• Journal of the Korean Society of Safety
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• v.27 no.3
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• pp.111-116
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• 2012

This study is about the quantitative safety assessment of hydrogen station in Korea operating with on-site type. This was written by background information that before qualitative safety assessment to write. For the qualitative safety assessment method, the study used FMEA(failure mode & effect analysis) and HAZOP(hazard & operability), and adopted the FTA(fault tree analysis) as the quantitative safety assessment method. To write the FTA, we wrote FT by Top event that hydrogen leakage can be called most serious accident of hydrogen station. Each base event collect reliability data by reliability data handbook, THERP-HRA and estimation of the engineering. Assessment looked at the high frequency and the possible risk through Gate, Importance, m.cutsets analysis.

• Journal of Energy Engineering
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• v.23 no.4
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• pp.223-229
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• 2014

This study investigated the explosion characteristics of HCNG fuel using a simulation tool. The damage caused by the storage container explosion and vapor cloud explosion in a gas station was predicted. In case of an vapor cloud explosion in the HCNG station, 50~200kPa explosion pressure was predicted inside the station. When the cylinder explosion was occurred, in case of hydrogen, the measured influential distance of overpressure was 59m and radiant heat was 75m. In case of CNG, influential distance of overpressure was 89m and radiant heat was 144m would be estimated. In case of 30% HCNG that was blended with hydrogen and CNG, influential distance of overpressure was 81m and radiant heat was 130m were measured. The damage distance that explosive overpressure and radiant heat influenced CNG was seen as the highest. HCNG that was placed between CNG and hydrogen tended to be seen as more similar with CNG.

• Nuclear Engineering and Technology
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• v.47 no.1
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• pp.33-46
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• 2015

During the past 10 years, the Korea Atomic Energy Research Institute (KAERI) has performed a study to control hydrogen gas in the containment of the nuclear power plants. Before the Fukushima accident, analytical activities for gas distribution analysis in experiments and plants were primarily conducted using a multidimensional code: the GASFLOW. After the Fukushima accident, the COM3D code, which can simulate a multidimensional hydrogen explosion, was introduced in 2013 to complete the multidimensional hydrogen analysis system. The code validation efforts of the multidimensional codes of the GASFLOW and the COM3D have continued to increase confidence in the use of codes using several international experimental data. The OpenFOAM has been preliminarily evaluated for APR1400 containment, based on experience from coded validation and the analysis of hydrogen distribution and explosion using the multidimensional codes, the GASFLOW and the COM3D. Hydrogen safety in nuclear power has become a much more important issue after the Fukushima event in which hydrogen explosions occurred. The KAERI is preparing a large-scale test that can be used to validate the performance of domestic passive autocatalytic recombiners (PARs) and can provide data for the validation of the severe accident code being developed in Korea.

• Journal of the Korean Institute of Gas
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• v.8 no.4 s.25
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• pp.55-61
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• 2004

This paper provided a counter measures against the troubles and accidents that are likely to take place in the power plant using hydrogen gas as a coolant for the cooling system of the generator. Because of the extremely wide flammability limits of hydrogen in comparison to the other flammable gases, the safety measures against the hydrogen accidents is very important to ensure the normal operation of electric-power facility. This study's purpose was a presentation of standard model of safety management of hydrogen equipments in the coal firing power plant such as following items: 1) providing the technical prevention manual of the hydrogen explosions and hydrogen fires occurring in the cooling system of power generator; 2) the selection of explosion-proof equipments in terms of the risk level of operating environment; 3) the establishment of regulations and counter measures, such as the incorporation of gas leakage alarm device, for preventing the accidents from arising, 4) the establishment of safety management system to ensure the normal operation of the power plant.

