• 제목/요약/키워드: IR spectroscopy

검색결과 1,339건 처리시간 0.03초

Thermal Decomposition Reaction of Gas-phase Uranyl Complexes as Studied by in-Situ IR Spectroscopy

  • Cho, Young-Hwan;Choi, In-Kyu;Kim, Won-Ho
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 2002년도 춘계공동학술발표회요약집
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    • pp.420.1-420
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    • 2002
  • Thermal decomposition reaction of gas-phase UO2(hfacac)2. THF was investigated in a static cell. IR spectroscopic method was used to study the thermal decomptsition of gas phase uranyl complexes. The decomposition reaction products were separated by using thermal-gradient fractional sublimation method utilizing the differences in their volatility.

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Herschel/PACS spectroscopy of the supernova remnant G21.5-0.9

  • 차희찬;안홍준
    • 천문학회보
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    • 제45권1호
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    • pp.53.1-53.1
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    • 2020
  • We present Herschel Space Observatory far-IR observations of the supernova remnant(SNR) G21.5-0.9. We search PACS-IFU data for 63um [O I], 88um [O III], 157um [C II] emission lines and detect the [O II] and the [C II]. We then produce emission line maps to check the spatial distribution of the elements. We compare the maps to Radio, IR-photometrics, and X-ray images in order to understand interaction of the ejecta with the Pulsar Wind Nebula(PWN) and physical environment in the SNR.

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Carbohydrate and lipid spectroscopic molecular structures of different alfalfa hay and their relationship with nutrient availability in ruminants

  • Yari, Mojtaba;Valizadeh, Reza;Nnaserian, Abbas Ali;Jonker, Arjan;Yu, Peiqiang
    • Asian-Australasian Journal of Animal Sciences
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    • 제30권11호
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    • pp.1575-1589
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    • 2017
  • Objective: This study was conducted to determine molecular structures related to carbohydrates and lipid in alfalfa hay cut at early bud, late bud and early flower and in the afternoon and next morning using Fourier transform infrared spectroscopy (FT/IR) and to determine their relationship with alfalfa hay nutrient profile and availability in ruminants. Methods: Chemical composition analysis, carbohydrate fractionation, in situ ruminal degradability, and DVE/OEB model were used to measure nutrient profile and availability of alfalfa hay. Univariate analysis, hierarchical cluster analysis (CLA) and principal components analysis (PCA) were conducted to identify FT/IR spectra differences. Results: The FT/IR non-structural carbohydrate (NSCHO) to total carbohydrates and NSCHO to structural carbohydrate ratios decreased (p<0.05), while lignin to NSCHO and lipid CH3 symmetric to CH2 symmetric ratios increased with advancing maturity (p<0.05). The FT/IR spectra related to structural carbohydrates, lignin and lipids were distinguished for alfalfa hay at three maturities by PCA and CLA, while FT/IR molecular structures related to carbohydrates and lipids were similar between alfalfa hay cut in the morning and afternoon when analyzed by PCA and CLA analysis. Positive correlations were found for FT/IR NSCHO to total carbohydrate and NSCHO to structural carbohydrate ratios with non-fiber carbohydrate (by wet chemistry), ruminal fast and intermediately degradable carbohydrate fractions and total ruminal degradability of carbohydrates and predicted intestinal nutrient availability in dairy cows ($r{\geq}0.60$; p<0.05) whereas FT/IR lignin to NSCHO and CH3 to CH2 symmetric stretching ratio had negative correlation with predicted ruminal and intestinal nutrient availability of alfalfa hay in dairy cows ($r{\geq}-0.60$; p<0.05). Conclusion: FT/IR carbohydrate and lipid molecular structures in alfalfa hay changed with advancing maturity from early bud to early flower, but not during the day, and these molecular structures correlated with predicted nutrient supply of alfalfa hay in ruminants.

