• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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• pp.26-29
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• 2001

Sorption/desorption Study was conducted to determine desorption-resistance hydrophobic organic compounds in natural soils with low organic carbon content. Sorption/desorption characteristics of chlorobenzene and phenanthrene for both PPI (Petro Processors, Inc. Superfund site) and BM (Bayou Manchac), soils were investigated. Desorption was biphasic including reversible and desorption-resistant compartments. The biphasic sorption parameters indicated the presence of appreciable size of desorption-resistant phase in these soils. A finite maximum capacity of desorption-resistant fraction (equation omitted) was observed after several desorption steps. The apparent organic carbon based Partition coefficient, K(equation omitted) was 10$^{4.92{\pm}0.27}$ for PPI soil and 10$^{4.92{\pm}0.27}$ for BM soil, respectively. The difference in K(equation omitted) was attributed to different characteristics in soil organic matter. The results suggest that desorption-resistance should be considered in remediation and risk assessments in natural soils and sediments.

• Environmental Engineering Research
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• 제7권2호
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• pp.93-101
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• 2002

The seasonal patterns of dissolved organic matter (DOM) in Lake Kasumigaura, a shallow, eutrophic lake, and serveral DOM sources in its catchment area were investigated. DOM was fractionated using three resin adsorbents into classes: aquatic humic substances (AHS=humic acid+fulvic acid), hydrophobic neutrals (HoN), hydrophilic acids (HiA), bases (BaS) and hydrophilic neutrals (HiN). The DOM produced significantly different fraction distributions depending on the origin of sample. AHS and HiA prevailed over AHS in the lake while AHS and HiA existed at almost the same concentration levels in the rivers. AHS seems to be a more dominant component in rever water than lake water. The dominance of organic acids was also observed in the DOM sources: forest stream (FS), plowed field percolate (PFP), domestic sewage (DS) and sewage treatment plant effluent (STPE).

• Archives of Pharmacal Research
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• 제28권6호
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• pp.667-674
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• 2005

The leaves of Persimmon (Diospyros kaki L.) has long been used for tea in Korea since it was thought to be effective against hypertension. An anticoagulant fraction was purified through gel filtration G-100, hydrophobic, gel filtration G-150, and FPLC, Phenyl superpose column chromatographies. The purified fraction was homogenous and its Mr was estimated 10,000 Da by gel filtration and SDS-PAGE. The purified fraction was sensitive to treatment of subtilisin B, but not to heat and its activity was not changed after periodate oxidation, indicating that the activity was not due to carbohydrates. It delayed thrombin time (TT), activated partial thromboplastin time (APTT), and prothrombin time (PT) using human plasma. TT was more sensitive than APTT and PT, suggesting that the anticoagulant activity may be caused by a degradation or a defect of fibrin or thrombin. It did not cause the hydrolysis of fibrin after incubation. However, it inhibited thrombin-catalyzed fibrin formation with a competitive inhibition pattern. These results indicate that it may be an antithrombotic agent and that it is bound to fibrinogen binding sites of thrombin.

• 자연과학논문집
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• 제8권2호
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• pp.21-26
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• 1996

시중에서 판매하는 중국산 옻칠을 그대로 혹은 유기용매에 녹는 부분과 녹지 않는 부분으로 분리하고 각각의 경화현상을 연구하였다. 그대로 사용하는 경우에는 상온에서 수분이 포화된 상태에서 경화를 관찰하였으며 유기용매로 분리한 부분의 경화는 섭씨 $100^{\circ}C$와 $150^{\circ}C$에서 경화를 관찰하였다. 서로 다른 방법으로 얻어낸 도막의 성질을 서로 비교하였으며 옻 중 유기용매에 녹는 부분과 1,6-diisocyanohexane, toluendiisocyanate(TDI)를 공중합하였을 때 얻어지는 도막과 다른 도막과의 성질로 비교하였다. 가열하여 형성된 도막은 매우 깨어지는 성질(취성)이 매우 높았으며 자연상태로 경화된 도막에 비하여 친수성이 낮았다. Diisocyanate를 사용하지 않은 경우에는 경화에 산소가 필수적이어서 오랜 시간이 지나도 내부는 경화가 되지 않았다.

• 한국지반환경공학회 논문집
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• 제2권1호
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• pp.103-114
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• 2001