• Journal of the Korean Institute of Gas
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• v.17 no.5
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• pp.15-21
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• 2013

This study evaluated comparison of the risk according to the type of fuel by three-dimensional simulation tool(FLACS). The consequence analysis of fire explosion and jet-fire was carried out in the layout of a typical high-pressure gas filling stations using CNG, hydrogen and 30%HCNG. Under the same conditions, hydrogen had a 30kPa maximum overpressure, CNG had a 0.4kPa and HCNG had a 3.5kPa. HCNG overpressure was 7.75 times higher than the CNG measurement, but HCNG overpressure was only 11.7% compared to hydrogen. In case of flame propagation, hydrogen had a very fast propagation characteristics. On the other hand, CNG and HCNG flame propagation velocity and distance tended to be relatively safe in comparison to hydrogen. The estimated flame boundary distance by jet-fire of hydrogen was a 5.5m, CNG was a 3.4m and HCNG was a 3.9m.

• Safety and Health at Work
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• v.11 no.1
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• pp.109-117
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• 2020

Background: Ammonia and hydrogen sulfide are harmful gases generated during aerobic/anaerobic bacterial decomposition of livestock manure. We evaluated ammonia and hydrogen sulfide concentrations generated from workplaces at livestock farms and determined environmental factors influencing the gas concentrations. Methods: Five commercial swine farms and five poultry farms were selected for monitoring. Real-time monitors were used to measure the ammonia and hydrogen sulfide concentrations and environmental conditions during the manure-handling processes. Monitoring was conducted in the manure storage facility and composting facility. Information on the farm conditions was also collected through interview and walk-through survey. Results: The ammonia concentrations were significantly higher at the swine composting facilities (9.5-43.2 ppm) than at other manure-handling facilities at the swine and poultry farms, and high concentrations of hydrogen sulfide were identified during the manure agitation and mixing process at the swine manure storage facilities (6.9-19.5 ppm). At the poultry manure-handling facilities, the ammonia concentration was higher during the manure-handling processes (2.6-57.9 ppm), and very low hydrogen sulfide concentrations (0-3.4 ppm) were detected. The air temperature and relative humidity, volume of the facility, duration of manure storage, and the number of animals influenced the gas concentrations. Conclusion: A high level of hazardous gases was generated during manure handling, and some levels increased up to risk levels that can threaten workers' health and safety. Some of the farm operational factors were also found to influence the gas levels. By controlling and improving these factors, it would be possible to protect workers' safety and health from occupational risks.

• Journal of the Korean Institute of Gas
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• v.27 no.4
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• pp.70-77
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• 2023

In response to climate change, each country is proposing a goal to reduce greenhouse gases in its energy supply and demand plan, and the use of hydrogen gas is a topic that is always prioritized as an energy resource for implementation. A popular way to use this hydrogen gas is the use of hydrogen fuel cell vehicles, and expansion of hydrogen charging stations is essential for using these hydrogen fuel cell vehicles. However, there are several limitations to the expansion of hydrogen refueling stations, the most representative of which is resident acceptance. Most of the hydrogen charging stations currently built in Korea are located in the outskirts with low population density, so the inconvenience to hydrogen fuel cell vehicle users has not been resolved, and as a result, there has been no progress in the spread of hydrogen fuel cell vehicles. In this paper, we analyzed the consequences of accident damage to determine the risks of constructing a hydrogen charging station on a railroad site frequently used by citizens. The target hydrogen charging station site was a railroad depot in Busan, and there are trains, national highways, and commercial facilities around this site. Assuming the worst-case scenario, we would like to consider the safety of the hydrogen refueling station site by analyzing the area affected by the accident and its consequence.

