• 한국가스학회지
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• 제23권6호
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• pp.74-80
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• 2019

수소를 고압으로 압축하여 사용하는 수소충전소는 안전 확보를 위해 설비간의 안전거리를 규정하고 있다. 수소 충전소에서 발생하는 사고 중 대부분의 사고는 누출사고이며, 누출 시 점화로 인해 제트화염이 생성된다. 고압의 수소 누출로 인한 가스 확산 및 제트화염의 해석은 안전거리 설정에 가장 중요한 요소이다. 본 연구에서는 고압의 환경에서 운용되는 수소충전소에서 발생할 수 있는 누출사고를 대비한 안전관리 규정 도출을 위하여 누출원 크기별 누출조건을 모사하고 위험거리 등을 파악하여 향후 안전기준 제정 시 참고자료로 활용하고자 한다.

• Bulletin of the Korean Chemical Society
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• 제2권1호
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• pp.8-11
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• 1981

A new potential function based on spectroscopic results for diatomic molecules is presented and applied to the hydrogen bonding systems. The potential energy of interaction is supposed to have electrostatic, polarization, dispersion, repulsion and effective charge-transfer contributions. Estimates of the effective charge-transfer quantity have been made based on the average charge of the proton donor and the acceptor atoms. For dimers such as water, methanol, acetic acid and formic acid, the vibrational stretching frequencies and dimerization energies are calculated and dicussed in connection with Badger-Bauer rule.

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2005년도 Proceedings of The 6th korea-china joint workshop on nuclear waste management
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• pp.141-148
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• 2005

Pt/SDBC catalyst, which is used for the hydrogen-water isotopic exchange reaction, was prepared. The various properties of the catalyst, such as the thermal stability, pore structure and the platinum dispersion, were investigated. A hydrophobic Pt/SDBC catalyst which has been developed for the LPCE column of the WTRF (Wolsong Tritium Removal Facility) was tested in a trickle bed reactor. An experimental apparatus was built for the test of the catalyst at various temperatures and gas velocities.

• 한국수소및신에너지학회논문집
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• 제34권6호
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• pp.631-640
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• 2023

This study selected Eco-AZ91 MgH₂, which shows high enthalpy as a material for this purpose, as the basic material, and analyzed the change in characteristics by synthesizing TiNi as a catalyst to control the thermodynamic behavior of MgH₂. In addition, the catalyst dispersion technology using graphene oxide (GO) was studied to improve the high-temperature aggregation phenomenon of Ni catalyst and to secure a source technology that can properly disperse the catalyst. XRD, SEM, and BET analysis were conducted to analyze the metallurgical properties of the material, and TGA and DSC analysis were conducted to analyze the dehydrogenation temperature and calorific value, and the correlation between MgH₂, TiNi catalyst, and GO reforming catalyst was analyzed. As a result, the MgH₂-5 wt% TiNi at GO composite could lower the dehydrogenation temperature to 478-492 K due to the reduction of the catalyst aggregation phenomenon and the increase in the reaction specific surface area, and an experimental result for the catalyst dispersion technology by GO could be ensured.

• 한국수소및신에너지학회논문집
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• 제22권4호
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• pp.415-423
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• 2011

HI decomposition step certainly demand catalytic reaction for efficient production of hydrogen in SI process. Platinum catalyst can apply to HI decomposition reaction as well as hydrogenation or dehydrogenation. Generally, noble metal is used as catalyst which is loaded form for getting high dispersion and wide active area. In this study, Pt was loaded onto zirconia, ceria, alumina, and silica by impregnation method. HI decomposition reaction was carried out under the condition of $450^{\circ}C$, 1atm, and $167.76h^{-1}$ (WHSV) in a fixed bed reactor for measuring catalytic activity. And property of a catalyst was observed by BET, TEM, XRD and chemisoption analysis. On the basis of experimental results, we discussed about conversion of HI according to physical properties of the loaded Pt catalyst onto each support.

• 한국수소및신에너지학회논문집
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• 제34권6호
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• pp.734-740
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• 2023

Hydrogen emphasis on safety management due to its high potential for accidents from wide explosive limits and low ignition energy. To prevent accidents, appropriate explosion-proof electrical equipment with installed to safe management of ignition sources. However, designing all facilities with explosion-proof structures can significantly increase costs and impose limitations. In this study, we optimize the barrier to effectively control the initial momentum in case of hydrogen release and form the control room as a non-hazardous area. We employed response surface method (RSM), the barrier distance, width and height of the barrier were set as variables. The Box-Behnken design method the selection of 15 cases, and FLACS assessed the presence of hazardous area. Analysis of variance (ANOVA) analysis resulting in an optimized barrier area. Through this methodology, the workplace can optimize the barrier according to the actual workplace conditions and classify reasonable hazardous area, which is believed to secure safety in hydrogen facilities and minimize economic burden.

