• 제목/요약/키워드: Hydrogen ions

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Chlorobium limicola f. thiosulfatophilum NCIB 8327에서 수소발생에 영향을 끼치는 요인분석 (Factors Afecting Hydrogen Evolution in Chlorobium limicola f. theosulfatophilum NCIB 8327)

  • 나종욱;강사욱
    • 미생물학회지
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    • 제30권6호
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    • pp.553-557
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    • 1992
  • 변형된 Pfennig 배지에서 Glutamate 를 질소원으로 배앙한 다음 수확된 Chlorobium limicola f. thiosulfatophilum NCIB 8327 의 세포에서 수소생산이 수소 전극법 (hydrogen electrode)으로 측정되었다. 이 방법에 의해서 수소발생을 측정할 때, 산소, 빛, 암모니아 NADPH, ATP, methionine sulfoximine, NADPH, ATP, methionine sulfoximine, NADPH, ATP, methl viologen, 및 methionine sulfoximine 의 농도에 따라 변하는 것을 보았을 때 본 균주에서의 수소생산은 nitrogenase 에 의존하고 있음을 알 수 있었다.

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The effect of addition of noble gases on negative hydrogen ion production in a dc filament discharge

  • James, B.W.;Curran, N.P.;Hopkins, M.B.;Vender, D.
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 1999년도 학술대회논문집-국제 전기방전 및 플라즈마 심포지엄 Proceedings of 1999 KIIEE Annual Conference-International Symposium of Electrical Discharge and Plasma
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    • pp.40-45
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    • 1999
  • The effect of the addition of helium, neon, argon and xenon on the production of negative hydrogen ions has been studied in a magnetically confined dc filament discharge. The addition of helium and neon produced effects similar to an equivalent increase in hydrogen pressure. However, the addition of argon and low fractions of xenon produced significant increases in the negative ion density for hydrogen at pressures around 1 mTorr. The addition of argon and xenon, by increasing electron density and decreasing electron temperature, achieved conditions closer to optimum for negative ion production. The largest enhancement of negative hydrogen ion density occurred with the addition of argon; it is suggested that this is due to a resonant energy exchange between excited argon atoms and hydrogen molecules.

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Template Synthesis, Crystal Structure, and Magnetic Properties of a Dinuclear Copper(II) Complex with Cooperative Hydrogen Bonding

  • Kang, Shin-Geol;Nam, Kwang-Hee;Min, Kil-Sik;Lee, Uk
    • Bulletin of the Korean Chemical Society
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    • 제32권3호
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    • pp.1037-1040
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    • 2011
  • The dinuclear complex 1 with cooperative hydrogen bonds can be prepared by the metal-directed reaction of Eq. (2). This work shows that the coordinated hydroxyl group trans to the secondary amino group is deprotonated more readily than that trans to the tertiary amino group and acts as the hydrogen-bond accepter. The lattice water molecules in 1 act as bridges between the two mononuclear units through hydrogen bonds. The complex is quite stable as the dimeric form even in various polar solvents. The complex exhibits a weak antiferromagnetic interaction between the metal ions in spite of relatively long Cu$\cdots$Cu distance. This strongly supports the suggestion that the antiferromagnetic behavior is closely related to the cooperative hydrogen bonds.

제주도 한라산 남북측 사면 용천수의 수리지구화학

  • 이광식;박원배;현승규;김용제;문덕철;김구영
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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    • pp.408-412
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    • 2004
  • A total of 23 springs distributed in the southern and northern sides of Mt. Hala in Jeju Island were seasonally sampled and analyzed for their major ion chemistry and oxygen and hydrogen isotope compositions to investigate their hydrogeochemical and isotopic characteristics. Dissolved ion concentrations of the south-side springs slightly increase with decreasing altitude. This indicates that dissolved ion concentrations of groundwater recharged at higher altitudes increase by water-rock interaction during the downgradient migration of groundwater through highly permeable volcanic aquifer. Dissolved ion concentrations of the north-side springs also slightly increase with decreasing altitude, but dramatically increase at ~300 m.a.s.l. This may indicate a sudden input of contaminants to the north-side groundwater system around ~300 m.a.s.l. Springs located in areas above ~300 m.a.s.l. have very low concentrations of dissolved ions, showing little seasonal variations. Whereas springs located in areas below ~300 m.a.s.l. show a big seasonal variation in the concentration of dissolved ions. Seasonal variation of oxygen isotope compositions of springs is ~3$\textperthousand$ for high-altitude springs (~1700 m.a.s.l.) and is ~2$\textperthousand$ near shore, indicating an attenuation of the variation through mixing with other groundwater bodies during migration.