• Toxicological Research
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• v.18 no.1
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• pp.13-22
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• 2002

In Korea, 2,320 tonnes of acetanilide were mostly wed as intermediates for synthesis in phar-maceuticals or additives in synthesizing hydrogen peroxide, varnishes, polymers and rubber. Only small amount of 120 kg were wed as a stabilizer for hydrogen peroxide solution for hair colouring agents in 1998. Readily available environmental or human exposure data do not exist in Korea at the present time. However, potential human exposures from drinking water, food, ambient water and in work places are expected to be negligible because this chemical is produced in the closed system in only one company in Korea and the processing factory is equipped with local ventilation and air filtering system. Acetanilide could be distributed mainly to water based on EQC model. This substance is readily biodegradable and its bioaccumulation is low. Acute toxicity of acetanilide is low since the L $D_{50}$ of oral exposure in rats is 1,959 mg/kg bw. The chemical is not irritating to skin, but slightly irritating to the eyes of rabbits. horn repeated dose toxicity, the adverse effects in rats were red pulp hyperplasia of spleen, bone marrow hyperplasia of femur and decreased hemoglobin, hematocrit and mean corpuscular hemoglobin concentration. The LOAEL for repeated dose toxicity in rats was 22 mg/kg/day for both sexes. Acetanilide is not considered to be genotoxic. In a reproductive/developmental toxicity study, no treatment-related changes in precoital time and rate of copulation, impregnation, pregnancy were shown in all treated groups. The NOAELs for reproduction and developmental toxicity (off-spring toxicity) are considered to be 200 mg/kg bw/day and 67 mg/kg bw/day, respectively. Ecotoxicity data has been generated in a limited number of aquatic species of algae (72 hr- $E_{b}$ $C_{50}$; 13.5 mg/l), daphnid (48hr-E $C_{50}$ > 100 mg/l) and fish (Oryzias latipes, 96hr-L $C_{50}$; 100 mg/l). Form the acute toxicity values, the predicted no effect concentration (PNEC) of 0.135 mg/1 was derived win an assessment factor of 100. On the basis of these data, acetanilide was suggested as currently of low priority for further post-SIDS work in OECD.in OECD.D.

• Restorative Dentistry and Endodontics
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• v.49 no.2
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• pp.14.1-14.13
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• 2024

This study aimed to answer the question through a systematic review: Can carbamide peroxide be as effective as hydrogen peroxide and cause less in-office bleaching sensitivity? A literature survey was performed in PubMed/MEDLINE, Embase, Scopus, ISI Web of Science, and gray literature. Primary clinical trials that compared the efficacy or the in-office bleaching sensitivity between carbamide and hydrogen peroxides were included. The risk of bias was evaluated using the RoB2. The certainty of the evidence was assessed using the GRADE approach. DPI training significantly improved the mean scores of the dental undergraduates from 7.53 in the pre-DPI-training test to 9.01 in the post-DPI-training test (p < 0.001). After 6 weeks, the mean scores decreased marginally to 8.87 in the retention test (p = 0.563). DPI training increased their confidence level from 5.68 pre-DPI training to 7.09 post-DPI training. The limited evidence suggests that the 37% carbamide peroxide may be similarly effective to the 35% hydrogen peroxide for bleaching teeth in-office and causes less bleaching sensitivity. However, more well-designed split-mouth clinical trials are necessary to strengthen the evidence.

• Journal of the Korea Safety Management & Science
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• v.26 no.3
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• pp.39-49
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• 2024

This study aims to propose an improvement of fire safety management plans for buildings, such as apartment complexes and schools, within a 10 km radius of industrial complexes. It utilizes an off-site consequence analysis program to reflect the toxic impact on national industrial complexes and surrounding areas. The ALOHA program was utilized to analyze the impact of toxicity due to a hydrogen chloride leak, a hazardous material. The results showed that the area with AEGL-2 and above ranged from 3.1 km to 10 km, the AEGL-3 area ranged from 1.9 km to 7.3 km. The ASET was measured to be between 3 and 24 minutes. Due to the impact of toxicity, it is necessary to prepare fire safety management plans for buildings, such as apartment complexes and schools that are within a 10 km radius from industrial complexes. These safety plans incorporate the hydrogen chloride risk assessment results, ASET, weather conditions, and coordination with the local community.