• Proceedings of the Korean Nuclear Society Conference
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• 2005.05a
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• pp.43-44
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• 2005

• Journal of computational fluids engineering
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• v.10 no.3 s.30
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• pp.9-18
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• 2005

During a hypothetical severe accident in a nuclear power plant (NPP), hydrogen is generated by the active reaction of fuel-cladding and steam in the reactor pressure vessel and released with steam into the containment. In order to mitigate hydrogen hazards possibly occurred in the NPP containment, hydrogen mitigation system (HMS) is usually adopted. The design of the next generation NPP (APR1400) designed in Korea specifies 26 passive autocatalytic recombiners and 10 igniters installed in the containment for the hydrogen mitigation. in this study, the analysis of the hydrogen and steam behavior during a total lose of feed water (TLOFW) accident in the APR1400 containment has been conducted by using the CFD code GASFLOW. During the accident, a huge amount of hot water, steam, and hydrogen is released in the in-containment refueling water storage tank (IRWST). The current design of the APR1400 includes flap-type dampers at the IRWST vents which are operated depending on the pressure difference between inside and outside of the IRWST. it was found that the flaps strongly affects the flow structure of the steam and hydrogen in the containment. The possibilities of a flame acceleration and transition from deflagration to detonation (DDT) were evaluated by using Sigma-Lambda criteria. Numerical results indicate the DDT possibility could be heavily reduced in the IRWST compartment when the flaps are installed.

• Applied Chemistry for Engineering
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• v.33 no.6
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• pp.653-660
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• 2022

In liquid hydrogen storage tanks, tank damage or leakage in the surrounding pipes possess a major risk. Since these tanks store huge amounts of the fluid among all the liquid hydrogen process facilities, there is a high risk of leakage-related accidents. Therefore, in this study, we conducted a risk assessment of liquid hydrogen leakage for a grid-type liquid hydrogen storage tank (lattice-type pressure vessel (LPV): 18 m³) that overcame the low space efficiency of the existing pressure vessel shape. Through a commercially developed three-dimensional computational fluid dynamics program, the geometry of the site, where the liquid hydrogen storage tank will be installed, was obtained and simulations of the leakage scenarios for each situation were performed. From the computational flow analysis results, the pool formation behavior in the event of liquid hydrogen leakage was identified, and the resulting damage range was predicted.

• Corrosion Science and Technology
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• v.5 no.4
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• pp.117-122
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• 2006

Hydrogen permeation measurements have been carried out on API X65 grade linepipe steel. In order to study the effect of steel microstructure on hydrogen diffusion behavior in linepipe steel, the accelerated cooling condition was applied and then three different kinds of microstructures were obtained. Hydrogen permeation measurement has been performed in reference to modified ISO17081 (2004) and ZIS Z3113 method. Hydrogen trapping parameters in these steels were evaluated in terms of the effective diffusivity ($D_{eff}$), permeability ($J_{ss}L$) and the amount of diffusible hydrogen. In this study, microstructures which affect both hydrogen trapping and diffusion were degenerated pearlite (DP), acicular ferrite (AF), bainite and martensite/austenite constituents (MA). The low $D_{eff}$ and $J_{ss}L$ mean that more hydrogen can be trapped reversibly or irreversibly and the corresponding steel microstructure is dominant hydrogen trapping site. The large amount of diffusible hydrogen means that corresponding steel microstructure is predominantly reversible. The results of this study suggest that the hydrogen trapping efficiency increases in the order of DP, bainite and AF, while AF is the most efficient reversible trap.

• Journal of Power System Engineering
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• v.21 no.4
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• pp.34-41
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• 2017

Diesel engines with compression-ignition type have superior thermal efficiency, durability and reliability compared to gasoline engine. To control emitted gas from the engines, it can be applied to alternative fuel without any modification to the engine. Therefore, in this study, as a basic study for applying emulsified fuel to the actual diesel engine, analysis of spray behavior characteristics of emulsified fuel was carried out simultaneously by experimental and numerical method. The emulsified fuel consist of diesel, hydrogen peroxide, and surfactant. The surfactant for manufacturing emulsified fuel is comprised of span 80 and tween 80 mixed as 9:1 and fixed with 3% of the total volume of the emulsified fuel. In addition, six kinds of emulsified fuel(EF0, EF2, EF12, EF22, EF32, and EF42) were manufactured according to the mixing ratio of hydrogen peroxide. The droplet and spray experiments were performed to observe the behavior characteristics of the emulsified fuel. The numerical analysis was carried out using ANSYS CFX to confirm the microscopic behavior characteristics. Consequently, rapid mixture formation can be expected due to evaporation of hydrogen peroxide in emulsified fuel, and it is confirmed that Reitz&Diwakar breakup model is most suitable as breakup model to be applied to the numerical analysis.

