• Title/Summary/Keyword: Hydrogen quality

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A Study on the effect of the multi-pass SMAW welding on the characteristic of the underwater welding areas (SMAW 수중 다층용접시 용접부 특성에 관한 연구)

  • 최기용;이상율;이보영;이병훈;이상용;박성두
    • Journal of Welding and Joining
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    • v.16 no.4
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    • pp.55-62
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    • 1998
  • While excellent joint quality has been obtained using dry chamber underwater welding methods, the size limitations imposed by this process restrict its use for underwater construction work. The wet underwater shielded metal-arc welding eliminates this restriction but suffers from poor weld properties by the 1-pass bead-on-plate welding due to the excessive diffusible hydrogen. On the other hand, in the wet underwater welding, it is well known that the quantity of diffusible hydrogen in multi-pass welded parts reduce to less than that in 1-pass welded parts. Therefore, in this paper, welding experiments are made the 3-pass bead-on-plate welds by using TMCP and normalized steel plates and E4301 and cellulose coated electrode. After that, The amounts of the hydrogen absorbed into the 3-pass welded area were measured according to the JIS Z 3118 specification. The microstructural changes as well as the microhardness distribution after the underwater 3-pass welding were also investigated using Vickers microhardness tester and S.E.M and O.M. The results indicated that the quantity of diffusible hydrogen in 3-pass welded areas was reduced little less than a half of one of that in 1-pass welded areas at the specific welding condition. As a result, the cold cracking of 3-pass welded areas decreased by reduced effect of diffusible hydrogen. In the underwater 3-pass welding, the micrography of cold cracking fracture surface showed mainly the cleavage of hydrogen embrittlement.

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Development of Welding Flux and Process for Prevention of Cold Cracking in SAW Weld Metal (잠호용접부 균열방지를 위한 용접 플락스 및 시공기법 개발)

  • Choi, Kee-Young;Kim, Chan;Kim, Young-Pil
    • Special Issue of the Society of Naval Architects of Korea
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    • 2007.09a
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    • pp.118-127
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    • 2007
  • SAW(Submerged Arc Welding) process is generally applied to a wide range of welding area in the fabrication of steel structure. This process has a good characteristic properties such as the high quality of welds and the high deposition rates, but in case of welding on a thick steel plate, it also has higher cold crack susceptibility than that of a thin steel plate. The purpose of this research is to find the main factor of crack generation and clarify the countermeasure for crack prevention, and then establish the optimum welding condition in a heavy thick steel plate. The results of this study are as follows, 1. The cause of crack generation is found the diffusible hydrogen penetrated into weld metal by decomposition of the remained moisture in SAW flux during welding. 2. For the removal of diffusible hydrogen, the raw materials of SAW flux are to be dehydrated at the high temperature in the initial manufacturing stage. 3. Mechanical properties of weld metal welded with the dehydrated SAW flux were evaluated very excellent, furthermore the weld metal has been proved to have low diffusible hydrogen content with 3.1ml /100g. 4. The weldability and quality welded with thick steel plates were improved by establishing the new optimum welding condition.

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Fabrication and Performance Evaluation of MEMS Methanol Reformer for Micro Fuel Cells (마이크로 연료전지용 MEMS 메탄올 개질기의 가공과 성능시험)

  • Kim, Tae-Gyu;Kwon, Se-Jin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.12 s.255
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    • pp.1196-1202
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    • 2006
  • A MEMS methanol reformer was fabricated and its performance was evaluated in the present study. Catalytic steam reforming of methanol was selected because the process had been widely applied in macro scale reformers. Conventional Cu/ZnO catalyst that was prepared by co-precipitation method to give the highest coating quality was used. The reactor structure was made by bonding three layers of glass wafers. The internal structure of the wafer was fabricated by the wet-etching process that resulted in a high aspect ratio. The internal surface of the reactor was coated by catalyst and individual wafers were fusion-bonded to form the reactor structure. The internal volume of the microfabricated reactor was $0.3cm^3$ and the reactor produced exhaust gas with hydrogen concentration at 73%. The production rate of hydrogen was 4.16 ml/hr that could generate power of 350 mW in a typical PEM fuel cell.

