• 접착 및 계면
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• 제3권2호
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• pp.17-29
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• 2002

Micromechanical 시험법과 표면 젖음성 측정을 이용한 implant용 생분해성 복합재료의 계면물성과 미세파괴 분해 메카니즘을 연구하였다. 분해시간이 경과함에 따라서 poly(ester-amide) (PEA)와 생활성 유리섬유의 인장강도와 탄성률 그리고 신율은 점차적으로 감소하는 경향을 보인 반면, chitosan 섬유는 거의 변화가 없었다. 생활성 유리섬유와 poly-L-lactide(PLLA) 사이의 계면전단강도는 PEA나 chitosan 섬유 시스템의 경우보다 더 큰 값을 보였으나, 계면전단강도 감소 속도는 가장 빨랐고 chitosan 섬유의 경우가 가장 느린 결과를 보였다. 접착일 ($W_a$)은 생활성 유리섬유와 PLLA 사이에서 가장 높은 값을 나타냈으며, 이러한 표면 젖음성 결과는 계면전단강도 결과와 잘 일치하였다. 계면물성과 미세파괴 분해 메카니즘은 생분해성 복합재료의 성능을 조절할 수 있는 가장 중요한 요인들이다.

• 접착 및 계면
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• 제4권1호
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• pp.18-27
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• 2003

Micromechanical 시험법과 표면 젖음성 측정을 이용하여 플라즈마 처리된 생분해성 poly(p-dioxanone) (PPDO) 섬유강화 poly(L-lactide) (PLLA) 복합재료의 계면물성과 미세파괴 분해메카니즘을 연구하였다. PPDO 섬유강화 PLLA 복합재료는 장기간의 사용기간 동안 우수한 기계적 물성을 제공할 수 있다. PPDO 섬유와 PLLA 기지재료의 분해정도는 열분석과 광학적인 관찰을 통해서 확인하였다. PPDO 섬유와 PLLA 기지재료 사이의 계면전단강도와 접착일은 플라즈마 처리 시간이 60초 일때 가장 컸으며, 접착일과 polar 표면자유에너지는 계면전단강도와 비례하였다. 초기상태의 PPDO 섬유는 연성파단 형상이 나타났으나, 분해시간이 진행됨에 따라 분자량 감소로 인해 점차적으로 취성 파단 형상으로 변하였다. 계면물성과 미세파괴 분해메카니즘은 분해가 진행됨에 따라 변하기 때문에 섬유강화 생분해성 복합재료의 성능을 조절하는데 중요한 요인들이다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2000년도 춘계학술발표대회 논문집
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• pp.159-162
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• 2000

Interfacial and microfailure properties of carbon fiber/epoxy matrix composites were evaluated using both tensile fragmentation and compressive Broutman tests with acoustic emission (AE). Amino-silane and maleic anhydride polymeric coupling agents were used via the dipping and electrodeposition (ED), respectively. Both coupling agents exhibited higher improvements in interfacial shear strength (IFSS) under tensile tests than compressive cases. However, ED treatment showed higher IFSS improvement than dipping case under both tensile and compressive test. The typical microfailure modes including fiber break, matrix cracking, and interlayer failure were observed during tensile test, whereas the diagonal slippage in fiber ends was observed during compressive test. For both the untreated and treated cases AE distributions were separated well under tensile testing. On the other hand, AE distributions were rather closer under compressive tests because of the difference in failure energies between tensile and compressive loading. Under both loading conditions, fiber breaks occurred around just before and after yielding point. Maximum AE voltage fur the waveform of carbon or basalt fiber breakage under tensile tests exhibited much larger than those under compressive tests.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 춘계학술발표대회 논문집
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• pp.258-262
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• 2001

The contact resistivity was correlated with IFSS and microfailure modes in conductive fiber/cement composites electro-pullout and AE. As IFSS increased, the number of AE signals increased and the contact resistivity increased latter to the infinity. In dual matrix composite (DMC) test and AE, the number of signals with high amplitude and energy in g]ass fiber composite is significantly larger than that of no-fiber composite. Many vertical and diagonal cracks were observed in glass fiber and no-fiber composite under tensile test, respectively. Electro-micromechanical technique and AE can be used efficiently for sensitive nondestructive (NDT) evaluation and to detect microfailure mechanisms in various conductive fibers reinforced brittle and nontransparent cement composites.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 추계학술발표대회 논문집
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• pp.116-120
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• 2001

Fiber fracture is one of the dominant failure phenomena to determine total mechanical properties in composites. Fiber fracture locations were measured by optical microscopic method and acoustic emission (AE) as functions of matrix toughness and surface treatment by the electrodeposition (ED), and then two methods were compared. Two AE sensors were attached on the epoxy specimen and fiber fracture signals were detected with elapsed time. The interfacial shear stress (IFSS) was measured using tensile fragmentation test and AE system. In ED-treated case, the number of the fiber fracture measured by an optical method and AE was more than that of the untreated case. The signal number measured by AE were rather smaller than the number of fragments measured by optical method, since some fiber fracture signals were lost while AE detection. However, one-to-one correspondence between the x-position location by AE and real break positions by optical method was generally established well. The fiber break source location using AE can be a valuable method to measure IFSS for semi- or nontransparent matrix composites nondestructively (NDT).

