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Effect of Non-ionic Additive on Morphology and Gas Permeation Properties of Polysulfone Hollow Fiber Membrane (비이온계 첨가제에 의한 폴리술폰계 중공사 막의 모폴로지 조절과 기체투과 특성)

  • Lee, Hye Jin;Koh, Mi Jin;Kim, Duek Ju;Nam, Sang Yong
    • Membrane Journal
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    • v.22 no.3
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    • pp.224-233
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    • 2012
  • To improve permeation performance of gas separation membrane, polysulfone hollow fiber membrane was prepared by wet-dry phase inversion method using Triton X-100 as non-ionic additive. And variation of gas permeation behavior by additive was investigated. Various spinning conditions such as air gap, concentration of polymer, dope tank temperature were controlled and these effects were studied. The morphology and gas permeation property of hollow fiber membranes were investigated using scanning electron microscope (SEM) and bubble flow meter respectively. We confirmed that the membranes added with Triton X-100 had a smooth external skin at various air gap length conditions. The macrovoids of these hollow fiber membranes were more developed with increase of air-gap from 4 to 90 cm and that induced higher permeance. The permeance of polysulfone membranes has the higher value at comparatively lower concentration polymer (30 wt% polysulfone) and lower concentration of additive (15 wt% Triton X-100). When temperature in dope tank was controlled, the membranes prepared at $100^{\circ}C$ showed low permeance because of volatilization of additive and solvent.

Preparation and Properties of Chlorine-Resistance Loose Reverse Osmosis Hollow-fiber Membrane (내염소성 중공사형 역삼투막(Loose RO)의 제조 및 특성)

  • Kim, Se-Jong;Woo, Seung-Moon;Hwang, Hae-Yong;Koh, Hyung-Chul;Ha, Seong-Yong;Choi, Ho-Sang;Nam, Sang-Yong
    • Membrane Journal
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    • v.20 no.4
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    • pp.304-311
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    • 2010
  • In this study, loose RO hollow fiber membranes using CTA polymer were prepared by phase inversion method and their water purification properties were tested. 1,4-dioxane and LiCl was used as a skin layer formation agent and pore formation agent, respectively. Water flux, salt rejection, chlorine resistance, MWCO and membrane morphology were evaluated as a function of the dope composition. When the membrane prepared using the dope solution of CTA/NMP/1,4-dioxane = 18/72/10 (wt%) with air gap of 30 cm, it shows improved RO performance such as $20.5L/m^2hr$ of water flux, 60% of NaCl rejection, 10,000 ppm/hr of chlorine-resistance and around 5,000 Da of MWCO.

Structural Safety Analysis of Electric Kickboard According to Shape of Connection Parts Using Finite Element Analysis (유한요소해석 기반의 전동 킥보드 연결부 형상에 따른 구조적 안전성 분석)

  • Kim, Min Gyu;Kim, Jung Jin
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.12
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    • pp.65-70
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    • 2021
  • Electric kickboards are inviting attention as next-generation transportation systems with their number of users increasing rapidly every year. However, the number of related accidents similarly increases with the increase in the number of users. The purpose of this study is to analyze the structural safety of electric kickboards according to the shape of the connection parts. For this purpose, four different shapes of the connection parts, i.e., cube, cylinder, toroid, and divided cube were selected. Subsequently, the safety was analyzed based on the finite element (FE) analysis under the front collision scenario. The results showed that the shape of the divided cube induced the lowest von Mises stress and the highest safety factor amongst the four models. Moreover, only the shape showed a safety factor higher than 1. However, the shape of the cylinder exhibited the lowest structural vulnerability. These results demonstrate the importance of the shape of the connection part in maintaining the overall safety of an electric kickboard.

Effect of Sintering Temperature on Structural and Dielectric Properties of (Ba0.54Sr0.36Ca0.10)TiO3 Thick Films

  • Noh, Hyun-Ji;Lee, Sung-Gap;Nam, Sung-Pill;Lee, Young-Hie
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.2
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    • pp.49-52
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    • 2009
  • Barium strontium calcium titanate powders were prepared with the sol-gel method. Ferroelectric $(Ba_{0.54}Sr_{0.36}Ca_{0.1})TiO_3$(BSCT) thick films were fabricated by the screen-printing method on alumina substrate. Then we investigated the structural and dielectric properties of the BSCT thick films at different sintering temperatures. The thermal analysis showed that the BSCT polycrystalline perovskite phase formed at around $660^{\circ}C$. The X-ray diffraction analysis showed a cubic perovskite structure with no second phase present in all of the BSCT thick films. The average grain size and the thickness of the specimens sintered at $1450^{\circ}C$ were about $1.6{\mu}m$ and $45{\mu}m$, respectively. The relative dielectric constant increased and the dielectric loss decreased as the sintering temperature was increased; for BSCT thick films sintered at $1450^{\circ}C$ the values of the dielectric constant and the dielectric loss were 5641 and 0.4%, respectively, at 1 kHz.

