• Title/Summary/Keyword: Hydrogen Mixing

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An Investigation on the Proper Hydrogen Mixing Rate in Heavy-Duty Hydrogen-CNG Engine (수소-천연가스 혼합연료기관의 최적 수소 분사율 검토)

  • LlM, H.S.;KIM, Y.Y.;LEE, JONG T.
    • Transactions of the Korean hydrogen and new energy society
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    • v.15 no.2
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    • pp.89-97
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    • 2004
  • A heavy duty hydrogen enriched CNG engine has the possibility to obtain stable operation at ultra lean condition and to reduce emission extremely. And it can also serve as a so called bridge technology between the current fossil fueled engine and the future hydrogen power system. The emission, torque and brake thermal efficiency characteristics of a heavy-duty hydrogen-CNG engine were investigated to determine the proper mixing rate of hydrogen and CNG. It was found that the proper mixing rates at ${\lambda}=1.4$ and ${\lambda}=1.6$ were around 20% and 30% for hydrogen addition rate respectively.

Correlation between Velocity Fluctuation and Fluctuation of Hydrogen Concentration in 2-D Air-Hydrogen Supersonic Mixing Layer

  • Sakima, Fuminori;Arai, Takakage;Edward, Shelley-R.;Mori, Yuko
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.111-116
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    • 2004
  • An experiment was carried out to confirm the validity of time series evaluation of supersonic mixing condition by using catalytic reaction on a platinum wire. Geseous hydrogen was injected parallel to supersonic freestream (M$\infty$ $\approx$ 1.81) from a slit injector, which was located at backward facing step. Time series condition of supersonic mixing was evaluated by using W-type probe which has a platinum wire and reference wire (nickel wire). The evaluation was by simultaneously measuring each electric circuit which kept the temperature of wire constant. Investigations were also conducted for helium, air and no secondary injectant cases to compare with the hydrogen injectant case. The results indicated that it was possible to measure the time series behavior of air and hydrogen supersonic mixing layer or coherent motion of turbulence by using this evaluation.

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Effects of Volatile Solid Concentration and Mixing Ratio on Hydrogen Production by Co-Digesting Molasses Wastewater and Sewage Sludge

  • Lee, Jung-Yeol;Wee, Daehyun;Cho, Kyung-Suk
    • Journal of Microbiology and Biotechnology
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    • v.24 no.11
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    • pp.1542-1550
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    • 2014
  • Co-digesting molasses wastewater and sewage sludge was evaluated for hydrogen production by response surface methodology (RSM). Batch experiments in accordance with various dilution ratios (40- to 5-fold) and waste mixing composition ratios (100:0, 80:20, 60:40, 40:60, 20:80, and 0:100, on a volume basis) were conducted. Volatile solid (VS) concentration strongly affected the hydrogen production rate and yield compared with the waste mixing ratio. The specific hydrogen production rate was predicted to be optimal when the VS concentration ranged from 10 to 12 g/l at all the mixing ratios of molasses wastewater and sewage sludge. A hydrogen yield of over 50 ml $H_2/gVS_{removed}$ was obtained from mixed waste of 10% sewage sludge and 10 g/l VS (about 10-fold dilution ratio). The optimal chemical oxygen demand/total nitrogen ratio for co-digesting molasses wastewater and sewage sludge was between 250 and 300 with a hydrogen yield above 20 ml $H_2/gVS_{removed}$.

Development of Two-Dimensional Hydrogen Mixing Model in Containment Subcompartment Under the Severe Accident Conditions

  • Lee, Byung-Chul;Cho, Jae-Seon;Park, Goon-Cherl;Chung, Chang-Hyun
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.05b
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    • pp.663-668
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    • 1996
  • A two-dimensional continuum model for the prediction of the hydrogen mixing phenomena in the containment compartment under the severe accident conditions is developed. The model could predict well the distribution of time-dependent hydrogen concentration for selected HEDL Experiment. For a simulation of these experiments, the hydrogen is mixed uniform over the test compartment. To predict the extent of non-uniform distribution, the dominant factors such as the geometrical shape of obstacle and velocity of source injection in mixing phenomena are investigated. If the obstacle disturbing the flow of gas mixture exists in the compartment, the uniform distribution of hydrogen may be not guaranteed. The convective circulation of gas flow is separately formed up and down of the obstacle position, which makes a difference of hydrogen concentration between the upper and lower region of the compartment. The recirculation flow must have a considerable mass flow rate relative to velocity of the source injection to sustain the well-mixed conditions of hydrogen.

