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The effect of 4,4'-bis(N,N-diethylamino)benzophenone on the degree of conversion in liquid photopolymer for dental 3D printing

  • Lee, Du-Hyeong;Mai, Hang Nga;Yang, Jin-Chul;Kwon, Tae-Yub
    • The Journal of Advanced Prosthodontics
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    • v.7 no.5
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    • pp.386-391
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    • 2015
  • PURPOSE. The purpose of this preliminary study was to investigate the effects of adding 4,4'-bis(N,N-diethylamino) benzophenone (DEABP) as a co-initiator to a binary photoinitiating system (camphorquinone-amine) to analyze on the degree of conversion (DC) of a light-cured resin for dental 3D printing. MATERIALS AND METHODS. Cylindrical specimens (N=60, n=30 per group, ${\phi}5mm{\times}1mm$) were fabricated using bisphenol A glycerolate dimethacrylate (BisGMA) both with and without DEABP. The freshly mixed resins were exposed to light in a custom-made closed chamber with nine light-emitting diode lamps (wavelength: 405 nm; power: $840mW/cm^2$) for polymerization at each incidence of light-irradiation at 10, 30, 60, 180, and 300 seconds, while five specimens at a time were evaluated at each given irradiation point. Fourier-transform infrared (FTIR) spectroscopy was used to measure the DC values of the resins. Two-way analysis of variance and the Duncan post hoc test were used to analyze statistically significant differences between the groups and given times (${\alpha}$=.05). RESULTS. In the DEABP-containing resin, the DC values were significantly higher at all points in time (P<.001), and also the initial polymerization velocity was faster than in the DEABP-free resin. CONCLUSION. The addition of DEABP significantly enhanced the DC values and, thus, could potentially become an efficient photoinitiator when combined with a camphorquinone-amine system and may be utilized as a more advanced photopolymerization system for dental 3D printing.

Histogram Analysis in Separated Region for Face Contour Extraction under Various Environmental Condition (다양한 환경 조건에서의 얼굴 윤곽선 영역 검출을 위한 분할 영역 히스토그램 분석)

  • Do, Jun-Hyeong;Kim, Keun-Ho;Kim, Jong-Yeol
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.47 no.1
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    • pp.1-8
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    • 2010
  • Some methods employing the Active Contour Model have been widely used to extract face contour. Their performance, however, depends on the initial position of the model and the coefficients of the energy function which should be reconsidered whenever illumination and environmental condition of an input image is changed. Additionally, the number of points in the contour model should increase drastically in order to extract a fine contour. In this paper, we thus propose a novel approach which extracts face contour by segmenting the face region with threshold values obtained by a histogram analysis technique in the separated region of input image. The proposed method shows good performance under various illumination and environmental condition since it extracts face contour by considering the characteristics of the input image.

Characteristics of Pitch Production of Pyrolyzed Fuel Oil/Coal-tar Blending Feedstock by Thermal Polymerization Reaction (Pyrolyzed Fuel Oil/Coal-tar 혼합원료의 열중합 반응에 따른 Pitch 제조 특성)

  • Lee, Eunbyul;Kim, Hyeong Gi
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.328-333
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    • 2020
  • In this study, blended feedstock derived pyrolyzed fuel oil (PFO) and coal-tar was prepared to produce a pitch by thermal polymerization reaction for manufacturing artificial graphite materials. The aromaticity value of 0.355 and 0.818 was obtained for PFO and coal-tar, respectively. In addition, PFO and coal-tar exhibited the difference tendency of weight loss curve for thermogravimetric analysis, which is related to the structural stability depending on the aromaticity and functional groups. The production characteristics confirmed that the pitch derived PFO showed lower production yield and higher softening point than that using blended feedstock. In particular, when comparing P360 (138.5 ℃) and B420 (141.4 ℃) having similar softening points, the production yields of both pitches exhibited 29.89 and 49.03 wt%, respectively. This is mainly due to the blending of PFO and coal-tar having high pitch polymerization reactivity including a large amount of alkyl groups and coal-tar having high thermal stability. This phenomenon indicated that the increased production yield is because of a synergic effect of both the high reactivity of PFO and thermal stability of coal-tar.

A Machine Learning Model for Predicting Silica Concentrations through Time Series Analysis of Mining Data (광업 데이터의 시계열 분석을 통해 실리카 농도를 예측하기 위한 머신러닝 모델)

  • Lee, Seung Hoon;Yoon, Yeon Ah;Jung, Jin Hyeong;Sim, Hyun su;Chang, Tai-Woo;Kim, Yong Soo
    • Journal of Korean Society for Quality Management
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    • v.48 no.3
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    • pp.511-520
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    • 2020
  • Purpose: The purpose of this study was to devise an accurate machine learning model for predicting silica concentrations following the addition of impurities, through time series analysis of mining data. Methods: The mining data were preprocessed and subjected to time series analysis using the machine learning model. Through correlation analysis, valid variables were selected and meaningless variables were excluded. To reflect changes over time, dependent variables at baseline were treated as independent variables at later time points. The relationship between independent variables and the dependent variable after n point was subjected to Pearson correlation analysis. Results: The correlation (R2) was strongest after 3 hours, which was adopted as a dependent variable. According to root mean square error (RMSE) data, the proposed method was superior to the other machine learning methods. The XGboost algorithm showed the best predictive performance. Conclusion: This study is important given the current lack of machine learning studies pertaining to the domestic mining industry. In addition, using time series analysis in mining data will show further improvement. Before establishing a predictive model for the proposed method, predictions should be made using data with time series characteristics. After doing this work, it should also improve prediction accuracy in other domains.