• Journal of Ecology and Environment
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• v.40 no.3
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• pp.136-143
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• 2016

Background: Mussels are stubborn organisms attached to solid substrata by means of byssus threads. The abundance of marine mussel Mytilus edulis in marine facilities like power stations was reason to select among fouling animals. Methods: Mortality patterns as well as physiological behavior (oxygen consumption, foot activity, and byssus thread production) of two different size groups (14- and 25-mm shell length) of M. edulis were studied at different hydrogen peroxide concentrations ($1-4mg\;l^{-1}$). Results: Studied mussels showed progressive reduction in physiological activities as the hydrogen peroxide concentration increased. Mussel mortality was tested in 30 days exposure, and 14 mm mussels reached the highest percentage of 90% while 25 mm mussels reached 81%. Produced data was echoed by Chick-Watson model extracted equation. Conclusions: This study points that, while it could affect the mussel mortality moderately in its low concentrations, hydrogen peroxide has a strong influence on mussels' physiological activities related to colonization. Therefore, hydrogen peroxide can be an alternative for preventing mussel colonization on facilities of marine environment.

• Korean Journal of Materials Research
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• v.13 no.9
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• pp.631-634
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• 2003

To fabricate W-Cu nanocomposite powder, $WO_3$-CuO powder mixture was high-energetically ball-milled and subsequently hydrogen-reduced. The effect of ball-milling on the hydrogen-reduction behavior of$ WO_3$-CuO was investigated with non-isothermal hygrometric analysis during hydrogen-reduction. Increasing the ball-milling time, the reduction peak temperatures of humidity curves were shifted to low temperature. It was considered that the reduction temperature should be decreased because the specific surface area of each oxide considerably increased with increasing the ball-milling time. In case of ball-milling for 0 h, $WO_3$and CuO were independently hydrogen-reduced and W particles were nucleated on the surface of Cu adjacent to W by CVT. However, in case of ball-milling for 50 h, the aggregates of about 200-300 nm were observed. W particles of size below 30-50 nm were homogeneously distributed with Cu in the aggregates.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.2
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• pp.123-128
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• 2010

Hydriding combustion synthesis (HCS) can produce full hydrides of alloys and in a short time. The conventional process based on ingot metallurgy cannot produce Mg-based alloy easily with the desired composition and the cast product needs a ling activation process for the practical use of hydrogen storage. In this study, the hydriding properties of Mg-xNi (x=5, 13.5, 54.7wt.%) alloys prepared by hydriding combustion synthesis were evaluated. The hydrogen storage capacity and kinetics of HCS Mg-xNi alloys were strongly dependent on the content of Ni. The HCS Mg-13.5wt.%Ni alloy shows the hydriding behavior to reach the maximum capacity within 30 min. and the reversible $H_2$ storage of 5.3wt.% at 623 K.

• Journal of the Korean Society for Heat Treatment
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• v.31 no.6
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• pp.283-289
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• 2018

This present study deals with the hydrogen embrittlement properties of austenitic Fe-30Mn-0.2C(-1.5Al) high-manganese steels for cryogenic applications. They were electrochemically charged with hydrogen and then subjected to tensile tests for evaluating hydrogen embrittlement behavior. Tensile test results showed that after hydrogen charging the tensile strength and elongation of the Al-free steel were more remarkably decreased with increasing current density when compared to the Al-added steel. After hydrogen charging of the Al-added steel, it was found that the measured hydrogen content was small and silver particles were relatively less decorated. Therefore, the Al-added steel has a superior hydrogen embrittlement resistance to the Al-free steel because the addition of Al suppresses the injection of hydrogen during electrochemical hydrogen charging.

• Journal of the Korean institute of surface engineering
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• v.46 no.1
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• pp.42-47
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• 2013

The strain-induced phase transformation from austenite to martensite is responsible for the high strength and ductility of TRIP steels. However high strength steels are susceptible to hydrogen embrittlement. This study aimed to evaluate the effects of hydrogen on the behavior of hydrogen delayed fracture in TRIP steel with hydrogen charging conditions. The electrochemical hydrogen charging was conducted at each specimen with varying current density and charging time. The relationship between hydrogen concentration and mechanical properties of TRIP steel was established by SP test and SEM fractography. The maximum loads and displacements of the TRIP steel in SP test decreased with increasing hydrogen charging time. The results of SEM fractography investigation revealed typical brittle mode of failure. Thus it was concluded that hydrogen delayed fracture in TRIP steel result from the diffusion of hydrogen through the ${\alpha}$' phase.