BAF 소둔의 저온점 변화에 관한 연구

  • 김순경;이승수;전언찬
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1997.04a
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    • pp.327-331
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    • 1997
  • As demand for various kinds and small lot products has been increasing, batch annealing has been appreciated for its small restiction for the opteration. The cold spot of the coil is very important in the BAF(Batch annealing furnace) annealing process. Because of the annealing cycle time in the BAF, annealing was decided on the cold spot of the coil. So, we tested the effect,variation of cold spot, for hydrogen contents of atmospheric gas at the annealing furnace. As a result of several investigations. We confirmed the following characteristics ; after the heating and soaking,the cold spot of coil moved to 1/3 of coil thickness in the NHx atmospheric gas, but the mid point of the coil thickness is the cold spot in the Ax or .H/sub2. atmospheric gas. Therefore, the use of hydrogen instead of nitrogen as the protective gas,combined with high convection in batch annealing furnaces, has shown that considerable increases in furnace output and material quality are attainable. Owing to the low density, high diffusion and reducing character of hydrogen, a better transfer resulting in uniform material temperatures and improved coil surfaces can be achieved.

Manufacturing of Ultrahigh Vacuum Electron Cyclotron Resonance Chemical Vapor Deposition Reactor and Si Wafer Surface Cleaning by Hydrogen Plasma (초고진공 전자 사이클로트론 공명 화학 기상증착장치의 제작과 수소 플라즈마를 이용한 실리콘 기판 표면 세정화)

  • 황석희;태흥식;황기웅
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.31A no.4
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    • pp.63-69
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    • 1994
  • The Ultrahigh Vacuum Electron Cyclotron Resonance Chemical Vapor Deposition(UHV-ECRCVD) system whose base pressure is 1${\times}10^{9}$ torr has been constructed. In-situ cleaning prior to the epitaxial growth was carried out at 56$0^{\circ}C$ by ECR generated uniform hydrogen plasma whose density is $10^{10}/cm{3}$. The natural oxide was effectively removed without damage by applying positive DC bias(+10V) to the substrate. RHEED(Reflection High Energy Electron Diffraction) analysis has been used to confirm the removal of the surgace oxide and the streaky 2$\times$1 reconstruction of the Si surface, and the suppression of the substrate damage is anaylized by X-TEM(cross-sectional Transmission Electron Microscopy). Surface cleaning technique by ECR hydrogen plasma confirmed good quality epitaxial growth at low temperature.

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A Study on the Characteristics of Mixed Combustion for Hydrox Gas (Hydrox Gas 혼합연소특성 에 관한 연구)

  • Kim, Hong-Gun;Kwac, Lee-Ku
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.19 no.2
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    • pp.230-234
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    • 2010
  • Hydrox gas which is the mixed gas of hydrogen and oxygen gained fromwater electrolysis is one of the new clean energy sources and thus is researched and commercialized actively. Especially, it can be replaced the fossil energy and shows the better quality compared to the conventional energy such as LPG or acetylene gas. The mixed gas of hydrogen and oxygen is gained from water electrolysis reaction. It has constant volume ratio 2:1 of hydrogen and oxygen, and it is used as a source of thermal energy by combustion reaction. Further, hydrox gas is nearly a mixed ideal gas combusting itself completely and its combustion shows anunique characteristics of implosion. In this study, temperature rise effects on hydrox gas content through mixed combustion test of kerosene and hydrox gas and LPG and hydrox gas are investigated. it is also confirmed that economy of mixed combustion of hydrox gas as effective energy is fairly probable.

