• Journal of the Korean Society of Clothing and Textiles
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• v.43 no.4
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• pp.592-604
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• 2019

This study examines the stealth function of sputtered fabric with an infrared thermal imaging camera in terms of the thermal and infrared (IR) transmittance characteristics. Various base fabrics were selected, infrared imaging was performed, and infrared transmittance was measured. By infrared camera experiment it was found that the sample was concealed because it had a similar color to the surroundings when the aluminum layer was directed toward the outside. In addition, a comparison of the infrared thermographic image of the untreated sample and the sputtered sample in the laboratory showed that the difference in ${\Delta}E$ value ranged from 31 to 90.4 and demonstrated effective concealment. However, concealment was not observed in the case of the 3-layer (Nylon-Al-Nylon) model when a sputtered aluminum layer existed between two nylon layers. The direction of the sputtering layer did not affect the infrared transmittance in the infrared transmittance experiment. Therefore, it seems better to interpret the concealing effect in the infrared thermographic images by using thermal transfer theory rather than infrared transmittance theory. We believe that the results of this study will be applicable to developing high performance smart clothing and military uniforms.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.30 no.9
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• pp.577-582
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• 2017

The white light of a hybrid LED is obtained by using red and green organic fluorescent layers made of polymethylmethacrylate (PMMA) films, which function as color down-conversion layers of blue light-emitting diodes. In this research, we studied the fluorescence properties of a red organic fluorophore, employing perylene bisimide derivatives applicable to hybrid LEDs. The solubility, thermal stability, and luminous efficiency are important characteristics of organic fluorophores for use in hybrid LEDs. The perylene fluorescent compounds (1A and 1B) were prepared by the reaction of 4-bromophenol and 4-iodophenol with N,N'-bis(4-bromo-2,6-diisopropylphenyl)-1, 6,7,12-tetrachloroperylene-3,4,9,10-tetracarboxyl diimide (1) in the presence of dimethyl formaldehyde (DMF) at $70^{\circ}C$. The synthesized derivatives were characterized by using $^1H-NMR$, FT-IR, UV/Vis absorption and PL spectra, and TGA analysis. Compounds 1A and 1B showed absorption and emission at 570 nm and 604 nm in the UV/Vis spectrum. We also documented favorable solubility and thermal stability characteristics of the perylene fluorophores in our work. Perylene fluorophore 1, with the 4-bromophenol substituent 1A, exhibited particularly good thermal stability and solubility in organic solvents.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2013.10a
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• pp.283-285
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• 2013

피부의 관리를 위한 방법 중 광을 이용한 케어는 비침습적인 방법으로 세포를 활성화 시켜 도움을 주는 매우 유용한 방법이다. 최근에는 낮은 에너지의 LED를 광원으로 이용하는 LLLT (Low Level Light Therapy)가 많이 적용이 된다. 본 논문에서는 피부 미용기기에서 많이 사용되고 있는 가시광 영역의 적색과 황색, 그리고 적외선 영역의 LED를 이용하여 array를 제작하였다. 제작된 LED array는 5V의 전압과 50mA의 전류로 구동되며, 적색이 평균 $10.7mW/cm^2$, 황색이 평균 $1.8mW/cm^2$, 적외선이 평균 $5.5mW/cm^2$의 광출력을 갖는다. 이를 배양된 human cell plate에 각각 10, 20, 40분의 시간으로 조사하였으며, LED array와 조사면 사이에 20 mm의 거리를 두어 균일한 광량이 조사 될 수 있도록 하였다. 실험결과, wound healing의 경우는 적색광을 조사하였을 때, injury line의 길이가 $604.36{\mu}m$에서 10분 조사 시 $368.92{\mu}m$, 20분 조사 시 $298.04{\mu}m$, 40분 조사 시 $491.22{\mu}m$로 줄어드는 효과를 보였으며 특히 20분간 조사하였을 경우의 효과가 가장 좋았다. Cell regeneration의 경우는 황색광을 20분간 조사하였을 경우에 UV 에 의해 손상된 세포 수가 가장 크게 줄어드는 것을 확인할 수 있었다. 결과적으로 photorejuvenation 효과를 줄 수 있는 wound healing과 cell regeneration에는 적색 및 황색광의 LED array를 20분간 조사하였을 때가 가장 효과적이었으며, 적외광의 경우에는 모든 실험에서 효과가 없음을 확인할 수 있었다.

• Applied Chemistry for Engineering
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• v.3 no.4
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• pp.595-604
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• 1992

Carbonate-type polyurethane resins containing anionic moieties were systhesized from NCO-terminated prepolymer method. Membranes were manufactured from the polymer solution and the separation of aqueous ethanol solution was investigated. To enhance the property of urethane resin, carbonate-type polyol(PTMCG) was used. ${\alpha}^{\prime},{\alpha}^{{\prime}{\prime}}$-dimethylolpropionic acid was used as a chain extender to increase the hydrophilicily of the urethane membrane. The ionization of the pendent carboxylic groups in urethane resin was carried out using trimthylamine. To confirm the formation of anionic groups in urethane resin, IR spectra of model compounds were compared with those of urethane resins. It was confirmed that the concentration of hard segment and hydrogen bond contributed to the property of the concentration of hard segment and hydrogen bond contributed to the property of urethane resin in which the mole ratio of chain extender and polyol was from 3:1 to urethane resin in which the mole ratio of chain extender and polyol was from 3:1 to 5:1. The carbonate-type polyurethane containing pendent carboxylic grop(PU) had Tg of around-$25^{\circ}C$ and Tm, $45^{\circ}C$ measured by DSC. Transition temperatures of one containing pendent anionic group(APU) prepared from the ionization of PU shifted to $8{\sim}10^{\circ}C$ lower temperature region than those of PU. Pervaporation membrane was prepared through the casting method. N, N-dimethylformamide (DMF) were used as a solvent and hexamethylene diisocyanate(HMDl) as a crosslinking agent. Swelling degree increased with ethanol concentration in mixure and the control of the swelling degree of the membrane could be achieved by crossliking. The results of pervaporation were as follows : separation factor, 2.3~9.8 ; flux, $27{\sim}79.5g/m^2hr$. Pervaporation separation capacity could be enhanced by reducing the molecular weight of polyol from 2,000 to 1,000.