• Journal of the Optical Society of Korea
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• 제3권2호
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• pp.69-73
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• 1999

This paper demonstrated the performance of a palladium wire hydrogen sensor based on a fiber Bragg grating as a means of developing a quasi-distributed hydrogen sensor network capable of operating at cryogenic temperatures. The new approach employing a fiber Bragg grating based palladium hydrogen sensor described in this study is advantageous over other traditional hydrogen sensors because of the multiplexing capability of fiber Bragg gratings. The sensitivity of the hydrogen sensor at room temperature is approximately 2.5 times that of the hydrogen sensor at cryogenic temperatures.

• 센서학회지
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• 제18권4호
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• pp.269-273
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• 2009

In this paper, a study on a portable hydrogen alarm system based on the palladium coated single mode fiber sensor has been reported. The fabricated hydrogen sensor exhibited 0.14 dB, 0.41 dB and 0.54 dB optical intensity variation when it was exposed by the nitrogen and hydrogen mixed gas containing 0.5 %, 1 % and 4 % of the hydrogen concentration, respectively. The fabricated sensor exhibited 20 second of response time and 120 second of recovery time for 4 % hydrogen containing gas. The fiber optics layout and software algorithm for detection of hydrogen leakage have been presented. The implanted portable hydrogen alarm system successfully generated an alarm signal when a 4 % hydrogen containing gas was leaked out.

• 한국재료학회지
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• 제29권5호
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• pp.297-303
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• 2019

A triple-layered $PMMA/Ni_{64}Zr_{36}/PDMS$ hydrogen gas sensor using hydrogen permeable alloy and flexible polymer layers is fabricated through spin coating and DC-magnetron sputtering. PDMS(polydimethylsiloxane) is used as a flexible substrate and PMMA(polymethylmethacrylate) thin film is deposited onto the $Ni_{64}Zr_{36}$ alloy layer to give a high hydrogen-selectivity to the sensor. The measured hydrogen sensing ability and response time of the fabricated sensor at high hydrogen concentration of 99.9 % show a 20 % change in electrical resistance, which is superior to conventional Pd-based hydrogen sensors, which are difficult to use in high hydrogen concentration environments. At a hydrogen concentration of 5 %, the resistance of electricity is about 1.4 %, which is an electrical resistance similar to that of the $Pd_{77}Ag_{23}$ sensor. Despite using low cost $Ni_{64}Zr_{36}$ alloy as the main sensing element, performance similar to that of existing Pd sensors is obtained in a highly concentrated hydrogen atmosphere. By improving the sensitivity of the hydrogen detection through optimization including of the thickness of each layer and the composition of Ni-Zr alloy thin film, the proposed Ni-Zr-based hydrogen sensor can replace Pd-based hydrogen sensors.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회B
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• pp.2009-2014
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• 2007

Hydrogen is a fuel of fuel cell system, which has powerful explosion possibility. Hence, the fuel cell system needs safety evaluation to prevent risk of hydrogen leakage. We use a actual size chamber of a common fuel cell module to analyze hydrogen. Hydrogen injection holes are located in lower part of the chamber in order to simulated hydrogen leakage. The hydrogen sensor can detect range of 0${\sim}$4%. Since the hydrogen gas, of which leaked amount is controled by MFC, are injected at the bottom holes, the transient sensor signals are measured. At a condition of 10cc/s of hydrogen leakage, the sensor detects hydrogen leakage after 22sec and there is also several seconds of time delay depending on the position of the sensor. This experimental data can be applied for the design of the hydrogen detection system and ventilation system of a residential fuel cell system.

• 조명전기설비학회논문지
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• 제27권3호
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• pp.1-6
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• 2013

In this study, we propose a fiber-optic hydrogen sensor using a polarization-diversity loop configuration composed of a polarization beam splitter, two quarter-wave plates, and a polarization-maintaining fiber coated with palladium whose thickness is ~400nm. One transmission dip of the output interference spectrum of the proposed sensor, chosen as a sensor indicator, was observed to spectrally shift with the increase of the hydrogen concentration, and the sensing indicator showed a wavelength shift of ~2.48nm at a hydrogen concentration of 4%. Except for a hydrogen concentration of 4%, the response time of the proposed sensor was measured as less than 12.5s and did not show significant dependence on the hydrogen concentration. In particular, the proposed fiber hydrogen sensor is more durable and highly resistant to external stress applied on a transverse axis of an optical fiber, compared with other hydrogen sensors based on side-polished fibers or fiber gratings.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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• pp.51.3-51.3
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• 2010

