• 한국추진공학회지
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• 제19권3호
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• pp.96-102
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• 2015

기존에 사용되고 있는 대부분의 추진물질들은 연소 시 이산화탄소, 염산가스 등의 환경유해 물질을 다량 발생시킨다. 본 연구에서는 이러한 문제점을 개선하기 위한 테트라진 계열의 저탄소 고질소 화합물인 DAAT의 합성공정을 확립하였다. 또한, 문헌에 빠져있는 구체적인 공정법 및 특성 분석 결과를 서술하였다. 그리고 분광분석(NMR, IR)을 통한 DAAT의 구조분석과 열, 충격, 마찰 안정성을 측정하였고, Gaussian 09와 EXPLO5를 이용하여 생성열과 폭발 특성(폭압, 폭속) 등을 계산하였다.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2003년도 제20회 춘계학술대회 논문집
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• pp.32-33
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• 2003

Mechanism of a periodic oscillation of shock-induced combustion over a two- dimensional wedges and axi-symmetric cones were investigated through a series of numerical simulations at off-attaching condition of oblique detonation waves(ODW). A same computational domain over 40 degree half-angle was considered for two-dimensional and axi-symmetric shock-induced combustion phenomena. For two-dimensional shock-induced combustion, a 2H2+02+17N2 mixture was considered at Mach number was 5.85with initial temperature 292 K and initial pressureof 12 KPa. The Rankine-Hugoniot relation has solution of attached waves at this condition. For axi-symmetric shock-induced combustion, a H2+2O2+2Ar mixture was considered at Mach number was 5.0 with initial temperature 288 K and initial pressure of 200 mmHg. The flow conditions were based on the conditions of similar experiments and numerical studies.[1, 3]Numerical simulation was carried out with a compressible fluid dynamics code with a detailed hydrogen-oxygen combustion mechanism.[4, 5] A series of calculations were carried out by changing the fluid dynamic time scale. The length wedge is varied as a simplest way of changing the fluid dynamic time scale. Result reveals that there is a chemical kinetic limit of the detached overdriven detonation wave, in addition to the theoretical limit predicted by Rankine-Hugoniot theory with equilibrium chemistry. At the off-attaching condition of ODW the shock and reaction waves still attach at a wedge as a periodically oscillating oblique shock-induced combustion, if the Rankine-Hugoniot limit of detachment isbut the chemical kinetic limit is not.Mechanism of the periodic oscillation is considered as interactions between shock and reaction waves coupled with chemical kinetic effects. There were various regimes of the periodicmotion depending on the fluid dynamic time scales. The difference between the two-dimensional and axi-symmetric simulations were distinct because the flow path is parallel and uniform behind the oblique shock waves, but is not behind the conical shock waves. The shock-induced combustion behind the conical shockwaves showed much more violent and irregular characteristics.From the investigation of characteristic chemical time, condition of the periodic instability is identified as follows; at the detaching condition of Rankine-Hugoniot theory, (1) flow residence time is smaller than the chemical characteristic time, behind the detached shock wave with heat addition, (2) flow residence time should be greater than the chemical characteristic time, behind an oblique shock wave without heat addition.

• Nuclear Engineering and Technology
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• 제41권5호
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• pp.575-602
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• 2009

In the wake of the Three Mile Island accident, vigorous research efforts were initiated to acquire a basic knowledge of the progression and consequences of accidents that involve a substantial degree of core degradation and melting. The primary emphasis of this research was placed on containment integrity, with: i) hydrogen combustion-detonation, ii) steam explosion, iii) direct containment heating (DCH), and iv) melt attack on the BWR Mark-I containment shell identified as energetic processes that could lead to early containment failure (i.e., within the first 24 hours of the accident). Should the core melt fail the reactor vessel, then non-condensable gas production from Molten Core-Concrete Interaction (MCCI) was identified as a mechanism that could fail the containment by pressurization over the long term. One signification question that arose as part of this investigation was the effectiveness of water in terminating an MCCI by flooding the interacting masses from above, thereby quenching the molten core debris and rendering it permanently coolable. Successful quenching of the core melt would prevent basemat melt through, as well as continued containment pressurization by non-condensable gas production, and so the accident progression would be successfully terminated without release of radioactivity to the environment. Based on these potential merits, ex-vessel corium coolability has been the focus of extensive research over the last 20 years as a potential accident management strategy for current plants. In addition, outcomes from this research have impacted the accident management strategies for the Gen III+LWR plant designs that are currently being deployed around the world. This paper provides: i) an historical overview of corium coolability research, ii) summarizes the current status of research in this area, and iii) highlights trends in severe accident management strategies that have evolved based on the findings from this work.

• 한국추진공학회지
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• 제1권1호
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• pp.8-23
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• 1997

스탠포드 대학의 expansion tube 장치를 이용한 램 가속기의 유동장의 실험적 연구와 비교를 위하여 정상 및 비정상 상태의 수치모사를 수행하였다. 수소/공기 연소에 대하여 9 화학종 19 반응 단계를 가지는 Jachimowski의 화학반응 모델을 이용하여 화학 반응 유동에 대한 Navier-Stokes 방정식을 시간 정확도를 가지는 완전 내재적수치 기법을 이용하여 해석하였다. 정상 상태 가정을 이용한 수치해석은 $2H_2$＋$O_2$＋$17N_2$에 대하여 쉴리렌 및 OH PLIF 을 이용하여 실험적으로 얻어진 영상과 부합하는 좋은 결과를 보였으나 $2H_2$＋$O_2$＋$12N_2$ 혼합기에 대해서는 충격파 교차점 후방의 연소 영역을 모사하지 못하였다. 따라서 이 경우에 대하여 비정상 수치 모사를 수행하였으며 자세한 유동 안정화 과정을 보여 주었다. 비정상 수치 모사의 결과로부터 실험적으로 얻어진 영상은 유동 안정화 단계의 일시적 상태의 결과로 보인다. 충격파 교차점 후방의 연소 영역은 유동이 안정화되는 초기 단계에 존재하는 강한 경사 충격파가 교차하여 발생하는 수직 폭굉파의 결과이다. 최종 단계에서 충격파 교차점 이후의 연소 영역은 사라지며 정상 상태의 결과가 얻어진다. 램 가속기 모델 내부의 화학반응 유동이 안정화되는데 필요한 시간은 실험적인 시험 시간과 비교하여 매우 긴 것으로 보인다.