• 한국수소및신에너지학회논문집
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• 제26권2호
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• pp.120-126
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• 2015

Recently, the ever-increasing use of fossil fuels for rapid industrial development and population significantly caused an environment pollution and global warming such as climate change. So research and development of sustainable and eco-friendly energy have been performed. Especially the interest in nuclear fusion fuel was significantly increased from the developed countries. The system of fusion energy production was tritium separation, storage and delivery, and purification. Republic of Korea is in charge of Storage and Delivery System (SDS) in the International Thermonuclear Experimental Reactor (ITER). Welding part of the SDS bottles for storing the tritium is known to be susceptible to hydrogen embrittlement. In this study, conducted a study for the relaxation of the stability and hydrogen embrittlement of the weld area. The hydrogen heat treatment was processed through the Pressure-Composition-Temperature (PCT) device according to the time variation. Also mechanical properties such as impact test and hardness test according to using the alkaline cleaning liquid for hydrogen embrittlement relief and the fracture was observed by scanning electron microscopy (SEM) after the mechanical properties evaluation.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2005년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
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• pp.274-276
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• 2005

This paper present an effective modeling scheme of SPE cell system for hydrogen production. As oxygen and hydrogen produced by water electrolysis using SPE are high purity, we can use oxygen in biomedical and hydrogen could be used in many ways. Recently, it is under the eye as a surplus power storage system. PSCAD/EMTDC model of SPE cell system for hydrogen production to efficiently utilize solar cell energy is showed in this paper. The simulated results are then verified by comparing them with the actual values obtained from the data acquisition system. Authors are sure that it is a useful method to the researchers who study SPE cell system for hydrogen production.

• 동력기계공학회지
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• 제19권5호
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• pp.60-66
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• 2015

Embrittlement of material by hydrogen charging should be cleared for safety of storage vessel of hydrogen and components deal with hydrogen. A stainless steel is generally used as materials for hydrogen transportation and storage, and it has a big advantage of corrosion resistance due to nickel component in material. In this study, microscopic damage behavior of stainless steel according to the hydrogen charging time using nondestructive evaluation was studied. The surface of stainless steel became more brittle as the hydrogen charging time increased. The parameters of nondestructive evaluation were also changed with the embrittlement of stainless steel surface by hydrogen charging. Ultrasonic test, which is the most generalized nondestructive technique, was applied to evaluate the relationship between the ultrasonic wave and mechanical properties of stainless steel by hydrogen charging. The attenuation coefficient of ultrasonic wave was increased with hydrogen charging time because of surface embrittlement of stainless steel. In addition, acoustic emission test was also used to study the dynamic behavior of stainless steel experienced hydrogen charging. AE event at the hydrogen charged specimen was obviously decreased at the plastic zone of stress-strain curves, while the number of event for the specimen of hydrogen free was dramatically generated when compared with the specimens underwent hydrogen charging.

• 한국군사과학기술학회지
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• 제20권4호
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• pp.528-535
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• 2017

Fuel cells have been spotlighted in the world for being highly efficient and environmentally friendly. A hydrogen which is the fuel of fuel cell can be obtained from a number of sources. Hydrogen source for operating the polymer electrolyte membrane fuel cell(PEMFC) in the current underwater environment, such as a submarine and unmanned underwater vehicles are currently from the metal hydride cylinder. However, metal hydride has many limitations for using hydrogen carrier, such as large volume, long charging time, limited storage capacity. To solve these problems, we suggest diesel reformer for hydrogen supply source. Diesel fuel has many advantages, such as high hydrogen storage density, easy to transport and also well-infra structure. However, conventional diesel reforming system for PEMFC requires a large volume and complex CO removal system for lowering the CO level to less than 10 ppm. In addition, because the preferential oxidation(PROX) reaction is the strong exothermic reaction, cooling load is required. By changing this PROX reactor to hydrogen separation membrane, the problem from PROX reactor can be solved. This is because hydrogen separation membranes are small and permeable to pure hydrogen. In this study, we conducted the pressurized diesel reforming and water-gas shift reaction experiment for the hydrogen separation membrane application. Then, the hydrogen permeation experiments were performed using a Pd alloy membrane for the reformate gas.

• 한국안전학회지
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• 제39권2호
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• pp.75-86
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• 2024

Hydrogen has been selected as one of the key technologies for reducing CO₂ emissions to achieve carbon neutrality by 2050. However, hydrogen safety issues should be fully guaranteed before the commercial and widespread utilization of hydrogen. Here, a bow-tie risk assessment is conducted for the hydrogen fuel supply system in a gas turbine power plant, which can be a mass consumption application of hydrogen. The bow-tie program is utilized for a qualitative risk assessment, allowing the analysis of the causes and consequences according to the stages of accidents. This study proposed an advanced bow-tie method, which includes the barrier criticality matrix and visualized maps of quantitative risk reduction. It is based on evaluating the importance of numerous barriers for the extent of their impact. In addition, it emphasizes the prioritization and concentrated management of high-importance barriers. The radar chart of a bow tie allows the visual comparison of risk levels before/after the application of barriers (safety measures). The risk reduction methods are semi-quantitatively analyzed utilizing the criticality matrix and radar chart, and risk factors from multiple aspects are derived. For establishing a secure hydrogen fuel storage system, the improvements suggested by the bow-tie risk assessment results, such as 'Ergonomic equipment design to prevent human error' and 'Emergency shutdown system,' will enhance the safety level. It attempts to contribute to the development and enhancement of an efficient safety management system by suggesting a method of calculating the importance of barriers based on the bow-tie risk assessment.