Due to the recent public awareness of global warming and sustainable economic growth, there has been a growing interest in alternative clean energy sources. Hydrogen is considered as a clean fuel for the next generation. One of the technical challenges related to the use of hydrogen is safe monitoring of the hydrogen leak during separation, purification and transportation. For detecting various gases, chemiresistor-type gas sensors have been widely studied and used due to their well-established detection scheme and low cost. However, it is known that many of them have the limited sensitivity and slow response time, when used at low temperature conditions. In our work, a sensor based on Schottky barriers at the electrode/sensing material interface showed promising results that can be utilized for developing fast and highly sensitive gas sensors. Our hydrogen sensor was designed and fabricated based on indium oxide (In2O3)-doped tin oxide (SnO2) semiconductor nanoparticles with platinum (Pt) nanoclusters in combination with interdigitated electrodes. The sensor showed the sensitivity as high as $10^7%$ (Rair/Rgas) and the detection limit as low as 30 ppm. The sensor characteristics could be obtained via optimized materials synthesis route and sensor electrode design. Not only the contribution of electrical resistance from the film itself but also the interfacial effect was identified as an important factor that contribute significantly to the overall sensor characteristics. This promises the applicability of the developed sensor for monitoring hydrogen leak at room temperature.

• 센서학회지
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• 제33권2호
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• pp.63-69
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• 2024

A novel method for measuring hydrogen concentration is introduced, along with its working principle and a novel detection algorithm. This configuration requires no additional reference compartment for potentiometric electrochemical measurements; therefore, it is the most suitable for measuring dissolved hydrogen in the liquid phase. The sensor's electromotive force saturates at a certain point, depending on the hydrogen concentration during the heating process of the sensor operation. This dynamic temperature scanning method provides higher sensitivity than the constant temperature measurement method.

• 센서학회지
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• 제32권5호
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• pp.290-294
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• 2023

Among various types of harmful gases, hydrogen sulfide is a strong toxic gas that is mainly generated during spillage and wastewater treatment at industrial sites. Hydrogen sulfide can irritate the conjunctiva even at low concentrations of less than 10 ppm, cause coughing, paralysis of smell and respiratory failure at a concentration of 100 ppm, and coma and permanent brain loss at concentrations above 1000 ppm. Therefore, rapid detection of hydrogen sulfide among harmful gases is extremely important for our safety, health, and comfortable living environment. Most hydrogen sulfide gas sensors that have been reported are electrical resistive metal oxide-based semiconductor gas sensors that are easy to manufacture and mass-produce and have the advantage of high sensitivity; however, they have low gas selectivity. In contrast, the electrochemical sensor measures the concentration of hydrogen sulfide using an electrochemical reaction between hydrogen sulfide, an electrode, and an electrolyte. Electrochemical sensors have various advantages, including sensitivity, selectivity, fast response time, and the ability to measure room temperature. However, most electrochemical hydrogen sulfide gas sensors depend on imports. Although domestic technologies and products exist, more research is required on their long-term stability and reliability. Therefore, this study includes the processes from electrode material synthesis to sensor fabrication and characteristic evaluation, and introduces the sensor structure design and material selection to improve the sensitivity and selectivity of the sensor. A sensor case was fabricated using a 3D printer, and an Ag reference electrode, and a Pt counter electrode were deposited and applied to a Polytetrafluoroethylene (PTFE) filter using PVD. The working electrode was also deposited on a PTFE filter using vacuum filtration, and an electrochemical hydrogen sulfide gas sensor capable of measuring concentrations as low as 0.6 ppm was developed.

• Nuclear Engineering and Technology
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• 제53권1호
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• pp.142-147
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• 2021

Hydrogen peroxide is a radiolysis product of water formed under gamma-irradiation; therefore, its reliable detection is crucial in the nuclear industry for spent fuel management and coolant chemistry. This study proposes an electrochemical sensor for hydrogen peroxide detection. Cysteamine (CYST), gold nanoparticles (GNPs), and horseradish peroxidase (HRP) were used in the modification of a gold electrode for fabricating Au/CYST/GNP/HRP sensor. Each modification step of the electrode was investigated through electrochemical and physical methods. The sensor exhibited strong sensitivity and stability for the detection and measurement of hydrogen peroxide with a linear range of 1-9 mM. In addition, the Michaelis-Menten kinetic equation was applied to predict the reaction curve, and a quantitative method to define the dynamic range is suggested. The sensor is highly sensitive to H₂O₂ and can be applied as an electrochemical H₂O₂-sensor in the nuclear industry.

• 센서학회지
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• 제31권6호
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• pp.397-402
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• 2022

In this short review, we explore the recent progress in metal-based gas-sensing techniques. The strong interaction between the metal films and hydrogen gas can be considered to play a considerably important role in the gas-sensing technique. The physical and chemical reactions in Pd-Pd hydride systems were studied in terms of the phase transition and lattice expansion of the metals. Two types of represented detection, electrical and optical, were introduced and discussed along with their advantages.