Development of An User-Friendly Integrated Program and Teaching System for Automatic Polishing Robot System (자동 연마 시스템의 사용자 지향형 통합 프로그램 및 자동 교시 시스템 개발)

  • Go, Seok-Jo;Lee, Min-Cheol;Lee, Man-Hyeong;An, Jung-Hwan;Jeon, Cha-Su;Lee, Don-Jin
    • Journal of Institute of Control, Robotics and Systems
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    • v.7 no.4
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    • pp.334-343
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    • 2001
  • Polishing a die that has free-form surfaces is a time-consuming and tedious job, and requires a considerable amount of high-precision skill. Some workers tend to gradually avoid the polishing work because of the poor environment caused by dust and noise. In order to reduce the polishing time and cope with the shortage of skilled workers, a user-friendly automatic polishing system was developed in this research. The polishing system with five degrees of freedom is able to keep the polishing tool normal to the die surface. The polishing system is controlled by a PC-NC controller. To easily operate the developed polishing robot system, this study developed an integrated program in the Windows environment. This program consists of four modules: the polishing module, the graphic simulator, the polishing data generation module, and the teaching module. Also, the automatic teaching system was developed to easily obtain teaching data and it consists of a three dimensional joystick and a proximity sensor. The joystick is used to simultaneously drive the polishing system to an arbitrary orientation and the proximity sensor is used to obtain teaching points precisely. Also, to evaluate the stability of the driving program and the teaching system, polishing experiments of a die of saddle shape were carried out.

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A STUDY ON THE EFFECT OF ELECTRO-ACUPUNCTURE ON ORAL PAIN (전기침이 구강동통에 미치는 영향에 관한 연구)

  • Choi, Yong-Sung;Lee, Chang-Seop;Song, Hyeong-Geun;Lee, Sang-Ho
    • Journal of the korean academy of Pediatric Dentistry
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    • v.23 no.3
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    • pp.717-728
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    • 1996
  • The effects of electro-acupuncture on the pain threshold and the amplitude of dEMG(di-gastric EMG) evoked by the noxious electric stimulation on teeth and gingiva in dogs were studied. Experiments were carried out with 10 dogs weighing 5-8kg. Each animal was anestheticed with Entobar given intraperitoneally in an initial dose of 30mg/kg. Maintenance dose of 5mg/kg/hr was given through a cannula, in the femoral vein, as required to keep up light anesthesia. Bipolar stimulating wire electrodes, 0.1mm in diameter, insulated except for tips, were inserted into the upper canine and palatal gingiva. Rectangular aluminium plate electrodes (15$\times$5mm) were placed on acupuncture points, called Yin-Hsiang, located at both sides of the upper jaw. Rectangular biphasic current pulses of 2Hz, with a $250{\mu}sec$ duration, were delivered for 15 minutes. The dEMG activities were recorded from the anterior belly of the digastric muscle(one of the jaw opening muscles) using bipolar wire electrodes. The magnitude of the jaw opening reflex at different intensties of electro-acupuncture(1volt 4volt and 10volt) was estimated by averaging the 30 superimposed dEMGs recorded on an oscilloscope and audiomonitor. Data were analysed statistically with ANOV A and paired t-test. The obtained results were as follows: 1. Pain thresholds were increased 7.7 %, 15.4 %, 17.3 % in the teeth and 11.1 %, 19.0 %, 25.4 % in the gingiva as the intensities of electro-acupuncture increased incrementally. 2. Amplitudes of dEMG were decreaed 8.3%, 22.4%, 27.4% in the teeth and 9.8%, 36.5%, 42.2 % in the gingiva as the intensities of electro-acupuncture increased incrementally. 3. Inhibition of pain responses by the electroacupuncture was more effective in the gingiva than in the teeth.

