• 한국수소및신에너지학회논문집
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• 제30권4호
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• pp.303-311
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• 2019

Reversible solid oxide fuel cell (RSOFC) has become a prospective device for energy storage and hydrogen production. Many studies have been conducted around the world focusing on system efficiency improvement and realization. The system should have not only high efficiency but also a certain level of simplicity for stable operation. External waste steam utilization was proved to remarkably increase the efficiency at solid oxide electrolysis system. In this study, RSOFC system coupled with waste steam was proposed and optimized in term of simplicity and efficiency. Ejector for fuel recirculation is selected due to its simple design and high stability. Three system configurations using ejector for fuel recirculation were investigated for performance of design condition. In parametric study, the system efficiencies at different current density were analyzed. The system configurations were simulated using validated lumped model in EBSILON(R) program. The system components, balance of plants, were designed to work in both electrolysis and fuel cell modes, and their off-design characteristics were taken into account. The base case calculation shows that, the system with suction pump results in slightly lower efficiency but stack can be operated more stable with same inlet pressure of fuel and air electrode.

• 한국수소및신에너지학회논문집
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• 제22권2호
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• pp.178-183
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• 2011

Metal hydride alloys are a promising type of material in hydrogen storage applications, allowing for low-pressure, high-density storage. However, while many studies are being performed on enhancing the hydrogen storage properties of such alloys, there has been little research on large-scale storage vessels which make use of the alloys. In particular, large-scale, high-density storage devices must make allowances for the inevitable generation or absorption of heat during use, which may negatively impact functioning properties of the alloys. In this study, we develop a numerical model of the discharge properties of a high-density MH hydrogen storage device. Discharge behavior for a pilot system is observed in terms of temperature and hydrogen flow rates. These results are then used to build a numerical model and verify its calculated predictions. The proposed model may be applied to scaled-up applications of the device, as well as for analyses to enhance future device designs.

• 한국수소및신에너지학회논문집
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• 제19권4호
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• pp.313-321
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• 2008

Dynamics of the proton exchange membrane fuel cell is specially important when the system is frequently working on transient conditions. Even though the dynamics of proton exchange membrane fuel cell for residential power generation is less critical than that of PEMFC for transportation application, the system dynamics of PEMFC for RPG can be very important for daily start-up and stop. In particular, thermal management of the PEMFC for RPG is very important because the heat generation from electrochemical reaction is delivered to the home for hot water usages. Additionally, the thermal management is also very important for heat balance of the system and temperature control of the fuel cell. The objective of this study is to develop a dynamic system model for the study of PEMFC performance over various BOP options. Basic simulation results will be presented.

• 한국수소및신에너지학회논문집
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• 제22권5호
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• pp.699-705
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• 2011

A combined heat and power cogeneration system driven by low-temperature sources is investigated by the first and second laws of thermodynamics. The system consists of Organic Rankine Cycle (ORC) and an additional process heater as a series circuit. Seven working fluids of R152a, propane, isobutane, butane, R11, R123, isopentane and n-pentane are considered in this work. Maximum mass flow rate of a working fluid relative to that of the source fluid is considered to extract maximum power from the source. Results indicate that the second-law efficiency can be significantly increased due to the combined heat and power generation. Furthermore, higher source temperature and lower turbine inlet pressure lead to lower second-law efficiency of ORC system but higher that of combined system. Results also show that the optimum working fluid varies with the source temperature.

• 전기학회논문지
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• 제65권11호
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• pp.1925-1930
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• 2016

Fuel cell power generation system, unlike conventional energy sources, converts chemical energy into electrical energy through electrochemical reaction of hydrogen and oxygen. This paper presents the control of interleaved multi-phase boost converter as the feasibility study on small-scale prototype electric railway vehicle application using fuel cell generation system. PSIM simulation program is to be used to implement the modeling of the electrical fuelcell as well as traction motor control with interleaved multi-phase boost converter. Comparing the input current ripple rate, two-phase interleaved boost converter is less than the boost converter. But the more multi-phase not less proportional to the ripple factor. we confirmed that the amplitude of the input current ripple rate of converter depend on duty ratio.

• 한국수소및신에너지학회논문집
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• 제25권1호
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• pp.39-46
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• 2014

Our lab designs a heat exchangers for hydrogen gas. Coolant is water, thus it is very difficult to determine heat transfer parameters in this gas-liquid system. Repeated experiments gives overdesign value 6.06%, overall heat transfer coefficient 36.32 ($kcal/m^2-hr-^{\circ}C$) for Hydrogen. Theoretically determined overall heat transfer coefficient is 38.44 ($kcal/m^2-hr-^{\circ}C$). Our lab simulated this system and overdesign 30.4% shows good match with this experiment by HTRI. These parameters are in same range with literature.