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Hydrogen Behavior at a Subcomparment in The Containment Building

  • Lee, U.J.;Park, G.C.
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.10a
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    • pp.495-500
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    • 1997
  • For hydrogen management in severe accidents with degraded nuclear core of PWR's, several experiments have been performed in the SNU hydrogen mixing facility. The objectives are understanding the extent of hydrogen mixing and analyzing the effects of factors which dominate uniform or non-uniform mixing at compartments in the containment building. The facility represents on a 1/11th linearly scaled model of the YGN unit 3&4, hydrogen was simulated by helium. Because there are the gaps between safety injection tank and compartment layers in the containment, the test facility was constructed in three dimentinal mode for analyzing of mixture behavior through the gaps. From the experimental results we could conclude that overall hydrogen concentration distributed uniformly in the free volume of the test compartment, but fluctuated in the gaps. This paper is focused on experimental result from several experiment.

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A Development of a Transient Hydrogen Generation Model for Metal-Water Interactions

  • Lee, Jin-Yong;Park, Goon-Cherl;Lee, Byung-Chul
    • Nuclear Engineering and Technology
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    • v.32 no.6
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    • pp.549-558
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    • 2000
  • A transient model for hydrogen generation in molten metal-water interactions was developed with separate models for two stages of coarse mixing and stratification. The model selves the mechanistic equations (heat and mass transfer correlation, heat conduction equation and the concentration diffusion equation) of each stage with non-zero boundary conditions. Using this model, numerical simulations were performed for single droplet experiments in the Argonne National Laboratory tests and for FITS tests that simulated dynamic fragmentation and stratification. The calculation results of hydrogen generation showed better agreement to the experiment data than those of previous works. It was found from the analyses that the steam concentration to be reached at the reaction front might be the main constraint to the extent of the metal droplet oxidized. Also, the hydrogen generation rate in the coarse mixing stage was the higher than that in the stratification stage. The particle size was the most important factor in the coarse mixing stage to predict the amount of hydrogen generation.

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Startup of Microbial Electrolysis Cells with different mixing ratio of Anaerobic Digested Sludge and Buffer solution (혐기성소화 슬러지 비율에 따른 미생물전기분해전지의 식종 특성)

  • Song, Geunwuk;Baek, Yunjeong;Seo, Hwijin;Jang, Hae-Nam;Chung, Jae Woo;Lee, Myoung-Eun;Ahn, Yongtae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.4
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    • pp.51-59
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    • 2019
  • In this study, the influence of anaerobic digested sludge and 50 mM PBS (phosphate buffer solution) mixing ratio (1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7) on hydrogen production and inoculation period were examined. MECs were operated in fed-batch mode with an applied voltage of 0.9 V. As a result, in the 1:1 mixing ratio reactor, 9.8-20.9 mL of hydrogen was produced with the highest hydrogen content of 66.8-79.6%. Hydrogen gas production and power density increased from after 12 days of inoculation for the 1:1 mixing ratio reactor. In case of 1:2, 1:3 and 1:4 mixing ratio reactor, the hydrogen gas production was 3.7-7.1 mL and the hydrogen gas content was 5.8-65.8%. The hydrogen gas yield in 1:5, 1:6 and 1:7 ratio reactors, was 0.50-0.69 mL and hydrogen content range was 1.8-7.1%. The mixing ratio was found to be suitable for hydrogen production and inoculation period by mixing ratio up to 1:4.

