• 한국분무공학회지
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• 제15권4호
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• pp.182-188
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• 2010

Significant real fluid behaviors including rapid property changes take place where high pressure combustion devices such as rocket engines. The flamelet model is the reliable approach to account for the real fluid effects. In the present study, the flamelet equations are extended to treat the general fluids over transcritical and supercritical states. The real fluid flamelet model is carried out for the gaseous hydrogen and cryogenic liquid oxygen flames at the wide range of thermodynamic conditions. Based on numerical results, the precise discussions are made for effects of real fluid, pressure, and differential diffusion on the local flame structure.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 추계학술대회 논문집
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• pp.157-158
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• 2007

Effects of post-metallization anneal (PMA) on interface trap characteristics of Si-$SiO_2$ are studied. The conventional PMA method utilizes forming gas anneal, where 10% hydrogen in nitrogen atmosphere is used. A new PMA method utilizes hydrogen rich PECVD- silicon nitride $(SiN_x)$ film as a hydrogen diffusion source and a out-diffusion blocking layer. It can be shown through charge pumping current measurement that the new PMA is indeed effective to decrease Si-$SiO_2$ interface trap density.

• 한국표면공학회지
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• 제42권5호
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• pp.232-239
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• 2009

This study presented the effect of membrane thickness on hydrogen permeability. Microvoids on the surface of the membrane should not exist for the exact values of hydrogen permeability. Pd-Cu-Ni hydrogen alloy membranes were fabricated by Ni powder sintering, substrate plasma pretreatment, sputtering and Cu reflow process. And this leaded to void-free surface and dense film of Pd-Cu-Ni hydrogen alloy membrane. Hydrogen permeation test showed that hydrogen permeability increased from 2.7 to $15.2ml/cm^2{\cdot}min{\cdot}atm^{0.5}$ as membrane thickness decreased from 12 to $4{\mu}m$. This represented the similar trend as a hydrogen permeability of pure palladium membrane based on solution-diffusion mechanism.

• 한국수소및신에너지학회논문집
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• 제16권4호
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• pp.324-333
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• 2005

The kinetics of external hydrogen embrittlememt is considered. The equation of the crack growth rate (CGR) is derived from modification of the model developed by Wilkinson and Vitek. After calculation of hydrogen pressure build-up in the void, the effect of the internal hydrogen pressure on the void growth is added. The CGR is expressed by two terms. One is the term dependent on the critical stress, which is exactly same as Wilkinson and Vitek. The other is term dependent on the pressure of the hydrogen in void.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.216-216
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• 2012

The interaction of hydrogen with ZnO single crystal surfaces, ZnO (0001), ZnO (000-1), and ZnO (10-10) has been investigated using temperature programmed desorption (TPD) and X-ray photoelectron Spectroscopy (XPS) techniques. When the ZnO single crystal surfaces are exposed to atomic hydrogen at 200 K, all three surfaces show hydrogen desorption at 450 K. ZnO (0001) surface shows hydrogen desorption feature at ~260 K as the hydrogen exposure is increased. The ZnO (10-10) surface shows low-temperature desorption feature first and the high-temperature desorption feature appears as the hydrogen exposure increases. The ZnO (000-1) surface does not show any lower temperature hydrogen desorption. We will report the adsorption configuration of hydrogen atoms on ZnO single crystal surfaces with different surfaces structures.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2008년도 추계학술대회 논문집
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• pp.65-66
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• 2008

• 한국연소학회지
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• 제10권3호
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• pp.34-41
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• 2005

Hydrogen safety is one of the key technical issue with growing attention on utilization of hydrogen energy. This study is aimed to predict behavior of momentum-controlling buoyant jet and flame caused by hydrogen leakage from a high pressured tank. Approximate solutions were derived for the case of turbulent buoyant jet and diffusion flame in still air. In case of hydrogen jet with low Froude number (100-4000), computed jet trajectories were compared with experimental data and showed good agreement with them. Jet and flame trajectories and flame length of hydrogen are predicted and compared with the buoyant flame of propane. The results well show that buoyancy is dominant in the range of low Froude number, while initial momentum is dominant in the range of high Froude number. That effect is more distinct for hydrogen flame than the case of propane.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2005년도 제31회 KOSCO SYMPOSIUM 논문집
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• pp.207-214
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• 2005

Hydrogen safety is one of the key technical issue with growing attention on utilization of hydrogen energy. This study is aimed to predict behavior of momentum-controlling buoyant jet and flame caused by hydrogen leakage from a high pressured tank. Approximate solutions were derived for the case of turbulent buoyant jet and diffusion flame in still air. In case of hydrogen jet with low Froude number (100-4000), computed jet trajectories were compared with experimental data and showed good agreement with them. Jet and flame trajectories and flame length of hydrogen are predicted and compared with the buoyant flame of propane. The results well show that buoyancy is dominant in the range of low Froude number, while initial momentum is dominant in the range of high Froude number. That effect is more distinct for hydrogen flame than the case of propane.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 추계학술대회 논문집
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• pp.476-479
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• 2000

In this study, mesh-type PECVD system was suggested to minimize the hydrogen concentration. The main structural difference between the triode system and a conventional system is that a mesh was attached to the substrate holding electrode. We investigated several conditions to compare with conventional PECVD. The main effect of mesh was to minimize the substrate damage by ion bombardment and to enhance the surface reaction to induce hydrogen desorption. It was also found that hydrogen concentration decreased but deposition rate increased as increasing applied dias. Applied DC bias enhanced sputtering process. Intense ion bombardment causes the weakly bonded hydrogen or hydrogen-containing species to leave the growing film and increased adatom mobility. Furthermore, addition of hydrogen gas enhance the surface diffusion of adatom. The structural properties of poly-Si films were analyzed by scanning electron microscopy(SEM).

• 공업화학
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• 제33권6호
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• pp.653-660
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• 2022

In liquid hydrogen storage tanks, tank damage or leakage in the surrounding pipes possess a major risk. Since these tanks store huge amounts of the fluid among all the liquid hydrogen process facilities, there is a high risk of leakage-related accidents. Therefore, in this study, we conducted a risk assessment of liquid hydrogen leakage for a grid-type liquid hydrogen storage tank (lattice-type pressure vessel (LPV): 18 m³) that overcame the low space efficiency of the existing pressure vessel shape. Through a commercially developed three-dimensional computational fluid dynamics program, the geometry of the site, where the liquid hydrogen storage tank will be installed, was obtained and simulations of the leakage scenarios for each situation were performed. From the computational flow analysis results, the pool formation behavior in the event of liquid hydrogen leakage was identified, and the resulting damage range was predicted.