• Membrane Journal
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• v.20 no.1
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• pp.55-61
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• 2010

A diblock copolymer of polystyrene-b-poly(oxyethylene methacrylate) (PS-b-POEM) was synthesized via atom transfer radical polymerization (ATRP), as revealed by FT-IR spectroscopy. The self-assembled block copolymer membrane was prepared and used to template the growth of silver nanoparticles in the solid state by the introduction of $AgCF_3SO_3$ precursor and UV irradiation process. Transmission electron microscopy (TEM) and UV-visible spectroscopy confirmed the in situ formation of silver nanoparticles within the block copolymer membranes, and the size of nanoparticles were controlled by adjusting the moiety of hydrophilic POEM domains. PS-b-POEM block copolymer with a lower POEM content was effective in generating smaller size of metal nanoparticles.

• Polymer(Korea)
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• v.24 no.4
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• pp.571-577
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• 2000

A new type of filler for epoxy-clay nanocomposites has been prepared by the reaction of octadecyltrimethylammonium bromide and layered sodium montmorillonite (MMT) via an ion-exchange reaction. The gallery space was further modified by grafting the aminopropyl groups via a reaction between a octadecyltrimethylammonium-MMT and 3-aminopropyltriethoxysilane (APS). The interlayer modification of MMT was confirmed by XRD, IR, and solid-state $^{29}$ Si CP/MAS NMR. Furthermore, clay-polymer nanocomposites have been synthesized by the polymerization of diglycidyl ether of bisphenol A(DGEBA) and $C_{18}$ H$_{37}$ N($CH_3$)$_3$-APS-MMT. The resulting hybrid nanocomposites were characterized by XRD, transmission electron microscopy (TEM) and scanning electron microscopy (SEM). The results proved that the organomontmorillonite could be exfoliated and uniformly dispersed in the epoxy matrix.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.7
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• pp.24-35
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• 2018

In wireless communications environments, a link adaptation technique that selects the proper rate from among several transmission rates is adopted to cope with variations in channel status. In block coded modulation, the frame time and/or the block length can be adjusted to the channel status. A smaller frame time can cause inter-frame interference (IFI), however, a larger frame time can reduce the data rate. Therefore, frame time is the design factor decided by a tradeoff between performance and the data rate. This paper presents a method to determine the frame time based on the processing gain for the channel model, CM1~CM4, recommended by IEEE 802.15a. Also, a link adaptation technique for block coded modulation is proposed for efficient communications by varying the frame time and the block length. Through simulation, link adaptation can be carried out with a step size of 2~5 nsec in a frame time range of 14~ 50 nsec for channel models CM1~CM4.

• Asian Pacific Journal of Cancer Prevention
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• v.15 no.3
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• pp.1299-1306
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• 2014

Background: Nano-biotechnology is recognized as offering revolutionary changes in various fields of medicine. Biologically synthesized silver nanoparticles have a wide range of applications. Materials and Methods: Silver nanoparticles (AgNPs) were biosynthesized with an aqueous extract of Pterocladiella (Pterocladia) capillacea, used as a reducing and stabilizing agent, and characterized using UV-VIS spectroscopy, Fourier Transform Infra red (FT-IR) spectroscopy, transmission electron microscopy (TEM) and energy dispersive analysis (EDX). The biosynthesized AgNPs were tested for cytotoxic activity in a human hepatocellular carcinoma ($HepG_2$) cell line cultured in Dulbecco's modified Eagle medium supplemented with 10% fetal bovine serum, 1% antibiotic and antimycotic solution and 2 mM glutamine. Bacterial susceptibility to AgNPs was assessed with Staphylococcus aureus, Bacillus subtilis [Gram+ve] and Pseudomonas aeruginosa and Escherichia coli [Gram-ve]. The agar well diffusion technique was adopted to evaluate the bactericidal activity of the biosynthesized AgNPs using Ampicillin and Gentamicin as gram+ve and gram-ve antibacterial standard drugs, respectively. Results: The biosynthesized AgNPs were $11.4{\pm}3.52$ nm in diameter. FT-IR analysis showed that carbonyl groups from the amino acid residues and proteins could assist in formation and stabilization of AgNPs. The AgNPs showed potent cytotoxic activity against the human hepatocellular carcinoma ($HepG_2$) cell line at higher concentrations. The results also showed that the biosynthesized AgNPs inhibited the entire panel of tested bacteria with a marked specificity towards Bacillus subtillus. Conclusions: Cytotoxic activity of the biosynthesized AgNPs may be due to the presence of alkaloids present in the algal extract. Our AgNPs appear more bactericidal against gram-positive bacteria (B. subtillus).

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.19 no.1
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• pp.11-14
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• 2009

Yb and Zn co-doped $LiNbO_3$ single crystal rods which had a diameter of 2 mm and a length of $15{\sim}25 mm$ were grown by micro-pulling down (${\mu}-PD$) method. The single crystals were successfully grown and had a uniform diameter and a smooth surface without crack. We realized of $LiNbO_3$ single crystals were hexagonal structure to compare with peaks of $LiNbO_3$ powder by Raman spectra. The threshold level of Zn concentration which is effective for optical damage were observed as about 1 mol% with IR transmission spectra.

