• Title/Summary/Keyword: Hydrocarbon Emission

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The Characteristics of the Appearance and Health Risks of Volatile Organic Compounds in Industrial (Pohang, Ulsan) and Non-Industrial (Gyeongju) Areas

  • Jung, Jong-Hyeon;Choi, Bong-Wook;Kim, Mi-Hyun;Baek, Sung-Ok;Lee, Gang-Woo;Shon, Byung-Hyun
    • Environmental Analysis Health and Toxicology
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    • v.27
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    • pp.12.1-12.8
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    • 2012
  • Objectives: The aim of this study was to identify the health and environmental risk factors of air contaminants that influence environmental and respiratory diseases in Gyeongju, Pohang and Ulsan in South Korea, with a focus on volatile organic compounds (VOCs). Methods: Samples were collected by instantaneous negative pressure by opening the injection valve in the canister at a fixed height of 1 to 1.5 m. The sample that was condensed in $-150^{\circ}C$ was heated to $180^{\circ}C$ in sample pre-concentration trap using a 6-port switching valve and it was injected to a gas chromatography column. The injection quantity of samples was precisely controlled using an electronic flow controller equipped in the gas chromatography-mass spectrometer. Results: The quantity of the VOC emissions in the industrial area was 1.5 to 2 times higher than that in the non-industrial area. With regards to the aromatic hydrocarbons, toluene was detected at the highest level of 22.01 ppb in Ulsan, and chloroform was the halogenated hydrocarbons with the highest level of 10.19 ppb in Pohang. The emission of toluene was shown to be very important, as it accounted for more than 30% of the total aromatic hydrocarbon concentration. Conclusions: It was considered that benzene in terms of the cancer-causing grade standard, toluene in terms of the emission quantity, and chloroform and styrene in terms of their grades and emission quantities should be selected for priority measurement substances.

The Study on Performance and Emission of CNG as a Potential Fuel in Kore (한국의 잠재적인 연료인 CNG연료의 성능 및 배출물에 관한 연구)

  • Cho, Haeng-Muk;Chauhan, Bhupendra Singh
    • Journal of the Korean Institute of Gas
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    • v.13 no.6
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    • pp.39-43
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    • 2009
  • Gasoline engine have proved its utility in light, medium and heavy duty vehicle in every sector of the world community. The concern about long term availability of petroleum and the increasing threat for the environment by the increasing load of vehicular emission, compel the technology to upgrade itself for meeting the challenges. CNG is environmentally clean alternative to the existing SI Engines with out much change in the hardware. Many researchers have found this as a potential substitute to meet the energy requirement. Higher octane number and higher self ignition temperature make it a good gaseous fuel. Although power output is slightly lesser than the gasoline it's thermal efficiency is better than the gasoline for the same SI Engine. Results showed that reduced CO, hydrocarbon emissions is a favorable outcome, with slight increase in NOx emission when compared with gasoline fuel to dual fuel mode in the existing SI Engines.

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Experimental Investigation of Steam Plasma Characteristics for High Energy Density Metal Powder Ignition Using Optical Emission Spectroscopy Method (OES 방법을 이용한 고에너지 금속 분말 점화용 스팀 플라즈마 특성에 관한 실험적 고찰)

  • Lee, Sang-Hyup;Ko, Tae-Ho;Yoon, Woong-Sup
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.545-550
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    • 2012
  • High Energy density metal powder has high melting point of oxide film. By this, the ignition source that can make a thermal effect of high-temperature during short time is needed to overcome ignition disturbance mechanism by oxide film. So effective ignition does not occurred with hydrocarbon ignitor, $H_2-O_2$ ignitor, high power laser. But steam plasma can be generate about 5000 K temperature field in short order. Because a steam plasma uses steam as the working gas, it is environmental-friendly and economical. Therefore in this study, we analyze steam plasma temperature field and radical species with optical emission spectroscopy method in order to apply steam plasma ignitor to metal combustion system and cloud particle ignition was identified in visual.

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A Study on Emission Reductions of Diesel Engine Using Plasmatron Fuel Converter (플라즈마트론을 이용한 디젤 엔진의 매연저감에 관한 연구)

  • Ki, Ho-Beom;Kim, Bong-Soo;Kwak, Yong-Hwan;Kim, Woo-Hyung;Lim, Won-Kyung;Chae, Jae-Ou
    • 한국연소학회:학술대회논문집
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    • 2006.10a
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    • pp.104-109
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    • 2006
  • Improvements in internal combustion engine and aftertreatment technologies are needed to meet future environmental quality goals. Plasmatron fuel converters provide a rapid response, compact means to transform a wide range of hydrocarbon fuels (including gasoline, natural gas and diesel fuel) into hydrogen-rich gas. Hydrogen-rich gas can be used as an additive to provide NOx reductions of more than 80% in diesel engine vehicles by enabling very lean operation or heavy exhaust engine recirculation. For diesel engines, use of compact plasmatron reformers to produce hydrogen-rich gas for the regeneration of NOx absorber/absorbers and particulate traps for diesel engine exhaust after-treatment could provide significant advantages. Recent tests of conversion of diesel fuel to hydrogen-rich gas using a low current plasmatron fuel converter with non-equilibrium plasma features are described.

