia (EA). The Surface Air Temperature (SAT) over Korea shows a similar relationship to that for EA. Since 2007, reduction of autumn SIA has been followed by warming in Korea in July. The regional distribution shows strong correlations in the southern and eastern coastal areas of Korea. The correlations in the sea surface temperature shows the maximum values in July around the Korean Peninsula, consistent with the coastal regions in which the maximum correlations in the Korean SAT are seen. In February, the response of the SAT to the SIA is the opposite of that for the July temperature. The autumn sea ice reduction is followed by cooling over Korea in February, although the magnitude is small. Cooling in the Korean Peninsula in February may be related to planetary wave-like features. Examining the autumn Arctic sea ice variation would be helpful for seasonal prediction of the Korean surface temperature, mostly in July and somewhat in February. Particularly in July, the regression line would be useful as supplementary information for seasonal temperature prediction.

• 대기
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• 제20권4호
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• pp.427-436
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• 2010

The single-scattering optical properties of ice crystals in cirrus clouds by the aircraft measurement data were investigated, and the radiative equilibrium temperatures and radiative fluxes were calculated and analyzed by radiative convective model with the variations of ice crystal habits and sizes in cirrus clouds. The homogeneous cloud is assumed to be in the layer 200~260 hPa with an ice crystal content of $10gm^{-2}$ for the flux calculation. The profiles of temperature, humidity, and ozone typical of mid-latitude summer are used. The surface albedo is assumed to be 0.2 for all spectral bands and the cosine of solar zenith angles is 0.5. The result of radiative equilibrium temperature at surface was less than surface temperature of the standard atmosphere data in case of smaller effective ice crystal size and larger optical thickness. The column, aggregation and plate in 6 ice crystal habits were the most effective in positive greenhouse effect and bullet-4 was the worst in it. At the surface, the maximum difference of equilibrium temperature by 6 kinds of ice crystal habits were about 3~15 K with 30 sample aircraft measurement data.

• Journal of Oral Medicine and Pain
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• 제20권2호
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• pp.307-315
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• 1995

The purpose of this study was to assess the efficacy of several thermal therapies using ice pack, moist-hot pack and ultrasound, separately and concomitantly and to obtain the background information on the vascular changes after thermophysical therapies. The author had used 15 healthy subjects were examined and the subjects were divide into 5 groups : ice pack, moist-hot pack, ultrasound, ice pack and moist-hot pack, ice pack and ultrasound. Observation were made immediate before and 0,5,10,20,30,45,60,90 minutes after treatment. Thermography was performed in an Agema 870 thermovisio with 0.1$^{\circ}C$ difference of gradual temperature shift. The results were as follows : 1. Using ice pack only, the surface temperature of the masseter region was increased lapse of time, and most remarkably 90 minutes after the treatment. 2. Using moist-hot pack only, the surface temperature of the region was remarkably increased immediately after the treatment, but decreased lapse of time. 3. Using moist-hot pack with ice pack, the surface temperature of the face was remarkably increased immediately after the treatment, and decreased lapse of time, Hyperthermia was maintained for a longer time as compared with the group of moist-hot pack only. 4. Using ultrasound only, the surface temperature of the region was increased gradually, and most remarkably 30 minutes after the treatment, but decreased in the course of time. 5. Using ultrasound combined with ice pack, the surface temperature of the region was gradually decreased until 30 minutes after the treatment, and decrease to some extend at 45 minute. And then a gradual increase observed over the remaining period of the experiment. 6. Hyperthermia were maintained for a long time in the groups using ice pack combined with moist-hot pack and ultrasound as compared with the other groups. Our data suggest that ice pack can promote the efficacy of other thermal therapies.

• 한국산업융합학회 논문집
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• 제24권6_2호
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• pp.873-882
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• 2021

In this study, a study was conducted to develop a system for predicting/responding to black ice occurring on roads in winter. Tests conditions were studied by making models of cement concrete pavement and asphalt concrete pavement. In order to freeze water on the manufactured model package, an tests was conducted at a temperature below zero using a freezer, and the freezing process was photographed using a thermal imaging camera. Black ice is generated when water is present on the road surface and the temperature is below freezing or the road surface temperature is below the dew point temperature. Under sub-zero conditions, the pavement, water, and ice were classified with a thermal imaging camera. As a result of the tests, it was possible to distinguish with a thermal imaging camera at a temperature below freezing in the same freezer due to the difference in the emissivity of the packaging, water, and ice. In the process of changing from water to ice during the tests, it was analyzed that ice and water were clearly distinguished by the thermal imaging camera due to the difference in emissivity and reflectance, so black ice could be predicted using the thermal imaging camera.

• 한국지구과학회지
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• 제28권5호
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• pp.598-602
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• 2007

A long-term in situ observation was carried out in the Ice-valley at Milyang in order to explain the factors and processes associated with the summertime ice formation. The variation of temperature inside Ice-valley in relation with ice formation in summer time was found to depend on precipitation rate in spring and cold air sinking in autumn and winter. The rate of temperature rising tends to correspond to sensible heat release depending on the precipitation amount at the freezing location. The reason of the cold air accumulation in a talus in the Ice-valley is the cold air sinking over the surface of talus due to the occurrence of outside clod air mass and the accumulated cold air from autumn to spring flow outside at the bottom of talus. The out-flowing cold air can result in the ice formation in the hot summer.

• 지구물리
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• 제8권4호
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• pp.173-185
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• 2005

This study examines the relationships among sea ice concentration, surface air temperature, surface wind, and SST (Sea Surface Temperature) in Bransfield Strait to understand the climatic characteristics and its related sedimentary process there. In analyses of the monthly data, during the austral autumn (Mar., Apr., and May), the frequency of southeasterlies is correlated positively with the sea ice concentration and negatively with the surface air temperature, whereas that of northwesterlies is reverse. These relationships are explained by the process that the southeasterlies of the cold air from the Antarctic Continent affect the ocean current around Bransfield Strait. And then the ocean current makes the sea ice generated in the Weddell Sea drift into the strait. During the spring (Sep., Oct., and Nov.), sea ice concentration and surface air perature are closely correlated with the frequency of northwesterlies with warm air mass. In the some parts of the northern boundary region, the sea ice concentration in Bransfield Strait is positively correlated with the SST during the autumn and spring. Such relationship may rather propel the sea ice melting in proportion to the sea ice concentration during the autumn.

• 설비공학논문집
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• 제21권5호
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• pp.291-296
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• 2009

Ice accumulating system patterned ice-an-coil is the way of refrigerating regenerative materials on the surface of copper-tube inserted into the inside of ice-storage. The study experimented to understand ice-an-coil type ice making characteristics according to changing shape of ice making tube. The experiment were carried out under various conditions, that used brine temperature($-l0^{\circ}C$, $-6^{\circ}C$) brine flow rate(l.0m/s, 1.8m/s) and inlet water temperature($6^{\circ}C$, $12^{\circ}C$) etc. Mass of ice per making area increased according to the decrease of the brine temperature and inlet water temperature, but that was increased according to the increase of the brine flow rate. And I set up two hypotheses and compared the capacity of ice-making of the two cases; each had the same thermal area and one had an round-shaped copper tube but the other had an oval-shaped copper tube.