• Title/Summary/Keyword: Hydrocarbons

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EXPERIMENTAL STUDY ON EMISSION CHARACTERISTICS AND ANALYSIS BY VARIOUS OXYGENATED FUELS IN A D.I. DIESEL ENGINE

  • CHOI S. H.;OH Y. T.
    • International Journal of Automotive Technology
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    • v.6 no.3
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    • pp.197-203
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    • 2005
  • This paper investigates the effect of oxygen composition in mixed fuel on the exhaust emissions for the direct injection diesel engine. These effects were tested to estimate the change in engine performance and exhaust emission characteristics when commercial diesel fuel and oxygenates blended fuels at a certain fuel and mixed ratio are used. Individual hydrocarbons $(C_1-C_6)$ in exhaust gases, as well as the total amount of hydrocarbons, were analyzed by using gas chromatography to find the mechanism by which smoke emission was remarkably reduced for various oxygenated fuels. The chromatograms between a diesel fuel and a diesel fuel blended DGM (diethylene glycol dimethyl ether), MTBE (methyl tert-butyl ether) and EGBE (ethylene glycol mono-n-butyl ether) were compared. The results showed that the number of individual hydrocarbons as well as the total number of hydrocarbons of oxygenated fuel reduced more remarkably than those of diesel fuel.

Characterization of Aromatic Hydrocarbon Degrading Bacteria Isolated from Pine Litter (솔잎 퇴적물에서 추출한 방향족 탄화수소물질 분해 박테리아의 동정)

  • Song, Yoon-Jae
    • Microbiology and Biotechnology Letters
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    • v.37 no.4
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    • pp.333-339
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    • 2009
  • Using a novel pine needle agar, fifteen bacterial species were isolated from pine litter. These bacteria were able to degrade aromatic hydrocarbons derived from lignin and utilize the ortho-cleavage of the $\beta$-ketoadipate pathway to degrade protocatechuate or catechol. A different utilization array of aromatic hydrocarbons by these bacteria was also determined. This study provides the information on bacterial species living in pine litter and suggests that these bacteria have metabolic abilities to utilize aromatic hydrocarbons derived from lignin biodegradation.

Linkage Between Biodegradation of Polycyclic Aromatic Hydrocarbons and Phospholipid Profiles in Soil Isolates

  • Nam, Kyoung-Phile;Moon, Hee-Sun;Kim, Jae-Young;Kukor, Jerome-J.
    • Journal of Microbiology and Biotechnology
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    • v.12 no.1
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    • pp.77-83
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    • 2002
  • A bacterial consortium capable of utilizing a variety of polycyclic aromatic hydrocarbons has been isolated from a former manufactured gas plant site. The consortium consisted of four members including Arthrobacter sp., Burkholderia sp., Ochrobacterium sp., and Alcaligenes sp., which were identified and characterized by the patterns of fatty acid methyl esters (FAME analysis) and carbon source utilization (BIOLOG system). With the individual members, the biodegradation characteristics of aromatic hydrocarbons depending on different growth substrates were determined. FAME analyses demonstrated that microbial fatty acid profiles changed to significant extents in response to different carbon sources, and hence, such shift profiles may be informative to characterize the biodegradation potential of a bacterium or microbial community.

A combined approach to remediate polycyclic aromatic hydrocarbons at a former manufactured gas plant site

  • Kyoungphile Nam;Kim, Jae-Young
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.09a
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    • pp.103-106
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    • 2001
  • A remediation technology consisting of biodegradation and a modified Fenton reaction was developed to degrade mixtures of polycyclic aromatic hydrocarbons (PAHs) at a former manufactured gas plant (MGP) site. The original Fenton reaction (i.e., $H_2O$$_2$ + Fe$^{2+}$) was modified to be biocompatible by using ferric ions and chelating agents such as catechol and gallic acid. The modified reaction was effective in degrading PAHs at near neutral pH and thus was compatible with biodegradation. By the combined treatment of the modified Fenton reaction and biodegradation, more than 98% of 2- or 3-ring hydrocarbons and between 70 and 85% of 4- or 5-ring compounds were degraded in the MGP soil, while maintaining its pH about 6.6.

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탈질조건을 이용한 유류물질 생분해 기초연구

  • 오인석;장순웅;이시진
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.368-371
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    • 2003
  • Leaking underground storage tanks are a major source of groundwater contamination by petroleum hydrocarbons. Bioremediation of aromatic hydrocarbons in groundwater and sediments is often limited by dissolved oxygen. Aerobic bioremediation has been highly effective in the remediation of many fuel releases, but Many aromatic hydrocarbons degrade very slowly under anaerobic conditions. Nitrate is a good alternative electron acceptor to oxygen and denitrifying bacteria are commonly found in the subsurface and in association with contaminated aquifer materials. Because nitrate is less expensive and more soluble than oxygen. it may be more economical to restore fuel-contaminated aquifers using nitrate rather than oxygen. This study show that biodegradation of BTEX and MTBE is enhanced by the nitrate-amended microcosms under aerobic/anaerobic conditons. Although aromatic hydrocarbons degrade very slowly under anaerobic conditions. Biodegradaton was observed for all of the test compounds.