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대기 입자상물질중 탄소(C)등의 열적특성에 관한 조사연구 (A Study on Thermal Characteristic Carbon and other Elements in Suspended Particulates)

  • 황경철
    • 한국환경보건학회지
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    • 제16권2호
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    • pp.31-39
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    • 1990
  • An analytical method for particulate carbon and other elements by using elemental analyzer was investigated. Carbon, hydrogen, and nitrogen was determined as CO$_{2}$, H$_{2}$, and N$_{2}$, respectively. Organic was determined after scparation from elemental carbon(Cae) by volatilization and thermal decomposition in a heated helium flow. With organic materials examined in this reprot, more than 90% of carbon was detected as above 600$^{\circ}$C. But it is considered that a few percents of some compounds were charred above 550$^{\circ}$C. A small amount of Cae was oxidized in the inert atmosphere above 850$^{\circ}$C, but the reason was not explained clearly. Based on the thermal chracteristics of Cao it was found that the optimum temperature of heating in the helium flow of an elemental analyzer for Cao analysis is 630$^{\circ}$C. Carbon in a sample after removing Cao was assumed as Cae and the gramatom ratio of hydrogen to carbon in the sample was 0.4 and less. Rescovery of nitrogen derived from some ammonium salts and nitrates was 100% by two-step measurement with elemental analyzer. By the analytical method investigated in this report, carbon and other elements in suspended particulates(S.P) collected at an urban area in Seoul were measured. There was a good correlation between total nitrogen in SP measured by elemental analyzer and nitrogen estimated form ammonium ions and nitrate ions in SP. The nitrogen from these ions accounts for 80% of the total nitrogen. It is further suggested that the residue(20%) of the total nitrogen is attributed to the other nitrogeneous compounds.

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상압 플라즈마의 광 방출 스펙트럼 특성조사에 관한 연구 (The Study on Emission Spectrum Characteristics of Atmosphere Pressure Plasma)

  • 박성진
    • 조명전기설비학회논문지
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    • 제27권2호
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    • pp.77-83
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    • 2013
  • In this study, we aimed to determine the optical properties of the plasma used for the dry cleaning method. The optical properties of the atmospheric pressure plasma device were measured through the degree of ionization of hydrogen or nitrogen gas by ionized atmospheric gas. The degree of ionization of hydrogen or nitrogen is closely associated with surface modification. We observed through our experiments that argon gas, an atmospheric gas, caused an increase in the ionization of nitrogen gas, which has similar ionization energy. This type of increase in nitrogen gas ions is believed to affect surface modification. The results of our study show that the pressure of argon gas and the partial pressure of argon and nitrogen gases lead to different results. This important result shows that argon ions can affect the ionization of nitrogen gas.

Optical Properties of a Proton-implanted Nd:CNGG Planar Waveguide

  • Zhu, Qian-Lin;Lin, Ming-Fu;Chen, Jing-Yi;Wang, Zhong-Yue;Liu, Chun-Xiao
    • Current Optics and Photonics
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    • 제3권2호
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    • pp.172-176
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    • 2019
  • The work reports on the fabrication of an optical planar waveguide in the Nd:CNGG crystal by the 0.4-MeV hydrogen ion implantation with a fluence of $8.0{\times}10^{16}ions/cm^2$. The nuclear energy loss of the implanted hydrogen ions was derived by using SRIM 2013 code. The microscope image of the proton-implanted Nd:CNGG crystal cross section was captured by a metallographic microscope. The transmittance spectra were recorded before and after the ion implantation. The light intensity distribution of the planar waveguide at 632.8 nm was experimentally measured to validate its effect on one dimension confinement. The investigation shows that the proton-implanted Nd:CNGG waveguide is a candidate for an optoelectronic integrated device.

