• 제목/요약/키워드: IPN

검색결과 136건 처리시간 0.032초

Advanced 'green' composites

  • Netravali, Anil N.;Huang, Xiaosong;Mizuta, Kazuhiro
    • Advanced Composite Materials
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    • 제16권4호
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    • pp.269-282
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    • 2007
  • Fully biodegradable high strength composites or 'advanced green composites' were fabricated using yearly renewable soy protein based resins and high strength liquid crystalline cellulose fibers. For comparison, E-glass and aramid ($Kevlar^{(R)}$) fiber reinforced composites were also prepared using the same modified soy protein resins. The modification of soy protein included forming an interpenetrating network-like (IPN-like) resin with mechanical properties comparable to commonly used epoxy resins. The IPN-like soy protein based resin was further reinforced using nano-clay and microfibrillated cellulose. Fiber/resin interfacial shear strength was characterized using microbond method. Tensile and flexural properties of the composites were characterized as per ASTM standards. A comparison of the tensile and flexural properties of the high strength composites made using the three fibers is presented. The results suggest that these green composites have excellent mechanical properties and can be considered for use in primary structural applications. Although significant additional research is needed in this area, it is clear that advanced green composites will some day replace today's advanced composites made using petroleum based fibers and resins. At the end of their life, the fully sustainable 'advanced green composites' can be easily disposed of or composted without harming the environment, in fact, helping it.

UV 경화형 키토산/지방족 폴리에스터 Hydrogel IPN 제조 및 약물투과 (Synthesis, Properties and Permeation of Solutes through Hydrogels based on Poly(ethylene glycol)-co-Poly(lactones) diacrylate Macromers and Chitosan)

  • 조성민;김소연;이영무;성용길;조종수
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1998년도 추계학술대회
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    • pp.229-230
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    • 1998
  • Triblock copolymers from poly(ethylene glycol) (PEG) and D,L-lactide or $\varepsilon$-carprolactone were synthesized to prepare semi-interpenetrating polymer network (semi-IPN) with chitosan by U.V. irradiation method. Then, solute permeation through these semi-IPNs hydrogels were investigated. The structures of semi-IPNs were confirmed by FT-IR spectroscopy and wide angle X-ray diffractometer (WAXD). Equilibrium water content (EWC) of these hydrogels was in the range of 67-75%. The crystallinity, thermal properties and mechanical properties of semi-IPNs hydrogels were studied. All the hydrogels revealed a remarkable decrease in crystallinity as compared with PEG macromer itself. The tensile strengths of semi-IPNs hydrogels in dry state were rather high, but those of hydrogels in wet state decreased drastically. The permeabilities of solutes of hydrogels followed the swelling behaviors and were regulated by solute size.

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First report of Gymnosporangium clavipes Cooke & Peck affecting Crataegus mexicana var. Chapeado and C. gracilior in Mexico

  • Alvarado-Rosales, D.;Nieto-Lopez, E.H.;Teliz-Ortiz, D.;Ayala-Escobar, V.;Silva-Rojas, H.V.;Nieto-Angel, R.;Leyva-Mir, S.G.;Jimenez-Nieto, A.;Mendez-Inocencio, C.
    • 식물병연구
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    • 제21권3호
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    • pp.250-252
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    • 2015
  • The tejocote (Crataegus spp.) is a tree considered to be native to Mexico. The aim of this study was to identify the causal agent of tejocote rust in the State of Puebla. Tejocote fruits were sampled in 2012 and 2013. The fungus was studied morphologically using light and scanning electron microscopy and molecularly using phylogenetic analysis of 18S and 28S rDNA genes. The fungus was identified as Gymnosporangium clavipes on tejocote fruits. To our knowledge, this is the first confirmed report of Gymnosporangium clavipes Cooke & Peck affecting Crataegus mexicana var. Chapeado and C. gracilior in Puebla Mexico.

Epoxy/Silicon Epoxy/Urethane계 IPN 복합재료의 개발에 관한 연구 (A study on the Dielectric Properties of IPN based on the Epoxy/Silicon and Epoxy/Urethane)

  • 신중흥;정은식;박정후
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1987년도 정기총회 및 창립40주년기념 학술대회 학회본부
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    • pp.504-507
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    • 1987
  • Interpenerating Polymer Networks (IPNs) are unique type of polymer blend, synthesized by swelling a crossed polymer (Epoxy) with second polymer (Silicon) and also we adopted Urethane as the second polymer. The relationship between dielectric and mechanical properties of high temperature curing IPNs(E/S, E/U) are investigated. The ratios of weight that we formed we re two kind of thing, one (E/S) about 1[wt%]. 3[wt%], 5[wt%], 7[wt%], 10[wt%], and the other (E/U) about 5[wt%], 15[wt%], 25[wt%]. It was heat-cured for 24hours at $100^{\circ}C$ 48 hours at $10^{\circ}C$, 5 hours at $130^{\circ}C$, 15hours at $130^{\circ}C$ in E/S and also for 5 hours at $130^{\circ}C$ in E/U. From the viewpoint of dielectric and mechanical properties, the optimum condition is obtained from the sample cured for 5hours at $130^{\circ}C$ for 1[wt%] in the E/S, and also obtained from the sample cure d for 5 hours at $130^{\circ}C$ in E/U.