• Macromolecular Research
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• 제9권1호
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• pp.20-29
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• 2001

Interfacial adhesion and nondestructive behavior of electrodeposited (ED) carbon fiber rein-forced composites were evaluated using electro-micromechanical techniques and acoustic emission (AE). The interfacial shear strength (IFSS) of the ED carbon fiber/epoxy composites was higher than that of the untreated fiber. This might be expected because of the possibility of chemical or hydrogen bonding in an electrically adsorbed polymeric interlayer. The logarithmic electrical resistivity of the untreated single-carbon fiber composite increased suddenly to infinity when fiber fracture occurred, whereas that of the ED composite increased relatively gradually to infinity. This behavior may arise from the retarded fracture time due to enhanced IFSS. In single- and ten-carbon fiber composites, the number of AE signals coming from interlayer failure of the ED carbon fiber composite was much larger than that of the untreated composite. As the number of the each first fiber fractures increased in the ten-carbon fiber composite, the electrical resistivity increased stepwise, and the slope of the logarithmic electrical resistance increased.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2004년도 추계학술발표대회 논문집
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• pp.92-95
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• 2004

Interfacial shear strength (IFSS) of environmentally- friend natural fiber reinforced polymer composites playa very important role in controlling the overall mechanical properties. In this work the IFSS of Ramie and Kenaf fibers/epoxy systems were evaluated using the combination of micromechanical technique, microdroplet test to find out an optimal condition in accordance with final purpose by comparing to each other. Clamping effect on fiber elongation was determined as well. In addition, the mechanical properties of the natural fibers were investigated using single fiber tensile test and analyzed statistically by both uni- and bimodal Weibull distributions. Microfailure modes of different natural fiber structures were observed using optical microscope.

• Macromolecular Research
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• 제10권1호
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• pp.24-33
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• 2002

Interfacial and microfailure properties of carbon fiber/epoxy composites were evaluated using both tensile fragmentation and compressive Broutman tests. A monomeric and two polymeric coupling agents were applied via the electrodeposition (ED) and the dipping applications. A monomeric and a polymeric coupling agent showed significant and comparable improvements in interfacial shear strength (IFSS) compared to the untreated case under both tensile and compressive tests. Typical microfailure modes including cone-shaped fiber break, matrix cracking, and partial interlayer failure were observed under tension, whereas the diagonal slipped failure at both ends of the fractured fiber appeared under compression. Adsorption and shear displacement mechanisms at the interface were described in terms of electrical attraction and primary and secondary bonding forces.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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• pp.109-113
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• 2002

Interfacial and electrical properties for the carbon fiber reinforced epoxy-amine terminated (AT) PEI composites were performed using microdroplet test and electrical resistance measurements. As AT PEI content increased, the fracture toughness of epoxy-AT PEI matrix increased, and IFSS was improved due to the improved toughness and energy absorption mechanisms of AT PEI. The microdroplet in the carbon fiber/neat epoxy composite showed brittle microfailure mode. At 15 wt% AT PEI content, ductile microfailure mode appeared because of improved fracture toughness. After curing, the changes of electrical resistance (ΔR) with increasing AT PEI content increased gradually because of thermal shrinkage. The matrix fracture toughness was correlated to IFSS, TEC and electrical resistance. In cyclic strain test, the maximum stress and their slope of the neat epoxy case were higher than those of 15 wt% AT PEI. The results obtained from electrical resistance measurements under curing process and reversible stress and strain were consistent well with matrix toughness properties.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 추계학술발표대회 논문집
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• pp.212-215
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• 2002

Interfacial evaluation and damage sensing of the carbon fiber/epoxy-amine terminated (AT)-polyetherimide (PEI) composites were performed using micromechanical test and electrical resistance measurement. As AT-PEI content increased, the fracture toughness of epoxy-AT-PEI matrix increased, and thus their interfacial shear strength (IFSS) was improved due to the improved toughness. After curing process, the changes in electrical resistance (ΔR) with increasing AT-PEI contents increased gradually because of the changes in thermal expansion coefficient (TEC) and thermal shrinkage of matrix. Matrix fracture toughness was correlated to the IFSS, residual stress and electrical resistance. The results obtained from the electrical resistance measurement during curing process, reversible stress/strain, and durability test were consistent with modified matrix toughness properties.