A Study on thermal cutting characteristics of hydrogen-oxygen mixed gas (수소-산소 혼합가스의 열절단 특성 연구)

  • Kim, Nam-In;Jang, Yong-Won;Jeong, Jun-Sik;Lee, Jeong-Su
    • Proceedings of the KWS Conference
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    • 2007.11a
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    • pp.8-10
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    • 2007
  • In recent years, hydrogen-oxygen mixed gas generated by electrically dissociating water has been proposed as alternative cutting fuel. The mixed gas consists of a hydrogen-oxygen mixed gas in the mixture ratio of 2:1. And gas has some merits as cutting quality and speed compared with existing gas cutting process. Because main source of mixed gas is water, mixed gas is environmental-friendly clean fuel. The purpose of the present paper is to investigate cutting characteristics and optimum cutting parameters of mixed gas, The effect of cutting parameter on the cutting characteristics of mixed gas is also investigated as compared to existing gas cutting process.

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Characterization and Fabrication of Microcrystalline Si Thin Films Prepared by FA-CVD (FA-CVD에 의한 미세결정질 실리콘 박막 제작 및 특성)

  • Cheong, Chang-Young;Chung, Kwan-Soo;Jang, Jin
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.27 no.9
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    • pp.1402-1408
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    • 1990
  • We studied the electrical, optical and structural properties of microcrystalline silicon thin films prepared by a new chemical vapour deposition technique, called filament assisted(FA)-CVD. The microcrystalline silicon is sucessfully deposited when the hydrogen dilution ratio exceeds 30. The Raman peak at 520 cm-1 and the X-ray diffraction peak at 27.7\ulcorner0.2\ulcornerbecome sharper with increasing hydrogen dilution ratio. We obtain high quality microcrystalline Si by FA-CVD with optical gap of \ulcorner2.2eV and hydrogen content of \ulcorner3 at %.

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Evaluation of Cigarette Quality by Measurement of Oxygen Free Radicals in Smoke (담배 연기 중 산소 자유 라디칼 측정에 의한 품질 평가)

  • Ji-Chang Park;Kyung-Ran Yoon;Young-Ha Rhee;Cheong Ho Lee
    • Journal of the Korean Society of Tobacco Science
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    • v.12 no.1
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    • pp.19-27
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    • 1990
  • To evaluate tobacco quality, several mathods including sensory test, or measurement of some toxic compounds such as tar, nicotine and carbon monoxide in cigarette smoke have been used. However, many detrimental effects of smoking on the physiological functions including respiratory system reported were turned out to be the action of reactive oxygen species. Therefore, the amounts of oxygen free radicals such as superoxide, hydroxyl radical, even hydrogen peroxide in the cigarette smoke are thought the very important factors. In the present study, we have determined the generation of superoxide and the content of hydrogen peroxide using superoxide dismutase and catalase in the gas and particulate phases obtained from cigarette smoke, respectively. In the aqueous extracts of total particulate materials, suproxide and hydrogen peroxide were detected, and there was an excellent correlation between oxygen tint of oxygen free radicals in cigarette smoke may be a useful index for evaluation of cigarette quality in the aspect of smoking and health.

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The Influence of Pulp Fines on Paper Structural Characteristics (종이의 구조 특성에 미치는 미세섬유의 영향)

  • Lee, Jin-Ho;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.4 s.117
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    • pp.17-23
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    • 2006
  • Paper has fibers and fines network structure and it is strongly affected by interface bond-ing between fibers. Paper structural properties can be determined depending on the inter-fiber bonding. Fines play an important role in Campbell and consolidation effect through wet pressing and drying operations. The fines are essential for the formation of bonds between fibers and for the improvement of strength properties of papers. Since the fines are components of the pulp, there are always two factors to be considered: the quality and quantity of the fines. The quality of fines might be a potential variable to give a more accurate picture of the papermaking potential of the pulp. The object of this study is to investigate the effect of different types of pulp fines on the properties of paper and to access the potential of fines for controlling the bulk of paper. Refined Sw-BKP, Hw-BKP and BCTMP fines were used to investigate the fines effect. Wet-web strength, breaking length, scattering coefficient, and hydrodynamic specific volume, and drying shrinkage were measured. According to the results, chemical and morphological compositions of fines do not strongly affect to wet-web forming by their similar Campbell effect, but strongly affect to drying operation which forms hydrogen bonding among fiber-fines-fiber matrixes. Paper bulk should be controlled by the extent of hydrogen bonding between fibers during drying operation.