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Numerical Study of PAH Formation Characteristics in Laminar Non-Premixed C2H4 Jet Flames (층류 비예혼합 C2H4 제트 화염장에서의 PAH 생성특성 해석)

  • Kim, Taehoon;Kim, Yongmo
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.133-134
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    • 2014
  • The full transport equation approach for laminar non-premixed flame with detailed chemistry, soot and radiation has an advantage in accuracy and describing for emission pathway, but this approach requires the excessive computational cost especially for a higher-order hydrocarbon fuel flames. On the other hand, the standard flamelet model has an efficiency and accuracy for non-premixed flame, though this model is not suitable for simulating slow processor like soot and radiation in laminar non-premixed flame situation. To overcome this limitation, modified transient flamelet model is developed which coupled with two-equation soot model involved in soot formation and evolution mechanism such as nucleation, surface growth, oxidation and agglomeration.

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Effects of Hydrogen Ratio on Combustion and Emissions Characteristics of Hydrogen/Diesel Dual-Fuel Engine (수소의 혼합 비율에 따른 수소/디젤 혼소 엔진의 연소 및 배기 특성 파악)

  • Park, Hyunwook;Bae, Choongsik
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.103-106
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    • 2014
  • The effects of hydrogen ($H_2$) ratio on combustion and emission characteristics in a $H_2/diesel$ dual-fuel engine were investigated. Dual-fuel strategy was applied to improve the control of combustion phasing. The combustion phasing was retarded with increasing $H_2$ fraction. This can be explained by both reduced diesel concentration and chemical effect of $H_2$, which reduce the heat release rate during the low temperature reaction stage. Hydrocarbon and carbon monoxide emissions of the engine were decreased drastically when $H_2$ ratio was increased.

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A Study on Combustion Characteristics of Gasoline and Diesel Fuels in a Compression Ignition Engine (압축착화 엔진에서 가솔린과 디젤연료의 연소 특성에 관한 연구)

  • Kim, Kihyun
    • Journal of Power System Engineering
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    • v.21 no.1
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    • pp.63-69
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    • 2017
  • The combustion characteristics of gasoline and diesel were tested in a compression ignition engine. Both fuels were used with same common rail injection system. Combustion experiment showed that low load condition of 0.45 MPa IMEP (indicated mean effective pressure) was tested in metal and optical engines. The gasoline combustion showed higher hydrocarbon and carbon monoxide emissions but lower soot emission compared with diesel combustion. NOx emissions were very high at late injection timing but significantly decreased at early injection timing due to the lean combustion resulted from vigorous mixing process. Direct combustion visualization showed that the diesel combustion was dominated by diffusion combustion exhibiting soot incandescence and the gasoline combustion was mostly consisted of premixed combustion showing blue chemiluminescence.

Heteroepitaxial Growth of Diamond Films Synthesized by Microwave Plasma Enhanced Chemical Vapor Deposition

  • Kim, Yoon-Kee;Lee, Jai-Young
    • The Korean Journal of Ceramics
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    • v.2 no.4
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    • pp.197-202
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    • 1996
  • The highly oriented diamond particles were deposited on the mirror-polished (100) silicon substrates in the bell-jar type microwave plasma deposition system using a three-step process consisting if carburization, bias-enhanced nucleation and growth. By adjusting the geometry of the substrate and substrate holder, very dense disc-shaped plasma was formed over the substrate when the bias voltage was below -200V. Almsot perfectly oriented diamond films were obtained only in this dense disc-shaped plasma. From the results of the optical emission spectra of the dense disc-shaped plasma, it was found that the concentrations of atomic hydrogen and hydrocarbon radical were increased with negative bias voltage. It was also found that the highly oriented diamonds were deposited in the region, where the intensity ratios of carbonaceous species to atomic hydrogen are saturated.

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A Numerical Study on Stratified Charge Formation and Combustion Processes (성층급기 연소현상에 관한 수치적 연구)

  • Lee, Suk-Young;Huh, Kang-Y.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.5
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    • pp.86-96
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    • 2007
  • A direct-injection stratified-charge(DISC) engine has been considered as a promising alternative in spite of high unburned hydrocarbon emission levels during light load operation. In this paper investigation is made to characterize formation and combustion processes of stratified mixture charge in a simple constant volume combustion chamber. Both experimental and numerical analyses are performed for fluid and combustion characteristics with 3 different induction types for rich, homogeneous and lean mixture conditions. The commercial code FIRE is applied to the turbulent combustion process in terms of measured and calculated pressure traces and calculated distributions of mean temperature, OH radical and reaction rate. It turns out that the highest combustion rate occurs for the rich state condition at the spark ignition location due to existence of stoichiometric mixture and timing.

AKARI near Infrared spectroscopy of luminous infrared galaxies

  • Lee, Jong-Chul;Hwang, Ho-Seong;Lee, Myung-Gyoon
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.50.2-50.2
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    • 2012
  • We present the results of near infrared (2.5-5 micron) spectroscopy of nearby luminous infrared galaxies (LIRGs) using AKARI. The LIRG catalog is constructed from the cross-correlation between the Infrared Astronomical Satellite and the Sloan Digital Sky Survey data, and optically non-Seyfert type LIRGs are selected for main targets. We search for optically elusive active galactic nuclei (AGNs), based on the strengths of 3.3 micron polycyclic aromatic hydrocarbon emission and dust absorption features at 3-4 micron. We investigate the hidden AGN fraction as a function of the infrared luminosity and correlation between optical and near infrared star formation indicators.

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