충북 청원군의 강수중의 이온들간의 상관관계 (Correlations between the ions in the precipitation at Chongwon, Chungbuk)

  • 박용남;송기형
    • 한국환경과학회지
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    • 제2권4호
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    • pp.337-346
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    • 1993
  • The amount of inorganic ions such as $Na^+$, $K^+$, $Ca^{2+}$, $Mg^{2+}$, $NH_4^+$, $Cl^-$, $NO_3^-$, and $SO_4^{2-}$ in the precipitation at hongwon area were analyzed during the period of February 1991 - June 1993. Ammonium ion was analyzed using Messier and indophenol methods. Cations were determined by atomic absorption spectroscopy, and ion chromatography was used for anions. For the entire period of study, there was no particular ion which has significant]y high correlation coefficient with hydrogen ion. The correlation between $NO_3^-$, and $SO_4^{2-}$ was 0.6, which suggests that these ions may be from the same source. Most cations have high correlation with each other. In the seasonal analysis, the nitrate and sulfate ions have high correlations with the acidity in the fall and winter. The rain waters of Taeahn area showed usually high concentrations of the ions, even though the pH was much higher than that of Chongwon area. It is considered that the ions came as neutral salt in Taeahn, while $NO_x$ and $SO_x$ contributes largely to the acidity of rains in Chongwon.

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금속이온으로 치환된 PVA/SSA 이온교환막의 메탄올 투과특성 연구 (Studies on the Methanol Permeability through PVA/SSA Ion Exchange Membranes Substituted with Various Metal Cations)

  • 이충섭;정선영;전지현;신현수;임지원
    • 멤브레인
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    • 제12권1호
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    • pp.51-53
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    • 2002
  • Poly(vinyl alcohol) (PVA)/sulfosuccinic acid $(SSA)-H^+$ 막은 1가 이온 $Li^+, Na^+,K^ + 2$가 이온 $Mg^{2+}, Ca^{2+},Ba^{2+}, 3$가 이온 $Al^{3+}$로 치환하였다. 또한 $Li^{+}$의 경우 치환도를 화하였다. 금속이온치환의 효과를 알아보기 위하여 Diffusion cell을 이용한 메탄올투과도를 측정하였다. 메탄올투과도를 1가 이온의 경우는 'Salting-out'효과뿐 아니라 electrostatic 가교와 금속 이온의 반응성에 의존한다고 사료되었다. 또한 $Li^+$이온이 경우 치환도에 비례하여 메탄올 투과도가 감소하였는데 이는 'Salting-out'효과에 기인한다고 사료되어진다.

폴리아크릴산/$H_2O$ 혼합물에서 $H_2O$ 열적 거동에 미치는 이온의 영향 (The Effect of Ions on Thermal Behaviors of Water in Poly(acrylic acid)/Water Mixtures)

  • Guan, Lan;Xu, Hongyan;Huang, Dinghai
    • 폴리머
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    • 제34권4호
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    • pp.386-389
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    • 2010
  • Thermal behaviors of water in the poly(acrylic acid) (PAA)/water mixtures with 0.1 M NaCl, HCl, and NaOH were investigated by DSC. It showed that adding ions in the mixtures affected the crystallization of water evidently. Compared with the PAA/water mixtures, the $T_m$ of freezable bound water in the mixtures with ions moved to lower values and varied with different cations and anions, due to the stabilization or destabilization of the hydrogen-bonding hydration between polymers and water molecules through ionic hydration. The content of non-freezable bound water in the non-crystalline phase of the PAA/water mixtures with ions was not constant, it increased with total water content gradually, owing to the more binding sites created by ions. The ions could change the distribution of different states of water in the polymer aqueous solutions evidently.