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Analysis of Volatile Compounds in Elsholtzia splendens by Solid Phase Microextraction (SPME에 의한 꽃향유의 휘발성 향기성분 분석)

  • 정미숙;이미순
    • Korean journal of food and cookery science
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    • v.19 no.1
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    • pp.79-82
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    • 2003
  • Volatile compounds in Elsholtzia splendens were extracted by solid phase microextraction (SPME). Two kinds of SPME fiber, carboxen/polydimethylsiloxane (CAR/PDMS) and polydimethylsiloxane (PDMS) were used to determine the selectivity of the fibers to the different flavor compounds present in the Elsholtzia splendens. Identification of volatile compounds was based on the linear retention indices (RI) and the comparison of their mass spectra with those of on-computer library. Thirty compounds were identified in the volatile compounds extracted by CAR/PDMS fiber, including 1 aldehyde, 5 alcohols, 3 hydrocarbons, 17 terpene hydrocarbons, 3 ketones and 1 miscellaneous. And 5 alcohols, 3 hydrocarbons, 18 terpene hydrocarbons, 3 ketones and 2 miscellaneouses were identified in PDMS fiber. These results suggested that the selectivity of PDMS fiber was similar to that of CAR/PDMS fiber in Elsholtzia splendens. The major volatile compounds were naginataketone and elsholtziaketone in Elsholtzia splendens.

The Production of Algal Hydrocarbons in Outdoor Cultivations of Dunaliella salina 1650

  • Pak, Jin-Hong;Lee, Shin-Young;Kim, Young-Nam
    • Journal of Microbiology and Biotechnology
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    • v.3 no.1
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    • pp.46-50
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    • 1993
  • In 12:12 hour light/dark cycle cultivation of D. salina 1650, maximum specific growth rate of 0.59 (l/day) and 0.35 (g-crude hydrocarbons/l/day) were obtained. The cell growth was inhibited at above 15$\times$$10^{-4} (kcal/cm^2/h)$ of light intensity in an outdoor cultivation. It was also showed that temperature is one of the critical growth parameters in the outdoor cultivation. The hydrocarbon production from D. salina 1650 seems to be partially growth related production process, and these algal hydrocarbons can be used for subsituting petroleum directly or through cracking processes. The value of weight fraction carbon of D. salina 1650 was similar to that of Botryococcus braunii and so was the hydrocarbon productivity.

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Prediction of Explosion Limits of Organic Halogenated Hydrocarbons by Using Heat of Combustions (연소열을 이용한 유기할로겐화탄화수소류의 폭발한계의 예측)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.26 no.4
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    • pp.63-69
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    • 2012
  • Explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, the lower explosion limit (LEL) and upper explosion limit (UEL) of organic halogenated hydrocarbons were predicted by using the heat of combustion and chemical stoichiometric coefficients. The calculated explosion limits by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the other organic halogenated hydrocarbons.

Distribution and Source of Atmospheric Polycyclic Aromatic Hydrocarbons and Nitropolycyclic Aromatic Hydrocarbons in Tieling City, Liaoning Province, a Typical Local City in Northeast China

  • Tang, Ning;Araki, Yuki;Tamura, Kenji;Dong, Lijun;Zhang, Xuemei;Liu, Qiuhua;Ji, Ruonan;Kameda, Takayuki;Toriba, Akira;Hayakawa, Kazuichi
    • Asian Journal of Atmospheric Environment
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    • v.3 no.1
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    • pp.52-58
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    • 2009
  • Airborne particulates were collected in three different size fractions (>7 ${\mu}m$; 2.1-7 ${\mu}m$; < 2.1 ${\mu}m$) by using Andersen low-volume air samplers at three sites in Tieling city, Liaoning Province, a typical local city in northeast China, in every season during the period from July 2003 to May 2004. Nine polycyclic aromatic hydrocarbons (PAHs) and seven nitropolycyclic aromatic hydrocarbons (NPAHs) in the airborne particulates were determined by HPLC with fluorescence and chemiluminescence detection, respectively. The mean total concentrations of the nine PAHs and seven NPAHs were highest at The mixed residential and light industrial site, and lowest at the residential site near the suburbs. At all sites, more than 70% of the total PAHs and more than 60% of the total NPAHs were found in the finest particulate (< 2.1 ${\mu}m$) fraction. Both cluster analysis and several diagnostic ratios showed that the major contributors of PAHs and NPAHs in airborne particulates were coal combustion systems such as domestic stoves and coal boilers in all seasons in Tieling city.

Optimization of Pre-Treatment Conditions for Hydrocarbons Detection from Irradiated Soybean Using Microwave-Assiated Extraction (마이크로파 추출법을 이용한 방사선 조사 대두의 Hydrocarbons 분석 전처리조건 최적화)

  • Lee, Jeong-Eun;Kwon, Joong-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.612-621
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    • 2013
  • Microwave-assisted extraction (MAE), which is known as less time and less solvent than current extraction methods, was applied to hydrocarbons extraction from irradiated soybean. Among the transported agricultural products, soybean was selected as representative samples for possible application of irradiated treatment and identification of radiation-induced markers. Using 4 kGy-irradiated soybean, different microwave extraction conditions (extraction time and microwave power) were applied and the changes in hydrocarbon concentrations were monitored. The predicted optimum extracted condition for hydrocarbon analysis of soybean was found to be microwave extraction with a microwave power of 97 W and extraction time of 2.2 min. This extraction time was significantly lower compared to the common extraction time of 12-24hr.