• 한국수소및신에너지학회논문집
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• 제12권3호
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• pp.177-189
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• 2001

T hydrogen absorption-desorption behavior induced by thermal or hydrogen pressure cycling in a closed system was observed in hydrogen storage alloys, $(La-R-Mm)Ni_{4.5}Fe_{0.5}$, $MmNi_4Fe_{0.85}Cu_{0.15}$ and $(Ce-F-Mm)Ni_{4.7}Al_{0.2}Fe_{0.1}$. Thereby (La-R-Mm), Mm and (Ce-F-Mm) refer to La-rich mischmetal, mischmetal and Ce-free mischmetal respectively. As the results, it is found that the alloy stabilities during thermal cycling varies with alloy composition change. The highest stability occurs in $MmNi_4Fe_{0.85}Cu_{0.15}$ and the lowest stability in $(La-R-Mm)Ni_{4.5}Fe_{0.5}$. Comparing hydrogen pressure cycling with thermal cycling, pressure cycling causes severer degradation of the alloy $(Ce-F-Mm)Ni_{4.7}Al_{0.2}Fe_{0.1}$ than thermal cycling. When the 1500 times-cycled alloy is annealed at $400^{\circ}C$ for 3hrs under 1 atm of hydrogen pressure the hydrogen storage capacity is recovered only partially but not completely to the initial capacity. The amount of capacity loss after annealing is larger in the hydrogen pressure cycled samples than in the thermal cycled, suggesting an incoming of impure gas during hydrogen pressure cycling.

• 한국수소및신에너지학회논문집
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• 제32권6호
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• pp.477-482
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• 2021

Hydrogen production, hydrogen production cost, and utilization rate were calculated assuming four cases of hydrogen production system in combination of photovoltaic power generation (PV), water electrolysis system (WE), battery energy storage system (BESS), and power grid. In the case of using the PV and WE in direct connection, the smaller the capacity of the WE, the higher the capacity factor rate and the lower the hydrogen production cost. When PV and WE are directly connected, hydrogen production occurs intermittently according to time zones and seasons. In addition to the connection of PV and WE, if BESS and power grid connection are added, the capacity factor of WE can be 100%, and stable hydrogen production is possible. If BESS is additionally installed, hydrogen production cost increases due to increase in Capital Expenditures, and Operating Expenditure also increases slightly due to charging and discharging loss. Even in a hydrogen production system that connects PV and WE, linking with power grid is advantageous in terms of stable hydrogen production and improvement of capacity factor.

• 한국수소및신에너지학회논문집
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• 제32권6호
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• pp.542-550
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• 2021

As the application of multirotor grows, the demands for multirotor that can fly longer and load more are increasing. Hydrogen has a high energy density, so it can satisfy these demands when used in multirotor. In order to design hydrogen fueled multirotor that satisfies the desired flight time and payload, it is important to calculate the specifications of a fuel cell, battery, and hydrogen storage system. This paper contains detailed information on various energy systems used in multirotor and fuel cell powered multirotor research trends. This study proposed a sizing calculation method that meets the target flight time and payload using thrust and power equations. It has been explained how the two equations derive the particular specifications. The specifications of the multirotor were derived by assuming a payload of 50 kg and a flight time of 1 hour. In addition, the effects of the values of the fuel cell, hydrogen storage system, and motor propeller were analyzed.

• Advanced Composite Materials
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• 제18권3호
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• pp.233-249
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• 2009

Safe installation and operation of high-pressure composite cylinders for hydrogen storage are of primary concern. It is unavoidable for the cylinders to experience temperature variation and significant thermal input during service. The maximum failure pressure that the cylinder can sustain is affected due to the dependence of composite material properties on temperature and complexity of cylinder design. Most of the analysis reported for high-pressure composite cylinders is based on simplifying assumptions and does not account for complexities like thermo-mechanical behavior and temperature dependent material properties. In the present work, a comprehensive finite element simulation tool for the design of hydrogen storage cylinder system is developed. The structural response of the cylinder is analyzed using laminated shell theory accounting for transverse shear deformation and geometric nonlinearity. A composite failure model is used to evaluate the failure pressure under various thermo-mechanical loadings. A back-propagation neural network (NNk) model is developed to predict the maximum failure pressure using the analysis results. The failure pressures predicted from NNk model are compared with those from test cases. The developed NNk model is capable of predicting the failure pressure for any given loading condition.

• 드라이브 ㆍ 컨트롤
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• 제19권2호
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• pp.36-44
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• 2022

Hydrogen energy as an alternative source of energy has been receiving tremendous support around the world, and research is being actively conducted accordingly. However, most of the studies focus on hydrogen storage tanks and only are few studies on interpreting the hydrogen filling system itself. In this study, with reference to SAE J2601, a hydrogen fueling protocol, a simulation model was developed that can confirm the behavior of the vehicle's internal tank during hydrogen fueling. With respect to factors such as fuel supply temperature, ambient temperature, and pressure increase rate, the developed model can check the change of temperature and pressure in the tank and the state of hydrogen charging during hydrogen fueling. The validity of the developed simulation model was confirmed by comparing the simulation results with the experimental results presented in SAE J2601.