Structural Properties of Polyaniline Blended with PNIPAM

  • Neupane, Kosh-Prasad;Ha, Jin-Wook
    • 한국산학기술학회논문지
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    • 제4권3호
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    • pp.209-213
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    • 2003
  • Polyaniline (PANi) composite particles were synthesized by chemical oxidation polymerization of aniline in presence of poly-n-isopropyl acryl amide (PNIPAM). The PANi particles formed in the reaction medium deposited onto non-conducting PNIPAM template to produce PANi-coated composite particles. The formation of composite was confirmed by FT-IR spectroscopy, and UV-VIS spectroscopy, and their morphological structures were examined by scanning electron microscopy (SEM). From the experimental results, it was determined that PANi was successfully coated onto non-conducting PNIPAM.

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VISIBLE/NEAR-IR REFLECTANCE SPECTROSCOPY FOR THE CLASSIFICATION OF POULTRY CARCASSES

  • Chen, Yud-Ren
    • 한국농업기계학회:학술대회논문집
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    • 한국농업기계학회 1993년도 Proceedings of International Conference for Agricultural Machinery and Process Engineering
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    • pp.403-412
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    • 1993
  • This paper presents the progress of the development of a nondestructive technique for the classification of normal, septicemic , and cadaver poultry carcasses by the Instrumentation and Sensing Laboratory at Beltsville, Maryland, U.S.A. The Sensing technique is based on the diffuse reflectance spectroscopy of poultry carcasses.

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Structural Properties of polyaniline blended with PNIPAM

  • Neupane, Kosh-Prasad;Ha, Jin-Wook
    • 한국산학기술학회:학술대회논문집
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    • 한국산학기술학회 2003년도 춘계학술발표논문집
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    • pp.334-336
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    • 2003
  • Polyaniline(PANi) composite panicles were synthesized by chemical oxidation polymerization of aniline in presence of Poly-N-Isopropyl acryl amide(PNIPAM). The PANi panicles are formed in the reaction medium deposited onto non-conducting PNIPAM template to produce PANi-coated composite panicles. The formation of composite was confirmed by FT-IR spectroscopy, and UV-VIS spectroscopy, and their morphological structures were examined by scanning electron microscopy(SEM). From the experimental results, it was determined that PANi was successfully coated onto non-conducting PANIPAM.

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Synthesis of Pentapeptide Containing DL-1-Aminobenzylphosphonic Acid

  • Hong, Suk-In;Kim, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • 제1권3호
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    • pp.114-115
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    • 1980
  • Six previously unreported peptides containing diethyl DL-1-aminobenzylphosphonate terminal unit were prepared. These are: Diethyl phthalyl-glycyl-gly-DL-1-aminobenzylphosphonate, diethyl gly-gly-DL-aminobenzylphosphonate, diethyl phthalyl-gly-gly-gly-DL-1-aminobenzylphosphonate , diethyl phthalyl-gly-gly-gly-gly-DL-1-aminobenzylphosphonate, diethyl phthalyl-DL-1-phenylalanyl-DL-1-aminobenzylphosphonate, diethyl phthalyl-gly-DL-phenylalanyl-DL-1-aminobenzylphosphonate. All the compounds were obtained as white crystalline powder and characterized by means of elemental analysis, IR spectroscopy, NMR spectroscopy, and ninhydrin test.

Preparation of polymeric nanoparticles from hydrophobically modified pullulan for hydrophobic drug carrier

  • Kim, In-Sook;Kim, Sung-Ho
    • 대한약학회:학술대회논문집
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    • 대한약학회 2002년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2
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    • pp.409.1-409.1
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    • 2002
  • For the development of a biocompatible nano-scale drug carrier. hydrophilic polysaccharide pullulan was hydrophobized by the conjugation with fatty acid. The synthesized polymers were characterized by the measurements of fourier transform infrared (FT -IR) spectroscopy and 1H -nuclear magnetic resonance (NMR) spectroscopy. In aqueous solution. hydrophobically modified puliulan was self-assembled and structured into the core-shell type nanoparticles. (omitted)

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