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A Case Report on the Use of Korean Medicine Treatment for a Patient with Dysarthria Caused by Progressive Bulbar Palsy (PBP)

  • Ahn, Jae Hyun;Kim, Sung Yoon;Park, Jun Hyeong;Cho, Jeongjae;Choi, Do Young;Lee, Seung Hoon;Lee, Jae Dong
    • Journal of Acupuncture Research
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    • v.34 no.1
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    • pp.49-58
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    • 2017
  • Objectives : To introduce a rare case of a patient with Progressive Bulbar Palsy (PBP) and suggest the possibility of treatment using electroacupuncture and Korean Medicine. Methods : A 61-year-old man with PBP, complaining of dysarthria, was treated with electroacupuncture and Korean Medicine, from June 16 to July 10, 2015. Improvements in symptoms were measured using the speech mechanism screening test (SMST), measurement of tongue and orbicularis oris motility, and speech handicap index (SHI). Results : The scores of SMST, motility of tongue and orbicularis oris showed a tendency for gradual improvement with 25 days of Korean Medicine Treatment after admission, but conversation was still impossible. In SHI scores, one point increased in the speech domain and one point decreased in the psycho-social domain, and three points increased in the other domain. Conclusion : Electroacupuncture and Korean Medicine Treatment improved dysarthria caused by PBP, but not completely. Korean Medicine Treatment seems effective in the management of accompanying symptoms such as black hairy tongue, dry mouth, and general condition. The symptoms of PBP are similar to those of amyotrophic lateral sclerosis and there is controversy regarding the classification of PBP. The most important aspect of treating a patient with PBP is an early diagnosis and devising appropriate rehabilitation strategies.

Substrate Specificity of the Yeast Protein Tyrosine Phosphatase, PTP1, Overexpressed from an Escherichia coli Expression System

  • Kwon, Mi-Yun;Oh, Min-Su;Han, Jun-Pil;Cho, Hyeong-Jin
    • BMB Reports
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    • v.29 no.4
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    • pp.386-392
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    • 1996
  • A Saccharomyces cerevisiae Protein Tyrosine Phosphatase, PTP1, was expressed from an Escherichia coli expression system and milligram quantities of active PTP1 were purified chromatographically. The substrate specificity of the recombinant PTP1 was probed using synthetic phosphotyrosine-containing peptides corresponding to the regulatory phosphorylation sites of the yeast MAP kinase homologues $Fus3_{176-186}$, $Kss1_{179-189}$, and $Hog1_{170-180}$. Peptide sequences derived from the MAP kinase homologues were chosen arbitrarily as starting points for sequence variation studies even though they are not likely to be candidates for physiological substrates of PTP1. Phosphotyrosyl-$Hog1_{170-180}$ peptide showed a $K_M$ value of 877 ${\mu}M$ and phosphorylated $Kss1_{179-189}$ and $Fus3_{176-186}$ peptides showed lower $K_M$ values of 74 ${\mu}M$ and 51 ${\mu}M$ each. To study the effect of sequence variations of the peptide, amino acids of the undecapeptide $Hog1_{170-180}$ (DPQMTGpYVSTR) were sequentially substituted by an alanine residue. More extensive variations of each amino acid revealed positional importance of each amino acid residue. Based on these results, we derived a peptide sequence (DADEpYDA) that is recognized by PTP1 with an affinity ($K_M$ is 4 ${\mu}M$) significantly higher than that of the peptides derived from the phosphorylation sites of Fus3, Kss1, and Hog1.

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A Case Study on the Information Capacity Assessment Index of local Residents Using Score Card (스코어카드를 활용한 개인 및 지역정보화 수준 측정 사례연구)

  • Jeong, Hyeong-Chul;Cho, Young-Im
    • The Korean Journal of Applied Statistics
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    • v.21 no.6
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    • pp.1077-1091
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    • 2008
  • In this study, we consider to assess the information ability of individuals related to local information. Questionnaire surveys are frequently used for studies on the measuring of information index and such specified indexes of society development. However, if questionnaire papers measured individuals' abilities and such parts of quality, the subjective judgments of respondents cannot but be intervened. Therefore a method which will enable subjective points to be comparatively objectified is needed. In this study, when an attempt is being made to measure individuals' information capacity through questionnaire surveys as the process for calculating the standards of regional information levels. Cases have been looked at for times when, by using a scorecard, individuals' subjective survey result have been be changed to be comparatively objectified scores and such process. The logit model was used in the preparation of the scorecard. In this study, we have presented a clue which enables the comparative measurement about regional information gaps by using characteristics of regional population statistics.

Design Sensitivity Estimation of Injector Nozzle Hole Considering Cavitation (캐비테이션에 관한 인젝터 노즐 홀의 설계민감도 평가)

  • Yeom, Jeong Kuk;Ha, Hyeong Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.11
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    • pp.1361-1369
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    • 2013
  • This study performs a computational fluid dynamics (CFD) analysis of the inner flow of a multihole injector nozzle by using ANSYS CFX 13.0. Based on the obtained results, a design of experiment (DOE) was performed and applied to investigate the effects of injector nozzle design parameters on cavitation. To analyze the design sensitivity and signal-to-noise ratio (S/N ratio), the hole diameter, hole length, hole angle, and K-factor of the nozzle hole were selected as design parameters, and the effect of these parameters was investigated at 16 experimental points. Consequently, it was found that the effect of the K-factor on the cavitation and inner flow of the injector nozzle is the greatest. Thus, the selection of a suitable K-factor is important in nozzle design considering cavitation flow.