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폴록사머-폴리아크릴산 IPNs의 약물 조절 방출 (Drug Release Control of Poloxamer-Poly(acrylic acid) Interpenetrating Polymer Networks)

  • 변은정;박주애;이승진;김길수
    • 약학회지
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    • 제41권1호
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    • pp.22-29
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    • 1997
  • Poloxamer-poly (acrylic acid) (PAA) interpenetrating polymer networks (IPNs) were prepared via matrix polymerization of acrylic acid with poloxamer prepolymer. The equilibrium s welling of poloxamer/PAA IPNs was determined in various pH medium. The swelling of poloxamer/PAA IPNs was more affected by pH difference compared with the swelling of homo PAA gel due to protonation and deprotonation of the PAA network, followed by reversible formation and dissociation of the interpolymer complex due to hydrogen bonding between acidic hydrogens and ether oxygens. Nonionic/anionic/cationic drugs were incorporated into IPN matriceds as a model drug and their release behavior was studied. Nonionic, drug revealed release patterns depending solely on pH dependent swelling kinetics. In contrast, the release of ionic drugs was significantly affected by ionic drug-polymer interaction as well as the swelling kinetics.

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Semi-interpenetrated Polymer Network of Sulfonated Poly(Styrene-Divinylbenzene-Acrylonitrile) based on PVC Film for Polymer Electrolyte Membranes

  • Yun, Sung-Hyun;Woo, Jung-Je;Seo, Seok-Jun;Park, Jung-Woo;Oh, Se-Hun;Moon, Seung-Hyeon
    • Korean Membrane Journal
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    • 제11권1호
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    • pp.8-14
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    • 2009
  • The sulfonated poly(styrene-divinylbenzene-acrylonitrile) (ST-DVB-AN) composite polymer electrolyte membrane based on the original PVC film was successfully synthesized to improve oxidative stability using semi-interpenetrated polymer network (semi-IPN). Weight gain ratio after copolymerization was enhanced by the DVB and AN contents, and the sulfonated membranes were characterized in terms of proton conductivity (k), ion exchange capacity (IEC), and water uptake ($W_U$). The effect of DVB content and AN addition were thoroughly investigated by comparing the resulted properties including oxidative stability. The obtained ST-DVB-AN composited semi-IPN membranes showed relatively high proton conductivity and IEC compared with Nafion117, and greatly improved oxidative stability of the synthesized membrane was obtained. This study demonstrated that a semi-interpenetrated sulfonated ST-DVB-AN composited membrane reinforced by PVC polymer network is a promising candidate as an inexpensive polymer electrolyte membrane for fuel cell applications.

FOOTPRINT AND MINIMUM DISTANCE FUNCTIONS

  • Nunez-Betancourt, Luis;Pitones, Yuriko;Villarreal, Rafael H.
    • 대한수학회논문집
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    • 제33권1호
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    • pp.85-101
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    • 2018
  • Let S be a polynomial ring over a field K, with a monomial order ${\prec}$, and let I be an unmixed graded ideal of S. In this paper we study two functions associated to I: The minimum distance function ${\delta}_I$ and the footprint function $fp_I$. It is shown that ${\delta}_I$ is positive and that $fp_I$ is positive if the initial ideal of I is unmixed. Then we show that if I is radical and its associated primes are generated by linear forms, then ${\delta}_I$ is strictly decreasing until it reaches the asymptotic value 1. If I is the edge ideal of a Cohen-Macaulay bipartite graph, we show that ${\delta}_I(d)=1$ for d greater than or equal to the regularity of S/I. For a graded ideal of dimension ${\geq}1$, whose initial ideal is a complete intersection, we give an exact sharp lower bound for the corresponding minimum distance function.

담관의 관내 유두상 종양에서 발생한 간 내 담관암 1예: 8년 간의 경과관찰 (A Case of Intraductal Papillary Neoplasm of the Bile Duct with 8 Years of Follow Up)

  • 전혜경;김동욱
    • Journal of Digestive Cancer Research
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    • 제2권2호
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    • pp.78-81
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    • 2014
  • 담관암은 예후가 불량한 암으로 전암성 병변의 병리, 임상적 특징, 예후 등의 이해가 중요할 것으로 생각된다. 관내 유두상 종양은 드문 질환으로 만성적인 담관의 염증이 동반되어 있는 환자에서 발생 위험이 증가하며 비교적 느리게 성장하고 덜 침습적인 특징이 있으나 악성 전환 가능성이 높은 질병이므로 첫 진단 시 조직학적으로 양성이라 하더라도 적극적인 치료를 고려하도록 권고하고 있다. 이에 질병의 자연경과에 대한 보고는 적어, 저자들은 치료없이 8년간 경과 관찰하여 담관암으로 진행한 담관내 유두상 종양 1예를 경험하였기에 문헌고찰과 함께 보고하는 바이다.

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