• 한국수소및신에너지학회논문집
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• 제26권4호
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• pp.308-317
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• 2015

To investigate the effect of microstructure on the formation of the desorption peak, the volumetric thermal analysis technique (VTA) was applied to the Mg-13.5 wt% Ni hydride system. The sample made by the HCS (hydriding combustion synthesis) process had two kinds of Mg microstructures. Linear heating was started with various constant heating rates. Only one peak was appeared in the case of the small initial hydrogen wt% (0.83 wt%). Yet, two peaks were appeared with increasing initial hydrogen wt% (1.85 and 3.73 wt%) when only Mg was hydrogenated. The first peak was formed through the evolution of hydrogen from $MgH_2$, made by eutectic Mg. The second peak was formed through the evolution of hydrogen from $MgH_2$, made by primary Mg. Therefore, this result shows that the microstructure also has a considerable effect on forming the desorption peak. We have also derived the hydrogen desorption equations by VTA to get apparent activation energy when the rate-controlling step for the desorption of the hydrided system is the diffusion of hydrogen through the ${\alpha}$ phase and the chemical reaction ${\beta}{\rightarrow}{\alpha}$.

• 대한금속재료학회지
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• 제46권5호
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• pp.296-303
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• 2008

Hydrogen permeation through dense palladium-based membranes has attracted the attention of many scientists largely due to their unmatched potential as hydrogen-selective membranes for membrane reactor applications. Although it is well known that the permeation mechanism of hydrogen through Pd involves various processes such as dissociative adsorption, transitions to and from the bulk Pd, diffusion within Pd, and recombinative desorption, it is still unclear which process mainly limits hydrogen permeation at a given temperature and hydrogen partial pressure. In this study, we report an all-electron density-functional theory study of hydrogen permeation through Pd membrane (using VASP code). Especially, we focus on the variation of the energy barrier of the penetration process from the surface to the bulk with hydrogen coverage, which means the large reduction of the fracture stress in the brittle crack propagation considering Griffith's criterion. It is also found that the penetration energy barrier from the surface to the bulk largely decreases so that it almost vanishes at the coverage 1.25, which means that the penetration process cannot be the rate determining process.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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• pp.280-280
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• 2012

We examined ammonia diffusion on the surface of amorphous ice film through the measurement of decreasing residual quantity of $NH_3$ molecules compared to $H_2O$. The populations of $NH_3$ molecules on the surface of amorphous ice were monitored by using the techniques of temperature programmed reactive ion scattering (TPRIS) method. The ratio of intensity between ammonia and water was examined as a function of time at controlled temperature. When ammonia molecules were externally added onto an ice film at a temperature of 80 K, ammonia coverage with regard to ice was 0.12-0.16 ML. The intensity of ammonia molecules on the surface of ice decreased as time increased and the extent of decreased intensity of ammonia increased as controlled temperature increased. Moreover, energy barrier was estimated to be $51kJmol^{-1}$ on amorphous ice film. The results of the experiment indicate that ammonia molecules have a property of vertical diffusion into amorphous ice and the energy barrier of ammonia diffusion into bulk of ice is higher than that of hydrogen bonding.

• 설비공학논문집
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• 제15권10호
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• pp.828-834
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• 2003

A diffusion absorption refrigerator is a heat-generated refrigeration system. It uses a three-component working fluid consisting of the refrigerant (ammonia), the absorbent (water) and the auxiliary gas (hydrogen or helium). In this study, experimental investigations have been carried out to examine the effects of charging conditions of working fluids on the evaporating temperature for diffusion absorption refrigerator. Experimental parameters considered in the present experiments are charging concentration, solution charge and system pressure determined by auxiliary gas charged. As a result, in the charging condition of 35% of concentration and 20 kg$_{f}$cm$^2$ of system pressure, the system has the lowest evaporating temperature. It was found that there exists a minimum value of solution charge for the operation of diffusion absorption refrigerator.r.

• Corrosion Science and Technology
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• 제6권4호
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• pp.164-169
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• 2007

Hydrogen induced cracking (HIC) was studied phenomenologically and the effect of microstructure on HIC was discussed for the steels having two different levels of nonmetallic inclusions. Steels having different microstructures were produced by thermomechanically controlled processes (TMCP) from two different heats which had the different level of nonmetallic inclusions. Ferrite/pearlite (F/P), ferrite/acicular ferrite (F/AF), ferrite/bainite (F/B) were three representative microstructures for all tested steels. For the steels with higher level of inclusions, permissible inclusion level for HIC not to develop was different according to steelmicrostructure. On the contrary, HIC occurred also at the martensite/austenite (M/A) constituents regardless of steel microstructure when they accumulated to a certain degree. It was proved that M/A constituents were easily embrittled by hydrogen atoms. Steels having F/AF is resistant to HIC at a given actual service condition since they covers a wide range of diffusible hydrogen content without developing HIC.