• Journal of the Korean Institute of Telematics and Electronics C
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• v.36C no.2
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• pp.54-61
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• 1999

This paper describes the design of a 4-Mbps wireless infrared data transceiver chip. The receiver consits of the analog front-end, clock recovery and frame generator, and demodulator. The transmitter consists of the demodulator and LED driver. The versatile analog front- end consisting of multiple amplifiers makes it possible for the chip to be applied to various infrared environments by compensating DC and offset signal components. A 4PPM (pulse position modulation) scheme is used for data transfer in order to meet the IrDA standards. The chip was fabricated in a $0.8-{\mu}m$ 2-poly, 2-metal CMOS technology and dissipates 122mW for ${\pm}2.5V$ supply.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.47 no.7
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• pp.8-17
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• 2010

Ubiquitous home refers not only to home but also to logical space, including a wide range of out-home personal devices such as mobile phones, PDAs, laptops, car navigators, and office PCs. There are certain connection barriers among the devices, such as the dynamic IP address, NAT. In a home network, various devices coexist in heterogeneous networks, such as IP, IEEE1394, PLC, Bluetooth, ZigBee, UWB, and IrDA, all of which lack interoperability due to their different physical transmission characteristics and protocols. In ubiquitous home where an unrestricted collaboration of the devices is essential to offer services that meet the users' requirements, free interoperability among the devices must be guaranteed. This paper proposes a networking model for interoperability of the heterogeneous devices in a ubiquitous home based on a virtual overlay network which hides the complicated physical network configurations and heterogeneity of the service protocols.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.48 no.2
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• pp.168-177
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• 2015

Shell waste from the butter clam Saxidomus purpuratus and littleneck clam Ruditapes philippinarum is a large by-product of shellfish aquaculture, and it is desirable to convert it into value-added products for industrial applications. In this study, calcium carbonate (CaC) polymorphs from butter clam (BCSP) and littleneck clam (LCSP) shell powders and commercial CaC were characterized using Fourier transmission infrared spectroscopy (FT-IR), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The results revealed that the optimal calcination conditions to eliminate organic substances and improve solubility for both BCSP and LCSP were $800^{\circ}C$ for 8 h in an electrical furnace. Calcination improved the white index of the butter clam (BCCP) and littleneck clam (LCCP) calcined powder compared with shell powders. The calcium content in BCCP (51.1%) was higher than that of LCCP (44.9%) or commercial calcium oxide (CaO, 44.7%). The XRD patterns of BCCP and LCCP were similar to that of CaO. Cubic-like crystals of CaC and irregular crystals of BCCP and LCCP were observed by SEM. The FT-IR and XRD analyses revealed the presence of calcite and aragonite in the BCSP and aragonite in the LCSP, whereas the CaC contained calcite. These results indicate that butter and littleneck clam shells are potential biomass resources for calcium carbonate and calcium oxide.

• Journal of Environmental Science International
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• v.27 no.7
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• pp.611-620
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• 2018

In this study, a metal-organic framework (MOF) material $NH_2$-MIL-101(Fe) was synthesized using the solvothermal method, and characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), UV-visible spectrophotometry, field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), and surface area measurements. The XRD pattern of the synthesized $NH_2$-MIL-101(Fe) was similar to the previously reported patterns of MIL-101 type materials, which indicated the successful synthesis of $NH_2$-MIL-101(Fe). The FT-IR spectrum showed the molecular structure and functional groups of the synthesized $NH_2$-MIL-101(Fe). The UV-visible absorbance spectrum indicated that the synthesized material could be activated as a photocatalyst under visible light irradiation. FE-SEM and TEM images showed the formation of hexagonal microspindle structures in the synthesized $NH_2$-MIL-101(Fe). Furthermore, the EDS spectrum indicated that the synthesized material consisted of Fe, N, O, and C elements. The synthesized $NH_2$-MIL-101(Fe) was then employed as an adsorbent and photocatalyst for the removal of Indigo carmine and Rhodamine B from aqueous solutions. The initial 30 min of adsorption for Indigo carmine and Rhodamine B without light irradiation achieved removal efficiencies of 83.6% and 70.7%, respectively. The removal efficiencies thereafter gradually increased with visible light irradiation for 180 min, and the overall removal efficiencies for Indigo carmine and Rhodamine B were 94.2% and 83.5%, respectively. These results indicate that the synthesized MOF material can be effectively applied as an adsorbent and photocatalyst for the removal of dyes.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.32 no.6A
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• pp.519-536
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• 2007

In this paper, we combine the Hybrid-Automatic Repeat reQuest (HARQ) algorithm with joint Tx and Rx antenna selection based on the reliability of the individual antennas links. The cyclic redundancy check (CRC) is applied on the data before being encoded using the Turbo encoder. In the receiver the CRC is used to detect errors of each antenna stream and to decide whether a retransmission is required or not. The receiver feeds back the transmitter with the Tx antennas ordering and the acknowledgement of each antenna (ACK or NACK). If the number of ACK antennas is higher than the NACK antennas, then the retransmission takes place from the ACK antennas using the Chase Combining (CC). If the number of the NACK antennas is higher than the ACK antennas then the ACK antennas are used to retransmit the data streams using the CC algorithm and additional NACK antennas are used to retransmit the remaining streams using Incremental Redundancy (IR, i.e. the encoder rate is reduced). Furthermore, the HARQ is used with the I-BLAST (Iterative-BLAST) which grantees a high transmission rate.