• Title/Summary/Keyword: IR drop

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Stripping of Asphalt Pavements and Antistripping Addities (도로포장 구조물에서의 스트리핑 현상과 스트리핑 방지제의 이용방안)

  • 윤현희
    • Journal of Korean Society of Transportation
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    • v.8 no.2
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    • pp.119-131
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    • 1990
  • Physico-chemical properties of asphalt, aggregate, and asphalt-aggregate mixture that might influence stripping were summarized in Table 1, based on the fundamental theories concerning stripping. It was found that although physical properties of aggregate affected stripping, there was no strong correlation between the physical properties of aggregate, such as pore volume and surface area, and the stripping propensity of the aggregate. Chemical and electrochemical properties of aggregate surface in the presence of water were most important factors for stripping. All mineral aggregates tested in this study imparted distinctive pH values to the contacting water and possessed distinctive electrochemical properties as measured by zeta potential. It was found that aggregates which had relatively higher surface potential in water and/or which imparted relatively higher pH to the contacting water were more susceptible to stripping. The functionalities contained in antistripping additives tested were primary and secondary amines and those of organic nitrogen compounds. The functionalities were determined by examining their infrared spectra. Based on the interfacial energy concept, the contact angle of an asphalt drop on an aggregate surface immersed in water related to the stripping propensity. The contact angle and stripping propensity were markedly reduced by the presence of an antistripping additive. In general, all the additives tested improved stripping resistance to some extent, depending on their concentration in the asphalts. The optimum dosage of an additive varied with different asphalts, as well as different aggregates. All antistripping additives tested in this study lost their effectiveness and failed to function to some extent when maintained for hours in a hot asphalt.

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Preparation of Porous Separators for Zn Air Batteries through Phase Inversions of Polyetherimide-PVP Solutions (Polyetherimide-PVP 용액의 상전이를 통한 아연공기전지의 다공성 분리막 제조)

  • Cho, Yu Song;Kim, Young Kyoung;Koo, Ja-Kyung
    • Membrane Journal
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    • v.24 no.3
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    • pp.231-239
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    • 2014
  • Polyetherimide (PEI) membranes for separators in Zn air batteries were prepared via phase inversion process from casting solution composed of PEI, n-methylpyrolidone (NMP), and polyvinylpurrolidone (PVP). Furthermore, Zn air batteries were fabricated with the separators. The effects of PEI content and PVP addition in the casting solution on the morphology, mechanical strength, ionic conductivity were investigated through SEM, stress-strain test and ac impedance test. The elelctrochemical performances of the batteries were evaluated through galvanostatic discharge analysis. The mechanical strength of the membrane increased with increasing PEI composition in the casting solution. Little effect of PVP addition into the solution on the mechanical strength of the membrane was investigated. The ionic conductivity value decreased with increasing PEI composition in the solution. With addition of PVP, ionic conductivity of membrane increased until 10 wt% to show the maximum value of 0.1 S/cm. In the higher range of PVP addition over 10%, the ionic conductivity decreased with increasing PVP addition. Ionic conductivity of separator strongly affected the capacity of Zn air battery, and the battery assembled with the separator which showed high ionic conductivity showed high capacity.

Reviewing the Explosively Deepening Cyclone(Cyclonic Bomb) over the East Sea with the Satellite Observations (위성관측에 의한 동해상의 폭발적 저기압의 고찰)

  • 정효상
    • Korean Journal of Remote Sensing
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    • v.12 no.2
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    • pp.126-138
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    • 1996
  • The characteristics of rapid development of the low pressure system over the East Sea from 06 to 08 Nov., 1995 has been analyzed in detail by the synoptic numerical products and satellite observations. The Low system was initially triggered the development of the baroclinic leaf cloud over the border of the northern part of Korea and China and moved eastward and then developed explosively com-ma or lambda type cloud system over the East Sea. To forecast well the general development and movement of the coastal winter cyclone over the East Sea popularly in a numerical simulation by several scientists, the large baroclinicity, continuous support of water vapor, and sequential cold outbreak over the warm sea surface have been more commonly concerned about. The cyclone which the central surface pressure was dropped 40hPa within 24 hours has often accompanied strong wind and heavy snow- or rain-fall in the winter season. In all successive observations with 12-hourly satellite imagery and analyzed meteorological variables in this period, the centers of the sea-level pressure and 500hPa geopotential height associated with this cyclone were typically illustrated by moving farther eastward using GMS combined enhanced IR images. The maxi-mum wind sustained by this system with the intensity and central pressure of tropical storm was about 60 knots with the center pressure drop of 44hPa/day similar to the North American cyclonic bomb and Atlantic storm.

Influence of Water-Cement Ratios and Curing Conditions on the Diffusion Characteristics of Chloride Ion in Concrete (콘크리트의 염소이온 확산특성에 미치는 물-시멘트비 및 양생조건의 영향)

  • Bae, Su-Ho;Lee, Kwang-Myong;Kim, Jee-Sang;Jung, Sang-Hwa
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4A
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    • pp.753-759
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    • 2006
  • To predict service life of concrete structures exposed to chloride attack, surface chloride concentration, diffusion coefficient of chloride ion, and chloride corrosion threshold value in concrete, are used as important factors. Of these, as the diffusion coefficient of chloride ion for concrete is strongly influenced by concrete quality and environmental conditions of structures and may significantly change the service life of structures, it is considered as the most important factor for service life prediction. The qualitative factors affecting the penetration and diffusion of chloride ion into concrete are water-cement (W/C) ratio, age, curing conditions, chloride ion concentration of given environment, wet and dry conditions, etc. In this paper the influence of W/C ratio and curing conditions on the diffusion characteristics of chloride ion in concrete was investigated through the chloride ion diffusion test. In the test, the voltages passing through the diffusion cell were measured by accelerated test method using potential difference, and then with the consideration of IR drop ratio the diffusion coefficient of chloride ion for concrete with different W/C ratios were estimated by Andrade's model. Furthermore, under different curing conditions formulas for the estimation of the diffusion coefficient of chloride ion have been proposed by the regression analysis considering the effect of W/C ratio and age.