• Transactions of the Korean hydrogen and new energy society
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• v.26 no.1
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• pp.64-70
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• 2015

Organic Rankine cycle (ORC) is an useful cycle for power generation system with low temperature heat sources ($80{\sim}400^{\circ}C$). Since the boiling point of operating fluid is low, the system is used to recover the low temperature heat source of waste heat energy. In this study, a ORC with R134a is applied to recover the waste energy of condenser of coal fired power plant. A system model is developed via Thermolib$^{(R)}$ under Simulink/MATLAB environment. The model is composed of a refrigerant heat exchanger for heat recovery from coal fired condenser, a drum, turbine, heat exchanger for ORC heat rejection, storage tank, water recirculation pump and water drip pump. System analysis parameters were heat recovery capacity, type of refrigerants, and types of turbines. The simulation model is used to analyze the heat recovery capacity of ORC power system. As a result, increasing the overall heat transfer coefficient to become the largest of turbine power is the most economical.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.6
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• pp.637-645
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• 2020

In this paper, entransy analysis is carried out for combined heat and power (CHP) generation system driven by low-grade heat source compared with energy and exergy analyses. The system consists of a regenerative organic rankine cycle (ORC) and an additional process heater in a series circuit. Special attention is paid to the effects of the turbine inlet pressure, source temperature, and the working fluid on the thermodynamic performance of the system. Results showed that the work efficiency of entransy is higher than that of energy but lower than that of exergy, wheress the process heat efficiency of entransy is lower than that of energy but higher than that of exergy. Entrance analysis showed the potential to complement the exergy analysis in the optimal design of the energy system.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.5
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• pp.374-387
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• 2021

Basic design of 3 MWth chemical looping combustion system for LNG combustion and steam generation was conducted based on the mass and energy balance and the previous reactivity test results of oxygen carrier particles. Process configuration including fast fluidized bed (air reactor), loop seal and bubbling fluidized bed (fuel reactor) was confirmed and their dimensions were determined by mass balance. Then, the external fluidized bed heat exchanger (FBHE) was adopted based on the energy balance to extract heat from the system. The optimum reactor design and operating condition was confirmed with sensitivity analysis by modifying system configuration based on the mass and energy balance.

• Journal of the Korean institute of surface engineering
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• v.56 no.6
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• pp.412-419
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• 2023

Anion exchange membrane electrolysis is considered a promising next-generation hydrogen production technology that can produce low-cost, clean hydrogen. However, anion exchange membrane electrolysis technology is in its early stages of development and requires intensive research on electrodes, which are a key component of the catalyst-system interface. In this study, we optimized the pressure conditions of the hot-pressing process to manufacture cobalt oxide electrodes for the development of a high uniformity and high adhesion electrode production process for the oxygen evolution reaction. As the pressure increased, the reduction of pores within the electrode and increased densification of catalytic particles led to the formation of a uniform electrode surface. The cobalt oxide electrode optimized for pressure conditions exhibited improved catalytic activity and durability. The optimized electrode was used as the anode in an AEMWE single cell, exhibiting a current density of 1.53 A cm^-2 at a cell voltage of 1.85 V. In a durability test conducted for 100 h at a constant current density of 500 mA cm^-2, it demonstrated excellent durability with a low degradation rate of 15.9 mV kh^-1, maintaining 99% of its initial performance.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.22 no.1
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• pp.135-140
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• 2022

In addition to the stack that directly generates electricity by the reaction of hydrogen and oxygen, the fuel cell power generation system has a reformer that generates hydrogen from various fuels such as methanol and natural gas. It also consists of a power converter that converts the DC voltage generated in the stack into a stable AC voltage. The fuel cell output of such a system is direct current, and in order to be used at home, an inverter device that converts it into alternating current through a power converter is required. In addition, a DC-DC step-up converter is used to boost the fuel cell voltage to about 30~70V, which is the inverter operating voltage, to about 380V. The DC-DC step-up converter is a DC voltage variable device that exists between the fuel cell output and the inverter. Accordingly, since a constant output voltage of the converter is generated in response to a change in the output voltage of the fuel cell, the inverter can receive constant power regardless of the voltage change of the fuel cell. Therefore, in this paper, we discuss the detailed hardware design of the full-bridge converter, which is the main power source of the inverter that receives the fuel cell output voltage (30~70V) as an input and is applied to the grid among the members of the fuel cell power generation system.