NOx Emission Reduction and Mixing Enhancement of Turbulent Hydrogen Diffusion Flame by An Acoustic Excitation (음파가진에 의한 수소 확산 화염의 NOx 배출저감 및 혼합증진)

  • Han, Jeong-Jae;Kim, Mun-Ki;Yoon, Sang-Wook;Yoon, Young-Bin
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.305-313
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    • 2005
  • Measurements of flame length, width and NOx emissions have been conducted to investigate the effect of an acoustic excitation on flame structure in turbulent hydrogen diffusion flames with coaxial air. The resonance frequency of oscillations was varied between 259 ,514 and 728 Hz with power rate of 0.405 and 2.88w. When these frequencies imposed to hydrogen flames, dramatic reduction of flame length and NOx emission was achieved. And acetone planar laser-induced fluorescence technique was used to measure a concentration of the near field of driven axisymmetric jet. The air-fuel stoichiometric line was plotted to investigate the mixing layer and development of air entrainment to fuel jet. Consequently, acoustic excitation on flame could enhance the air-fuel mixing resulting in abatement of NOx emission quantitatively.

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음식물쓰레기와 폐활성 슬러지를 이용한 생물학적 수소생산

  • Sang, Byeong-In;Lee, Yun-Ji;Kim, Dong-Im;Kim, Dong-Geon;Kim, Ji-Seong;Yu, Myeong-Jin;Park, Dae-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.11a
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    • pp.299-306
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    • 2005
  • Anaerobic fermentation of food waste (FW) and waste activated sludge (WAS) for hydrogen production was performed in CSTR (Continuous Stirred tank reactor) under various HRTs and volumetric mixing ratio (V/V) of two substrates, FW and WAS. The specific hydrogen production potential of FW was higher than that of WAS. However, pH drop in the CSTR for hydrogen production from FW was higher than that from WAS. The maintenance of desired pH during fermentative hydrogen production is regarded as the most important operation parameter for the stable hydrogen production. Therefore, when the potential of hydrogen production from FW and better buffer capacity of WAS, the proper mixture of FW and WAS for fermentative hydrogen production were considered as a useful complementary substrate. The maximum yield of specific hydrogen production, 140 mL/g VSS, was found at HRT of 2 day and the volumetric mixing ratio of 20:80 (WAS : FW). The spatial distribution of hydrogen producing bacteria was observed in anaerobic fermentative reactor using fluorescent in situ hybridization (FISH) method.

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Enhancement of Sewage Sludge Dewaterability by H2O2-Oxidation and Mixing with Paper Sludge (하수슬러지 탈수성 개선을 위한 과산화수소 처리 및 제지슬러지 혼합탈수에 관한 연구)

  • Hwang, Sun-Jin;Eom, Hyoung-Choon;Jang, Hyun-Sup;Jang, Kwang-Un;Kwon, Jae-Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.4
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    • pp.508-514
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    • 2004
  • Industrial and municipal wastewater treatment plants produce large amounts of sludge cakes for final disposal. This problem is an inevitable drawback inherent to the activated sludge process. Both the reduction of the amount of sludge produced and improvement of its dewaterability are presently very important issue also in Korea. So many pre-treatment processes have been developed in order to improve sludge dewatering efficiency. In this study the effects of hydrogen peroxide and paper sludge mixing processes were considered as reasonable alternatives to enhance sludge dewaterability. The CST of sludge was significantly decreased, and dewaterability improved by hydrogen peroxide oxidation treatment. The optimum dosage of hydrogen peroxide was proved to be 10mg/g-TS (when TS of sludge was 2%) with the conditions of pH 4 and only 1~2 minutes of reaction time. The mixing of paper sludge with sewage sludge was turned out to be very effective in reduction of sludge cake; 30% of sludge cake reduction was accomplished. Optimum mixing ratio of paper sludge was about 30%(v/v). This process also could save 25% of polymer to be required. These two alternatives are somewhat realistic, but it was concluded that paper sludge mixing process will be the best choice.