• Corrosion Science and Technology
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• 제6권3호
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• pp.112-119
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• 2007

This paper presents the importance of corrosion control and protection technology with a real case study of heater tube rupture damaged by High temperature H2S-H2 corrosion in the refinery. The heater was operated at the Hydrocracking unit and the operation temperature and pressure was $340^{\circ}C$ and $18kg/cm^{3}$ respectively. Top side of the convection tube was thinned by high temperature hydrogen sulfide and hydrogen gas as a uniform corrosion and finally ruptured under operation pressure. Damaged area (Convection tube zone) was blocked by protection wall, so it was impossible to inspect with conventional nondestructive examination. Instead the elbow area which is out of the protection wall was inspected regularly to evaluate the corrosion rate of convection tube indirectly. However the operation temperature and the phase of the process stream was different between inside the chamber and outside the chamber. As a result, it caused severe corrosion to the horizontal convection tube inside the chamber comparing to the elbow outside the chamber. Finally convection tube was corroded more rapidly than the elbow and ruptured after 13 years operation. Because of the rupture, the heater was totally burned and the operation was stopped for 3 months until it has been reconstructed. To prevent this kind of corrosion problem and accident, corrosion control should be strengthened and protection technology should be improved.

• 전기학회논문지
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• 제64권4호
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• pp.552-559
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• 2015

Hydrogen is commonly used in many industrial field. However, hydrogen should be filled in a high pressure container to use it. Therefore, many researches have been conducted about an electrolyzer. The operating principle of the electrolyzer is that the electrolyzer can separate water molecules into hydrogen and oxygen. To use the electrolyzer, a power conversion system is needed because the current of the electrolyzer increases exponentially depending on the voltage of the electrolyzer. Thus, this paper proposes the power conversion system for the electrolyzer using a full-bridge DC-DC converter topology.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2009년도 제40회 하계학술대회
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• pp.1132_1133
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• 2009

In this paper, a observer-based PI controller will be developed for PEM fuel cell system. Nonlinear model of PEM fuel cell system is introduced to study the controller design problems. Sliding mode observer will be designed to estimate the cathode and anode pressures of PEMFC system. And a nonlinear state observer is also designed to estimate the other states such as supply manifold pressure, Oxygen pressure, Hydrogen pressure, return manifold pressure, etc. These estimated states are used to design the observer-based PI controller. The validity of the proposed controller will be verified by using computer simulation.

• 한국수소및신에너지학회논문집
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• 제10권1호
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• pp.19-26
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• 1999

수소 액화시스템의 중요한 구성요소인 열교환기를 이중관 형태로 설계 제작하여 극저온 영역에서의 유용도를 실험적으로 측정하였다. 이중관 열교환기의 내관과 내 외관 사이의 환상 공간으로 수소를 공급하고, 온도와 압력, 유량을 측정하였다. 측정된 온도와 유량으로부터 유용도를 환산한 결과, 열교환면적이 증가함에 따라 열교환기의 유용도는 증가하였다. 또한 저온 수소와 고온 수소의 열용량비가 감소함에 따라 열교환기의 유용도는 증가하나 유용도의 증가폭은 감소하였다. 따라서 본 연구에서는 수소 액화시스템에 필요한 유용도를 얻기 위한 열교환기의 길이 및 열용량비의 선정 기준을 제시하였다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2009년도 춘계학술대회 논문집
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• pp.67-70
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• 2009

고농도 과산화수소를 이용한 연구가 활발해짐에 따라 과산화수소의 국내 생산을 위한 증류 방법에 대한 연구가 요구된다. 증류 방법에는 증류할 물질의 공급방식과 증류 회수, 증류 압력 등의 증류 조건에 따라 여러 가지 방법이 존재하며 과산화수소 증류에는 진공증류법이 사용된다. 진공 증류는 과산화수소의 열분해와 공기 중 입자와의 반응을 줄일 수 있다. 증류 조건은 Raoult's law를 이용하여 결정하였다. 실험 장치의 낮은 진공도와 진공도의 조절이 중요한 문제로 나타났으나 진공 챔버의 교체로 진공의 누설을 막아 진공도를 높였으며, 실험 장치에 정량밸브를 설치하여 진공도를 조절하였다.