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.3
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• pp.285-292
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• 2012

The integrated gasification combined cycle (IGCC) system is well known for its high efficiency compared with that of other coal fueled power generation system. IGCC offers substantial advantages over pulverized coal combustion when carbon capture and storage (CCS) is required. Commercial plants employ different types of quenching system to meet the purpose of the system. Depending on that, the downstream units of IGCC can be modeled using different operating conditions and units. In case with $CO_2$ separation and capture, the gasifier product must be converted to hydrogen-rich syngas using Water Gas Shift (WGS) reaction. In most WGS processes, the water gas shift reactor is the biggest and heaviest component because the reaction is relatively slow compared to the other reactions and is inhibited at higher temperatures by thermodynamics. In this study, tehchno-econimic assessments were found according to the quench types and operating conditions in the WGS system. These results can improve the efficiency and reduce the cost of coal gasification.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.3
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• pp.276-281
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• 2019

The process of separating oxygen and nitrogen from the air is mainly performed by electric liquefaction, which consumes a lot of electricity, resulting in higher operating costs. On the other hand, when used for cold energy of LNG, electric power can be reduced compared to the electric Linde cycle. Currently, LNG cold energy is used in the cold refrigeration warehouse, separation of air-liquefaction, and LNG cold energy generation in Japan. In this study, the system using LNG cold energy and the Linde cycle process system were simulated by PRO/II simulators, respectively, to cool the elevated air temperature from the compressor to about $-183^{\circ}C$ in the air liquefaction separation process. The required amount of electricity was compared with the latent heat utilization fraction of LNG, the LNG supply pressure, and the LNG cold energy usage. At the air flow rate of $17,600m^3/h$, the power source unit of the Linde cycle system was $0.77kWh/m^3$, compared with $0.3kWh/m^3$.

• Nuclear Engineering and Technology
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• v.39 no.1
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• pp.9-20
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• 2007

Design study on the Gas Turbine High Temperature Reactor 300-Cogeneration (GTHTR300C) aiming at producing both electricity by a gas turbine and hydrogen by a thermochemical water splitting method (IS process method) has been conducted. It is expected to be one of the most attractive systems to provide hydrogen for fuel cell vehicles after 2030. The GTHTR300C employs a block type Very High Temperature Reactor (VHTR) with thermal power of 600MW and outlet coolant temperature of $950^{\circ}C$. The intermediate heat exchanger (IHX) and the gas turbine are arranged in series in the primary circuit. The IHX transfers the heat of 170MW to the secondary system used for hydrogen production. The balance of the reactor thermal power is used for electricity generation. The GTHTR300C is designed based on the existing technologies of the High Temperature Engineering Test Reactor (HTTR) and helium turbine power conversion and on the technologies whose development have been well under way for IS hydrogen production process so as to minimize cost and risk of deployment. This paper describes the original design features focusing on the plant layout and plant cycle of the GTHTR300C together with present development status of the GTHTR300, IHX, etc. Also, the advantage of the GTHTR300C is presented.

• Journal of the Korean Institute of Gas
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• v.26 no.1
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• pp.7-19
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• 2022

Hydrogen purification is generally performed through chemical and physical methods. Among various types of purification method PSA(Pressure Swing Adsorption) is widely used with its purification capacity and economic efficiency. In Korea, most of the hydrogen used in automobiles and power generation fuel cells is purified using PSA. Hydrogen produced in petrochemical complexes has difficulties in transportation. The government is planning to install hydrogen extractors that produce hydrogen directly from consumers in connection with the city gas supply chain, and companies are also installing related research and demonstration facilities one after another. Europe and others have recently established safety standards related to PSA and are making efforts for systematic safety management at the construction and operation stage, but domestic safety standards related to PSA are still insufficient. This study aims to identify problems of existing facilities through surveys and risk assessment by companies operating existing PSA, and to prepare domestic technical standards including them in overseas technical standards to promote the safety of new and existing PSA systems.

• Membrane Journal
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• v.31 no.2
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• pp.133-144
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• 2021

Alkaline water electrolysis system is the oldest technology among various hydrogen production processes to produce green hydrogen with the least amount of greenhouse gas generated. Alkaline water electrolysis (AWE) system is used in alkaline atmosphere condition. In comparison to polymer electrolyte membrane water electrolysis (PEMWE), this system can utilize stable transition metals such as nickel, cobalt, and silver, as electrode catalysts. AWE is relatively inexpensive, and can easily be scaled up to large scale. The system is a mature technology, as it has been in operation since the beginning of the 20th century in MW-scale for hydrogen generation, and there are currently more than 20 commercial manufacturers. In this review, the basic principles of AWE, along with catalysts, electrodes, and diaphragm membranes, are summarized. Particularly, the research and development trends of the diaphragm membrane unit, which is the core component of an AWE, are discussed in detail.