A Surfactant-based Method for Carbon Coating of LiNi0.8Co0.15Al0.05O2 Cathode in Li Ion Batteries

  • Chung, Young-Min;Ryu, Seong-Hyeon;Ju, Jeong-Hun;Bak, Yu-Rim;Hwang, Moon-Jin;Kim, Ki-Won;Cho, Kwon-Koo;Ryu, Kwang-Sun
    • Bulletin of the Korean Chemical Society
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    • v.31 no.8
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    • pp.2304-2308
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    • 2010
  • A $LiNi_{0.8}Co_{0.15}Al_{0.05}O_2$ (LNCAO/C) active material composite cathode was coated with carbon. The conductive carbon coating was obtained by addition of surfactant during synthesis. The addition of surfactant led to the formation of an amorphous carbon coating layer on the pristine LNCAO surface. The layer of carbon coating was clearly detected by FE-TEM analysis. In electrochemical performance, although the LNCAO/C showed similar capacity at low C-rate conditions, the rate capability was improved by the form of the carbon coating at high current discharge state. After 40 cycles of charge-discharge processes, the capacity retention of LNCAO/C was better than that of LNCAO. The carbon coating is effectively protected the surface structure of the pristine LNCAO during Li insertion-extraction.

Design of an Adaptive Video-based Community in Ubiquitous Environment (유비쿼터스 환경에서 적응력있는 화상 커뮤니티의 설계)

  • Sung, Young-Hoon;Ha, Seok-Wun;Lee, Jae-Inn
    • Journal of The Korean Association of Information Education
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    • v.11 no.2
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    • pp.243-249
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    • 2007
  • Most homepages of schools are available to publicize activities of education, to load educational materials efficiently. But we can't use current homepages of schools in making characteristic information or sharing educational resources. In this study, this I-CUBE system with RSS was designed and embodied for sharing characteristic educational activities and works in schools. Currently, I-CUBE is being under experimental test for sharing education activities and making community in elementry schools,.

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Effect of Carbon Content of Sulfur Electrode on the Electrochemical Properties of Lithium/Sulfur Battery Using PEO Electrolyte (유황전극의 탄소량 변화에 따른 리튬/유황 전지의 방전특성 변화)

  • Kang, K.Y.;Ryu, H.S.;Kim, J.S.;Kim, K.W.;Ahn, J.H.;Lee, G.H.;Ahn, H.J.
    • Transactions of the Korean hydrogen and new energy society
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    • v.17 no.3
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    • pp.317-323
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    • 2006
  • Electric conductive material should be homogeneously mixed with sulfur in sulfur electrode fabrication of lithium/sulfur battery, because sulfur is electric insulator. In this paper electrochemical properties of Li/S battery was studied with various compositions of sulfur electrodes. When content of sulfur changed from 40 wt.% to 80 wt.%, the 60 wt.% sulfur electrode showed the maximum capacity of 1489 mAh/g-sulfur. Electrochemical properties of Li/S battery using 60 wt.% sulfur was also investigated with various carbon contents. The discharge capacity changed as a function of carbon contents. The optimum composition was 25 wt.% carbon for 60 wt.% sulfur electrode.

Effect of Si Contents on Structure and Mechanical Properties of Al-Si Alloy Metallic Foams (Al-Si 합금 발포금속의 조직 및 기계적 특성에 미치는 Si함량의 영향)

  • Kim, Byeong-Gu;Tak, Byeong-Su;Jeong, Seung-Reung;Jeong, Min-Jae;Hur, Bo-Young
    • Journal of Korea Foundry Society
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    • v.30 no.1
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    • pp.22-28
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    • 2010
  • Metal foam is a porous or cellular structure material and representative property is a very high porosity. Foamed materials have very special properties such as sound, vibration, energy and impact absorption capacity. Especially this properties are widely used for safety demands of architecture, auto and aircraft industry. But metal foam need to increased its compression strength and hardness. This study were researched about Al-Si alloy foams with variation amount of Si contents for their fabrication and properties such as porosity, cell structure, microstructure and mechanical properties. The result are that the range of pore size is 2~4 $mm{\phi}$, the high porosity are 88%, high yield strength is 1.8MPa, the strain ratio is 60~70% and vickers hardness is 33.1~50.6.

The Study on Fabrication and Sound Absorption Properties of Al-Zn-Mg-Cu Alloy Foams (Al-Zn-Mg-Cu 발포합금 제조 및 흡음특성에 관한 연구)

  • Jeong, Seung-Reung;Hur, Bo-Young
    • Journal of Korea Foundry Society
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    • v.31 no.3
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    • pp.145-151
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    • 2011
  • Metallic foam has been known as a functional material which can be used for absorption properties of energy and sound. The unique characteristics of Al foam of mechanical, acoustic, thermal properties depend on density, cell size distribution and cell size, and these characteristics expected to apply industry field. Al-Zn-Mg-Cu alloy foams was fabricated by following process; firstly melting the Al alloy, thickening process of addition of Ca granule to increased of viscosity, foaming process of addition of titanium hydride powder to make the pores, holding in the furnace to form of cooling down to the room temperature. Metal foams with various porosity level were manufactured by change the foaming temperature. Compressive strength of the Al alloy foams was 2 times higher at 88% porosity and 1.2 times higher at 92% porosity than pure Al foams. It's sound and vibration absorption coefficient were higher than pure Al foams and with increasing porosity.

Research and Development Trend of Pertraction Process using Membrane (분리막을 이용한 투과추출공정의 연구와 개발 동향)

  • Kim, Deuk Ju;Choi, Whee Moon;Nam, Sang Yong
    • Membrane Journal
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    • v.22 no.6
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    • pp.381-394
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    • 2012
  • Recently, a variety of chemical and physical methods are employed to separate ionic materials from complex aqueous. Most of all, membrane pertraction using contactor has been considered as alternative recovery and separation system in field of chemical, petrochemical and medicines because heavy metals, hydrocarbon based materials in contaminants like wastewater can be recovered by pertraction system. Also, pertraction process has characteristics such as ease of operation, lower energy consumption and operational cost, higher selectivity. This work investigates some example of developed membrane and their performance for the application of pertraction process.