• 한국표면공학회지
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• 제41권5호
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• pp.194-198
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• 2008

Several methods for improving dispersion of carbon nanotubes (CNTs) have been investigated. CNTs modified by acids and hydrogen peroxide ($H_2O_2$) showed improved dispersion. From SEM micrographs and photos of dispersion, CNTs modified with nitric acid and $H_2O_2$, showed no agglomeration in solution even standing for 4 months, which means successfully improved dispersion property. TEM micrographs of surface modified single CNT treated with 69% $HNO_3$ in boiling acid solution as the optimum method were obtained. For confirmation of CNTs' application to EDLC electrode materials, characteristics of EDLC have been analyzed by cyclic voltammetry curve, specific capacitance of unit cell, electrode discharge curves and AC impedance curve. From the results, it could be confirmed that electrochemical properties of CNTs were enhanced after surface modification with 69% $HNO_3$ acid treatment.

• 한국수소및신에너지학회논문집
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• 제23권6호
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• pp.588-597
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• 2012

In the present study, the dispersion characteristics of hydrogen leakage from a Fuel Cell Vehicle (FCV) were analyzed by numerical simulation in order to assess the risk of a hydrogen leakage incident in a long road tunnel. In order to implement the worst case of hydrogen leakage, the FCV was located at the center of a tunnel, and hydrogen was completely discharged within 63 seconds. The Leakage velocity of hydrogen was adopted sub-sonic speed because that the assumption of the blockage effect of secondary device inside a vehicle. The temporal and spatial evaluation of the hydrogen concentration as well as the flammable region in a road tunnel was reported according to change of ventilation operating conditions. The hydrogen was blended by supply air form a ventilation fan, however, the hydrogen was discharged to outside in the exhaust air. It is observed that the efficiency way to eliminate of hydrogen is supply air operating condition under the hazardous hydrogen leaking incident. The present numerical analysis can be provided useful information of ventilation under the hydrogen leaking situation.

• 문화기술의 융합
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• 제10권1호
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• pp.551-557
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• 2024

수소는 청정, 무탄소, 고에너지등 다양한 특징을 가진 재생에너지원으로 국제적으로 '미래에너지'로 인정받고 있다. 수소에너지 산업의 급속한 발전과 더불어 수소 수요를 충족시키기 위하여 더 많은 수소 인프라가 필요한 실정이다. 그러나 수소 인프라 사고가 빈번한 발생함으로 인해, 수소산업 발전에 걸림돌이 되고 있다. 미국 Sandia National Laboratories에서 개발한 HyRAM+는 수소충전소를 포함한 다양한 저장 응용 분야에 대한 수소 안전 평가와 관련된 데이터와 방법을 통합하는 소프트웨어 툴킷이다. HyRAM+의 물리 모드는 수소충전소 컴포넌트에 따라 수소누출 결과를 모사하여 가스 플룸 분산, 제트 프레임 온도와 궤적 그리고 복사 열속 등을 그래프로 나타낸다. 본 논문에서는 강원도 삼척시에 있는 수소충전소를 대상으로하여 HyRAM+ 소프트웨어를 이용하여 수소 누출 데이터를 추출하였다. HyRAM+에서 추출한 데이터를 이용하여 수소 누출(Leakage) 발생 시뮬레이터를 개발하였다. 데이터베이스와 그라파나(Grafana)를 이용하여 시뮬레이터에서 발생한 데이터를 보여주는 대쉬보드(Dashboard)로 구현하였다.

• 공업화학
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• 제28권2호
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• pp.221-229
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• 2017

본 연구에서는 다양한 상용 알루미나 지지체의 수소 상온산화 반응특성을 확인하기 위하여 활성금속 Pt를 기본으로 한 촉매에 습식함침법으로 제조하였다. 제조된 촉매들은 XPS, CO-chemisorption, BET를 이용하여 특성분석을 수행하였다. 다양한 $Pt/Al_2O_3$계 촉매는 열처리 조건에 따라서 촉매를 제조할 경우 전자 전하의 이동으로 발생하는 전기음성도 특성이 Pt의 산소종을 제어하였다. Pt의 담지량이 증가함에 따라 분산도가 감소하는 이유는 Pt의 HT (Huttig Temperature)에 기인한 것으로 보인다. 또한 상온에서 제어할 수 있는 최소 수소농도는 metallic Pt가 촉매 내 70.09% 이상에서 1.0 vol%까지 수소를 제어할 수 있었다.