• 한국수소및신에너지학회논문집
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• 제22권5호
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• pp.625-633
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• 2011

Characteristics of a commercial metal hydride (MH) hydrogen supply system have been investigated and an operating strategy was developed based on the experimental data. As a prior step, charging/discharging capacity, thermal properties such as heat capacity, heat of reaction of MH system were experimentally measured. And then P-C-T data for various operating conditions were collected and a correlation between P, C and T predicting the behavior of MH was derived. Based on the basic experimental data, an operating strategy of MH system was developed, in which the hot water temperature supplied into the water jacket of MH was controlled depending on the pressure of MH, thereby the pressure of MH could be maintained at a suitable range. By adjusting the temperature of hot water from $40^{\circ}C$ to $60^{\circ}C$, the maximum discharging capacity of hydrogen could be increased by 4.7%, and consequently more stable hydrogen supply and longer operation time of fuel cell system could be achieved.

• 한국수소및신에너지학회논문집
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• 제32권4호
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• pp.205-211
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• 2021

Recently, it is necessary for study on renewable energy due to environmental pollution and fossil fuel depletion. Therefore, in this study, the filling temperature according to the nozzle geometry was evaluated based on the limit temperature specified in SAEJ2601 for charging hydrogen, a new energy. There are three types of nozzles, normal, angle and round, fixed the average pressure ramp rate at 52.5 MPa/min, and the injection temperature was set at 293.4 K. As a result, the lowest temperature distribution was found in the round type, although the final temperature did not differ significantly in the three types of nozzles. In addition, Pearson's coefficient was calculated to correlate the mass flow rate with the heat transfer rate at the inner liner wall, which resulted in a strong linear relationship of 0.98 or higher.

• 한국수소및신에너지학회논문집
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• 제34권5호
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• pp.456-464
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• 2023

In this study, a compact hydrogen liquefaction system was constructed with the aim of creating a data storage and monitoring program for liquid hydrogen production. This program was designed to receive and record signals from diverse control equipment through the LabVIEW software. A range of measurement instruments were devised to collect data, encompassing variables such as flow rate, pressure, temperature, and liquid level. As a result, it was possible to directly check the production of liquid hydrogen by obtaining various data of condensed liquid hydrogen. In addition, it was confirmed that long-term storage of liquid hydrogen is possible by developing automatic ON/OFF through the LabVIEW program.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.284-284
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• 2010

Currently, hydrogen has been produced by Steam Reforming or partial oxidation reforming processes mainly from oil, coal, and natural gas and results in the production of $CO_2$. However, these are influenced greatly on the green house effect of the earth. so it is important to find the new way to produce hydrogen utilizing water without producing any environmentally harmful by-products. In our research, we use microwave water plasma and photocatalyst to improve dissociation rate of water. At low pressure plasma, electron have high energy but density is low, so temperature of reactor is low. This may cause of recombination in the generated hydrogen and oxygen from splitting water. If it want to high dissociation rate of water, it is necessary to control of recombination of the hydrogen and oxygen using photocatalyst. We utilize the photocatalytic material($TiO_2$, ZnO) coated plasma reactor to use UV in the plasma. The quantity of hydrogen generated was measured by a Residual Gas Analyzer.

• 한국결정성장학회:학술대회논문집
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• 한국결정성장학회 1996년도 제11차 KACG 학술발표회 Crystalline Particle Symposium (CPS)
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• pp.87-107
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• 1996

The fine Co powder with an average particle sie of less than 1$\mu\textrm{m}$ was prepared by hydrothermal reduction with hydrogen from Co(OH)2 slurry obtained by mixing the solutons of CoSO4$.$7H2O and NaOH. A method to control pH of the end solution around neutrality was proposed. The reduction rate was found to be a function of pH, temperature, hydrogen pressure and the amount of catalyst.