• 한국항해항만학회지
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• 제44권4호
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• pp.283-290
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• 2020

액화 수소 운반선에서 증발가스의 발생은 불가피하며, 화물탱크 내부의 압력 문제를 피하기 위해 적절한 조치가 필요하다. 이 증발 가스는 선박의 추진연료로 사용 될 수 있으며, 추진에 사용되고 남은 나머지 부분은 재액화 또는 연소시키는 등 효과적으로 관리해야 한다. 본 연구에서는 수소 추진 시스템을 갖춘 160,000㎥ 액화 수소 운반선에 최적화된 증발 가스 재액화 시스템을 제안한다. 이 시스템은 수소 압축 및 헬륨 냉매 섹션으로 구성되고, 화물탱크로부터 배출되는 증발가스의 냉열을 효과적으로 활용하여 효율을 증가시켰다. 본 연구에서는 공급 온도 -220℃인 수소 증발가스가 재액화 시스템에 들어가는 상태에서 증발가스의 재액화 비율에 따른 엑서지 효율 및 에너지 소모율 (SEC, Specific Energy Consumption) 분석을 통해 시스템을 평가하였다. 그 결과 재액화 비율 20%에서 4.11kWh/kgLH₂의 SEC와 60.1%의 엑서지 효율을 보여 주었다. 아울러, 수소 압축압력, 수소 팽창기의 입구온도, 공급 증발가스 온도변화에 따른 영향을 확인하였다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.124.2-124.2
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• 2010

Generally, a coolant of the nuclear power plant is manufactured by electrolyzing the sea water near the plant for making the sodium hypochlorite(NaOCl), which is used for sterilizing the bacteria and the shellfishes sticking to the drains or the pumps at the outlet of the cooling system due to $8-10^{\circ}C$ warmer temperature than the inlet sea water. During manufacturing the sodium hypochlorite, the hydrogen with the high purity is also produced at the anode side of the electrolyzer. This paper describes a novel power plant system combined with the polymer electrolyte membrane(PEM) fuel cell, the wasted hydrogen from the sea water electrolyzer and the wasted heat of the nuclear power plant. The present status over the exhausted hydrogen at twenty nuclear power plants in Korea was investigated in this study, from which an available power generation is estimated. Furthermore, the economic feasibility of the PEM fuel cell power plant is also evaluated by a current regulations over the power production and exchange using a renewable energy shown in Korea Power Exchange(KRX).

• Korean Chemical Engineering Research
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• 제55권2호
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• pp.170-179
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• 2017

본 논문은 소듐냉각고속로 원형로 소듐-물 반응 압력완화계통의 급수배출부와 수소방출부의 설계요건 도출을 목적으로 한다. 증기발생기 전열관 누설에 의한 소듐-물 반응 발생 시, 증기발생기 내의 급수 증기를 신속하게 배출하는 조건을 도출하기 위해 급수덤프탱크 가스방출배관의 단면적과 증기발생기 급수배출배관의 수직길이를 변화시켜 연구를 수행하였다. 정상운전과 재장전운전에 대해 각각 계산을 수행하여 급수덤프탱크 가스방출배관의 단면적과 증기발생기 급수배출배관의 수직길이를 결정하였다. 정상운전 조건에서 소듐-물 반응 발생 시, 생성물인 수소에 의해 형성되는 과압이 소듐덤프탱크의 설계압력을 만족시킬 수 있도록 하는 가스방출배관의 직경을 도출하였고, 이 때 대기로 방출되는 수소의 유량과 농도를 계산하였다. 본 논문의 계산결과는 향후 소듐냉각고속로 원형로의 소듐-물 반응 압력완화계통의 설계요건으로 활용될 예정이다.

• 한국수소및신에너지학회논문집
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• 제29권3호
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• pp.235-242
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• 2018

Hydrogen can be produced by reforming reaction of natural gas (NG) and biogas, or by water electrolysis. In this study, hydrogen production through water-electrolysis needs superheated steam above $700^{\circ}C$ for high efficiency. The production method of hydrogen like this was recommended for the 4-type processes for superheated steam ($700^{\circ}C$, 3 atm) by Bio-SRF combustion furnace. The 4-type processes to produce superheated steam at $700^{\circ}C$ from the heat source of SRF combustion furnace was simulated using PRO II. The optimum process was selected through exergy analysis. The difference of process 1 and 2 is to the order of depressure and heating process to change $180^{\circ}C$ and 7 atm to $700^{\circ}C$ and 3 atm. Process 3 and 4 is to utilize 25% of steam to generate superheated steam and remaining to use for the power generation by steam generator.