• Title/Summary/Keyword: Hydrogen

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Implantation of portable hydrogen alarm system based on palladium coated single mode optical fiber sensor (팔라듐이 코팅된 단일모드 광섬유 센서를 이용한 수소 경보 시스템 구현)

  • Mun, Nam-Il;Yang, Byung-Cheol;Kim, Kwang-Taek;Kim, Tae-Un
    • Journal of Sensor Science and Technology
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    • v.18 no.4
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    • pp.269-273
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    • 2009
  • In this paper, a study on a portable hydrogen alarm system based on the palladium coated single mode fiber sensor has been reported. The fabricated hydrogen sensor exhibited 0.14 dB, 0.41 dB and 0.54 dB optical intensity variation when it was exposed by the nitrogen and hydrogen mixed gas containing 0.5 %, 1 % and 4 % of the hydrogen concentration, respectively. The fabricated sensor exhibited 20 second of response time and 120 second of recovery time for 4 % hydrogen containing gas. The fiber optics layout and software algorithm for detection of hydrogen leakage have been presented. The implanted portable hydrogen alarm system successfully generated an alarm signal when a 4 % hydrogen containing gas was leaked out.

An Investigation of Combustion and EmissionCharacteristics in Heavy-Duty Hydrogen-CNG Engine (중대형 수소-천연가스 기관의 수소혼합율 변화에 대한 연소 및 배기특성)

  • LIM, H.S.;KIM, Y.Y.;LEE, J.T.
    • Transactions of the Korean hydrogen and new energy society
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    • v.14 no.3
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    • pp.276-282
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    • 2003
  • A hydrogen enriched CNG engine can be stably operated at ultra lean condition and reduce emission extremely. It also has advantage to increase gradually the use of hydrogen for the coming hydrogen-energy age. In this studies, the combustion and emission characteristics of heavy-duty hydrogen-CNG engine were investigated to verify the enhancement of performance by enriched hydrogen into natural gas. The results showed that a hydrogen-CNG engine could achieve ultra lean operation and low emission, while power was reduced by the decrease of intake air flow.

Local Structure Study of Liquid Phase Ethylene Glycol and 1,3-propanediol through Density Functional Theory

  • Nam, Seungsoo;Sim, Eunji
    • Proceeding of EDISON Challenge
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    • 2016.03a
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    • pp.140-146
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    • 2016
  • Using density functional Theory, we studied local structure of liquid ethylene glycol and 1,3-propanediol. For both liquid, making intramolecular hydrogen bonding is not preferred, because relative energy between with and without intramolecular hydrogen bond is only -1.95kcal/mol, which is far less than intermolecular hydrogen bonding energy, about -7.5kcal/mol. Also, hydrogen bond induce polarization of hydroxyl group and make $2^{nd}$ hydrogen bond more stronger. This effect was small in intramolecular hydrogen bond of ethylene glycol. When considering energy per hydrogen bond, making only one intermolecular hydrogen bond for ethylene glycol pair is energetically favored, while two intermolecular hydrogen bond can be formed in 1,3-propanediol pair.

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Simulation of Temperature Behavior in Hydrogen Tank During Refueling Using Cubic Equations of State (3차 상태방정식을 이용한 수소 충전 온도 거동 모사)

  • PARK, BYUNG HEUNG
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.5
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    • pp.385-394
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    • 2019
  • The analysis of temperature behavior of a hydrogen tank during refueling is of significance to clarify the safety of the compressed hydrogen storage in vehicles since the temperature at a tank rises with inflow of hydrogen. A mass balance and an energy balance were combined to obtain analytical model for temperature change during the hydrogen refueling. The equation was coupled to Peng-Robinson-Gasem (PRG) equation of state (EOS) for hydrogen. The PRG EOS was adopted after comparison with other four different cubic EOSs. A parameter of the model was determined to fit data from experiments of various inlet flow rates and temperatures. The temperature and pressure change with refueling time were obtained by the developed model. The calculation results revealed that the extent of precooling was more effective than the flow rate control.

Study of Hydrogen Bus Operational Safety Monitoring Method through Driving Data Analysis (주행 데이터 분석을 통한 수소버스 운행안전 모니터링 기법 연구)

  • Hyunmi Lee;Insik Lee;Yongju Yi;Jeong-Ah Jang;Siwoo Kim;Sojung Sim
    • Journal of Auto-vehicle Safety Association
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    • v.15 no.4
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    • pp.58-64
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    • 2023
  • The adoption of hydrogen-powered Elec is expanding globally. Hydrogen is recognized as a potentially hazardous energy source, and safety assessment is crucial for the development of plans to supply hydrogen-powered electric buses. Hydrogen gas leakage can have a significant impact during bus operations, and continuous hydrogen leakage in hydrogen-powered vehicles can result in fatal accidents. In this study, information about hydrogen leakage is collected through sensors installed within the vehicles and is measured when the sensor detects a leak. The study also proposes the use of Pseudo Fuel Leakage (PFL, %) as an additional indicator for evaluating and monitoring hydrogen safety and leakage.