본 연구에서는 근래에 퇴적된 습지토양의 유기물질에 느린 흡착부분이 존재하는지 살펴보기 위해 흡착실험을 행하였다. 최근 퇴적된 민물 습지토양에서의 소수성 유기화합물 (chlorobenzene and phenanthrene)의 흡착 특성을 회분식 흡착법을 사용하여 결정하였다. 유기물질의 나이의 상대 척도로서 산소/탄소 원소비 등을 포함한 여러 방법으로서 평가하였다. 토양의 나이가 유기화합물의 습지토양에서의 흡착에 차이를 유발하는지에 대해 조사하기 위하여 습지 토양의 표층부(상층부 0-2cm, 5년 미만)과 하층부(below 10cm, 20년 이상)에 대한 느린 흡착 특성을 상대적으로 오래된 PPI(Petro Processors, Inc. Superfund site), BM(Bayou Manchac) 토양과 비교하였다. 느린 흡착모델 변수의 비선형성(KF와 N)의 증가로서 느린 흡착부분이 존재함을 알 수 있었다. 느린 흡착모델의 분석결과 상당한 크기의 느린 흡착부분이 존재하였으며 습지 토양의 경우 흡착된 chlorobenzene의 25.4-263%가 phenanthrene의 경우 흡착된 양의 1.4-1.9%(phenanthrene)가 각각 느린 흡착 부분에 해당하였으며, PPI 토양과 BM토양의 경우 흡착된 chlorobenzene의 40.0-55.93%와 흡착된 phenanthrene의 2.9-3.19%가 각각 느린 흡착 부분에 해당하였다. 느린 흡착 부분은 상층부 < 하층부 < PPI < BM 토양의 순으로 증가하였는데 이것은 토양 유기물질의 나이가 증가할수록 느린 흡착부분의 크기가 증가함을 나타낸다.

• 한국생물물리학회:학술대회논문집
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• 한국생물물리학회 1999년도 학술발표회 진행표 및 논문초록
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• pp.45-45
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• 1999

Cytochrome c (cyt c) binds to acidic membranes at low ionic strength. Replacement of Lys-72 or Lys-87 by Glu reduced the binding affinity of cyt c toward large unilamellar vesicles (LUV) in liquid crystalline phase. The differences were smaller for LUV in gel phase. A fraction of bound cyt c was non-electrostatically associated.(omitted)

• Bulletin of the Korean Chemical Society
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• 제9권4호
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• pp.209-212
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• 1988

The hydrophobic interaction leading to the formation of ion-pair between $MB^+$ and $TPB^-$ was investigated spectroscopically by varying the medium with the addition of 1,A-dioxane or urea. Beyond 0.01 mole fraction of 1,A-dioxane in water or above 2.0M urea the ion-pair appeared to be completely dissociated into individual ions. The ion-pair was not observed in common organic solvents and the absorption maxima of $MB^+$ were correlated relatively well with the ${\pi}^{\ast}$-scale.

• Korean Membrane Journal
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• 제7권1호
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• pp.51-57
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• 2005

Pervaporation with a membrane is one of the economic technologies for separation of liquid mixtures including organic/water mixtures. The ZSM-5 membrane was used fur pervaporation of dichloromethane, 1,2-dichloroethane and trans-1,2-dichloroethylene from their aqueous solutions since its physical property shows very hydrophobic. ZSM-5 crystals were hydrothermally grown and deposited on the inside of a porous sintered stainless steel tube by the secondary growth method. Fluxes of dichlorinated organic compounds were observed to be $50{\~}429\;g/m^2/h$ while separation factors were $15{\~}320$ depending on a mole fraction of a dichlorinated organic compound in a feed solution ranged from 0.0001 to 0.001 mole fraction and the operation temperature between $25^{\circ}C\;and\;35^{\circ}C$.

• Journal of Applied Biological Chemistry
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• 제51권1호
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• pp.36-44
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• 2008

Organic forms of arsenic (As) were determined through fractionation procedure of soil organic matter (SOM) in soil, sediments and mine tailing samples from the Myungbong, Dongil, and Okdong mining areas of southern Korea. An alkaline extraction method was applied to soil samples followed by the fractionation procedures of SOM by the DAX-8 and XAD-4 resin adsorption method. Major fraction of organic As species (42% to 98%) was found in acid-soluble fraction, whereas minor fraction (0.1 % to 67.8%) was present in the humic-associated As. In acid-soluble fractions, the transphillic- and hydrophilic-associated As were dominant in addition to As binding with humic and fulvic SOM. Arsenic binding was the strongest between pH 6 to 8 and reduced to about 70% at both low and high pH regions. The amount of both transphillic and hydrophillic associated As was less changed than humic and fulvic-associated As, in both low and high pH regions. This apparently indicates that As has stronger affinity towards hydrophillic rather than hydrophobic organics. From the experimental observation of As-binding SOM in natural soil, the ligand exchange model may be a feasible explanation of transphillic and hydrophillic affinity of As.

• 분석과학
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• 제13권3호
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• pp.269-276
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• 2000

역상액체크로마토그래피에서 7종의 벤조산의 머무름에 대해서 연구하였다. 벤조산의 불감시간 측정은 무기염이 적당하였다. 로그 용량인자(log k')와 Hildebrand의 용해인자(${\delta}$)는 직선관계를 가지며 머무름 메카니즘이 소용매성 효과에 영향을 받는다. 용질의 전이 엔탈피는 온도증가 그리고 이동상에서 유기변형제의 비와 반비례 관계를 가진다. 이동상에서 물의 부피분율과 log k'의 관계로부터 얻은 기울기인 S값은 양의 값을 가진다. 자유에너지 변화는 유기변형제의 부피분율의 증가와 비례한다. 소수성지표 ${\varphi}_0$은 컬럼의 온도와 반비례한다.