• 한국수소및신에너지학회논문집
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• 제5권2호
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• pp.59-63
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• 1994

Thermally evaporated Pd films on substrate were hydrogenated upto 1 bar of hydrogen gas at room temperature. Thickness dependence on hydrogenation on Pd film is examined in the thickness range between $60{\AA}$ and $800{\AA}$. Hydrogenation kinetics of thinner films(thinner than $500{\AA}$) and that of thicker films are different. Thin film(thickness < $200{\AA}$, substrate temp. = RT) showed recrystallization due to hydrogen induced heat. Hydrogen was absorbed by chemisorption process in ${\alpha}$ phase of thinner films, and diffusion process in ${\alpha}'$ phase of thicker films respectively.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2007년도 제34회 KOSCO SYMPOSIUM 논문집
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• pp.7-12
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• 2007

To reveal the newly found liftoff height behavior of hydrogen jet, we have experimentally studied the stabilization mechanism of turbulent, lifted jet flames in a non-premixed condition. The objectives of the present research are to report the phenomenon of a liftoff height decreasing as increasing fuel velocity, to analyse the flame structure and behavior of the lifted jet, and to explain the mechanisms of flame stability in hydrogen turbulent non-premixed jet flames. The velocity of hydrogen was varied from 100 to 300m/s and a coaxial air velocity was fixed at 16m/s with a coflow air less than 0.1m/s. For the simultaneous measurement of velocity field and reaction zone. PIV and OH PLIF technique was used with two Nd:Yag lasers and CCD cameras. As results, it has been found that the stabilization of lifted hydrogen diffusion flames is related with a turbulent intensity, which means that combustion occurs where the local flow velocity is valanced with the turbulent flame propagation velocity.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 추계학술대회 논문집 학회본부 A
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• pp.442-445
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• 1999

In this work, to detect of hydrogen in DI water in the generator area of nuclear power plants was fabricated Pd/Pt gate MISFET sensor using Pd membrane. $H_2$ permeation through Pd accounts for external mass transfer, surface adsorption and desorption, transitions to and from the bulk metal, and diffusion within the metal. The identification of pinholes in the generator area of plant is an important safety consideration, as hydrogen build-up gives rise to explosion. For this type of application the sensor needs to be isolated in DI water, accordingly, a Pd membrane was used to separate the DI water. The hydrogen in the DI water was then absorbed on the Pd thin film and diffused into the oil through the thin film. The Pd/Pt gate MISFET sensor, encapsulated by oil, will thereby detect permeated hydrogen.

• 에너지공학
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• 제24권2호
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• pp.84-90
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• 2015

Hydrogen has some remarkably high values of the key properties for transport processes, such as kinematic viscosity, thermal conductivity and diffusion coefficient. Hydrogen, as an energy medium, has some distinct benefits for its high efficiency and convenience in storage, transportation and conversion. Hydrogen has much wider limits of flammability in air than methane, propane or gasoline and the minimum ignition energy is about an order of magnitude lower than for other combustibles. Statistical thermodynamics provides the relationships that we need in order to bridge this gap between the macro and the micro. Our most important application will involve the calculation of the thermodynamic properties of the ideal gas.

• Nuclear Engineering and Technology
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• 제37권6호
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• pp.537-556
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• 2005

A primary-pipe rupture accident is one of the design-basis accidents of a High-Temperature Gas-cooled Reactor (HTGR). When the primary-pipe rupture accident occurs, air is expected to enter the reactor core from the breach and oxidize in-core graphite structures. This paper describes an experiment and analysis of the air ingress phenomena and the method fur the prevention of air ingress into the reactor during the primary-pipe rupture accident. The numerical results are in good agreement with the experimental ones regarding the density of the gas mixture, the concentration of each gas species produced by the graphite oxidation reaction and the onset time of the natural circulation of air. A hydrogen production system connected to the High-Temperature Engineering Test Reactor (HTTR) Is being designed to be able to produce hydrogen by themo-chemical iodine-Sulfur process, using a nuclear heat of 10 MW supplied by the HTTR. The HTTR hydrogen production system is first connected to a nuclear reactor in the world; hence a permeation test of hydrogen isotopes through heat exchanger is carried out to obtain detailed data for safety review and development of analytical codes. This paper also describes an overview of the hydrogen permeation test and permeability of hydrogen and deuterium of Hastelloy XR.