An Experimental Study on the Sensor Response at Hydrogen Leakage in a Residential Fuel Cell System (가정용 연료전지 시스템 내부 수소 누출 시 센서 응답 특성에 관한 연구)

  • Kim, Young-Doo;Shin, Dong-Hoon;Chung, Tae-Yong;Nam, Jin-Hyun;Kim, Young-Gyu;Lee, Jung-Woon
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.5
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    • pp.378-383
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    • 2009
  • Hydrogen is the primary fuel in fuel cell systems. Because of high inflammation and explosion possibility of hydrogen, fuel cell systems require safety measures to prevent hydrogen hazard upon leakage. In this study, a model enclosure was made by referring to a commercial residential fuel cell system and hydrogen leakage experiments and computational simulations were conducted therein. Hydrogen was injected into the cavity through leakage holes located at the bottom while its flow rate was precisely controlled using MFC. The transient sensor signals from hydrogen sensors installed inside the enclosure were recorded and analyzed. The hydrogen sensor signals showed different delay times depending on their position relative to a leakage point, which indicated that hydrogen generally moves upward and accumulates at the upper region of a closed cavity. The inflammable regions with hydrogen concentration over 4% LEL were observed to locate near the leakage hole initially, and broaden towards the upper cavity region afterward. The simulation result showed that detection time at the hydrogen sensor was similar to the pattern of experimental results. However, the maximum concentration of hydrogen had a gap between experiment and simulation at detect point due to measurement errors and reaction rate.

Study on the Optimum Capacity Analysis for Hydrogen Fueling Station in Korea (국내 수소충전소의 적정 용량 분석)

  • HAN, JA-RYOUNG;PARK, JINMO;LEE, YOUNG CHUL;KIM, SANG MIN;JEON, SO HYUN;KIM, HYOUNG SIK
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.6
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    • pp.649-656
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    • 2017
  • At present, hydrogen is emerging as a future energy source based on environment-friendly aspect, creation of new industry, and enhancement of domestic energy security. In accordance with it, the world's leading automobile companies are focusing on the development and commercialization of hydrogen electric vehicle technology, and each country is strengthening its hydrogen fueling station deployment strategy for its own country. Furthermore, the supply of hydrogen fueling stations is actively promoting under national support. More than 500 hydrogen fueling stations are being constructed, operated and planned around the world. The introduction of hydrogen energy is also progressing in Korea, by announcing road-map to supply hydrogen electric vehicles and hydrogen fueling stations by year. However, there is insufficient discussion on the capacity of hydrogen fueling station in Korea. Therefore, this study suggests the optimum capacity of hydrogen fuelling station for domestic hydrogen economy.

Photoelectrochemical Hydrogen Production with Holmium-doped TiO2 (홀뮴 도핑된 TiO2를 이용한 광전기화학 수소 제조)

  • HYEONMIN JUNG;MINSEO KIM;HYEKYUNG CHO;HYUNKU JOO;KYOUNGSOO KANG;KWANGBOK YI;HANSUNG KIM;JAEKYUNG YOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.5
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    • pp.413-420
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    • 2023
  • Holmium-doped TiO2 nanotubes (Ho-TNTs) were manufactured through anodization treatment and electrochemical deposition, and optimization experiments were conducted using various Holmium doping concentrations and time as variables. Surface as well as electrochemical characteristics were analyzed to study the prepared photocatalysts. Ho-TNTs were found to exist only in anatase phase through X-ray diffraction analysis. Ho-TNTs with 0.01 wt% 100 seconds shows a photocurrent density of 3.788 mA/cm2 and an effective photo-conversion efficiency (PCE) of 4.30%, which is more efficient than pure TiO2 nanotubes (pure-TNTs) (at bias potential 1.5 V vs. Hg/HgO). The photocatalytic activity of the aforementioned Ho-TNTs for hydrogen production was evaluated with the result of -29.20 µmol/h·cm2.

Preliminary Cost Estimates for Nuclear Hydrogen System Based on High Temperature Electrolysis (고온전기분해 이용 원자력수소 예비타당성 연구)

  • Yang, Kyeongjin;Lee, Taehoon;Lee, Kiyoung
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.228.2-228.2
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    • 2010
  • In this work, the hydrogen production costs of the nuclear energy sources are estimated in the necessary input data on a Korean specific basis. G4-ECONS was appropriately modified to calculate the cost for hydrogen production of HTE process with Very High Temperature nuclear Reactor (VHTR) as a thermal energy source rather than the LUEC (Levelized Unit Electricity Cost). The general ground rules and assumptions follow G4-ECONS. Through a preliminary study of cost estimates, we wished to evaluate the economic potential for hydrogen produced from nuclear energy, and, in addition, to promptly estimate the hydrogen production costs for an updated input data for capital costs. The estimated costs presented in this paper show that hydrogen production by the VHTR could be competitive with current techniques of hydrogen production from fossil fuels if $CO_2$ capture and sequestration is required. Nuclear production of hydrogen would allow large-scale production of hydrogen at economic prices while avoiding the release of $CO_2$. Nuclear production of hydrogen could thus become the enabling technology for the hydrogen economy. The major factors that would affect the cost of hydrogen were also discussed.

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THE NUMERICAL SIMULATION OF HYDROGEN JET DIFFUSION FOR HYDROGEN LEAKAGE IN THE ENCLOSED GEOMETRY (밀폐공간에서 수소 누설로 인한 수소 제트 확산에 대한 수치해석)

  • Ahn, Hyuk-Jin;Lee, Sang-Hyuk;Hur, Nahm-Keon;Lee, Moon-Kyu;Yong, Gee-Joong
    • 한국전산유체공학회:학술대회논문집
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    • 2009.04a
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    • pp.176-182
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    • 2009
  • In the present study, a numerical simulation for the diffusion of hydrogen jet in a enclosure was performed to aid the leakage test of the hydrogen for the safety of the hydrogen vehicle. The temporal and spatial distributions of the hydrogen concentration in the test chamber are predicted from the present numerical analyses. Flammable region of 4-74% and explosive region of 18-59% hydrogen by volume was identified from the present results. Factors influencing the diffusion of the hydrogen jet were examined to evaluate the effectiveness of forced ventilation for relieving the accumulation of the leaked hydrogen gas in the chamber, which include location of open windows, size of leakage nozzle, and leakage rate among others. The distribution of the concentration of the leaked hydrogen for various cases can be used as a database in various applications for the hydrogen safety.

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