• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2003년도 학술.기술논문발표회
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• pp.95-98
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• 2003

This paper presents the results of field experiment to apply the difference of setting tine method using super retarding agent for reducing hydration heat of mass concrete of foundation. According to the results, as the properties of fresh concrete, base concrete satisfies aimed slump and air content, and there is no difference of slump and air content with mixture of super retarding agent. The mixing ratio of super retarding agent is determined for setting time to be retarded by 12 hours in comparison with base concrete, but because the temperature of the air and concrete is low, the difference of setting time is retarded to 24 hours. In man concrete of foundation to which the difference of setting time method is applied, crack by hydration heat is not seen because the lower concrete of super retarding agent generates heat after generation of hydration heat of the upper concrete.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2016년도 춘계 학술논문 발표대회
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• pp.203-204
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• 2016

In this research, it used cement power and reduction slag, which generates high hydration heat in hydration reation without heat cure below -5℃ degree. Purpose of final research is preventing freezing and thawing by making the compressive strength 5MPa in 3days below zero temperature due to own heat of concrete. and it is the result of physical characteristic and thermal property evaluation of reduction slag. Because reduction sag generates high hydration heat, compressive strength development is excellent. By generating highly Hydration heat by C₁₂A₇ and C₃A in reduction slag, compressive strength is developed in low temperature. In case of displacing only reduction slag without SO₃, it is indicated that quick-setting occurs by shortage of SO₃. For preventing quick-setting, gypsum is used essentially. According to this research result, in case of using reduction slag and gypsum as a ternary system, Compressive strength developed 5MPa in 3days below zero temperature. It is identified to prevent early frost damage of concrete below zero temperature.

• 한국세라믹학회지
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• 제34권8호
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• pp.861-869
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• 1997

In order to investigate the reaction in the system of anhydrite II-blast furnace slag, the paste hydration which made up with a liquid/solid ratio of 0.45 for 1, 3, 7, 14, 28days by the addition of accelerators to 10~30wt.% slag with natural gypsum calcined for 1hour at 500/$700^{\circ}C$ was studied by combined water determination, XRD, DTA, DSC and SEM. As a result of this experiment, it was found that hydration rate was faster in the system calcined at 50$0^{\circ}C$. Therefore the anhydrite was converted to calcium sulfate dihydrate in the hydration for 1day but the slag was not almost reacted. For the gypsum calcined at $700^{\circ}C$, the hydraton rate in the system of K2SO4 addition was faster than others in the earier period, but the activated effect of the system of Al2(SO4)3 addition was regarded as the highest over 3days. As the amount of slag was increased, they dydration rate was delayed and ettringite was observed in the case of K2SO4 system. However both Al2(SO4)3 and AlK(SO4)2 systems showed calcium sulfate dhydrate only as hydrated products.

• 대한건축학회논문집:구조계
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• 제36권1호
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• pp.155-162
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• 2020

The aim of the research is to investigate the fundamental properties and heat of hydration reducing performance of the fly ash incorporated concrete mixture when the coal gas slag (CGS) from integrated gasification combined cycle (IGCC) is used as fine aggregate. From the results of the experiment, the workability was generally increased and the air content was decreased up to one to four percent with increasing the replacing ratio of CGS to fine aggregate. The compressive strength was similar or increased within five percent to the Plain mixture when the CGS was used as a fine aggregate. When the CGS and fly ash were used same time, the heat of hydration reducing performance was improved than single using cases either CGS or fly ash. Based on the results, for the concrete mixture using CSG as a portion of the combined fine aggregate, the general properties were improved and heat of hydration was decreased approximately 16 % when the fly ash was replaced 30 % to cement and the CGS was replaced less than 50 % to fine aggregate.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2004년도 학술대회지
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• pp.21-26
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• 2004

This study deals with the Hydrated Ability of the Ready-Mixed Concrete's Sludge which is the recycling technology of that sludge. The experiment gathers sludge from Ready-mixed factory. shatters these into pieces in dry condition and understands the differences between current using Portland cement. And then. this examines the possibility of the recycle as a bonding agent through the Compressive Strength and considers the recovery of the hydration. This experiment concludes the same Chemical Composition with the normal Portland cement. while. under the appropriate procedure in hydration recovery. this sludge can be used as the bonding agent in cement. The chemical composition of solid Remicon sludge shows that it has 1.8 times $SiO_2$ than the normal Portland cement. meaning lots of aggregate in Remicon sludge. Also. the specific gravity of Remicon sluge increases with the rise of Baking Temperature and has no difference between 2.77 and 2.94. The mortar flow used for combining the baking material of Remicon sludge does was not changed and is the highest between $750^{\circ}C{\cdot}120min\;and\;800^{\circ}C{\cdot}180min$. Additionally. the Compressive Strength increases with the age, certifying the same Hydrated Ability like cement and the best condition for hydration is $750^{\circ}C{\cdot}120min.$

• 한국결정성장학회지
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• 제18권4호
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• pp.174-178
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• 2008

본 연구에서는 균일침전법으로 합성된 $CaCO_3$를 하소한 후 수화시키는 방법을 이용하여 소석회를 제조하였다. 소석회를 제조하기 위하여, 염화칼슘$(CaCl_2)$과 우레아(Urea)가 출발 물질로 사용되었으며 염화칼슘 수용액과 우레아 수용액을 혼합하여 가열하는 동안 반응용기 내에서 탄산칼슘이 합성되었다. 침전물들을 여과하고 증류수와 에탄올로 수 차례 세척하였으며 건조시켰다. 소석회는 하소된 탄산칼슘의 수화과정을 통하여 합성되었다. 최적의 합성조건을 선정하는데 있어 실험의 잡음인자를 최소화하고 결과를 통계적으로 추론할 수 있는 실험계획법(다구치 실험계획법)을 이용하였다. 제조된 탄산칼슘을 $1000^{\circ}C$에서 30분 동안 하소시킨 후 에탄올 및 옥살산이 첨가된 증류수로 수화시킴으로써 결정입자 크기가 약 50 nm인 소석회를 제조할 수 있었다.

• 한국세라믹학회지
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• 제24권3호
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• pp.289-295
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• 1987

The changes of physical properties of portland cement pastes and mortars were investigated by addition of sodium gluconate. Flow table experiment and viscosity measurement were took in order to find dispersing effect, and time-dependent changesof viscosity and rates of hydration heat evolution were carried out for the sake of finding retardation effect of hydration. And changes of physical properties of cement pastes and mortars were discussed by setting time, compressive strength and porosity.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표회 논문집(I)
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• pp.19-24
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• 1998

In this study, blended cement with low blaine(2000, 3000$\textrm{cm}^2$/g) blast-furnace slag power by 10-70wt.% was investigated through the measurement hydration heat, physical properties. The experiment results indicated compressive strength was decreased as low blaine slag blended, but hydration heat was reduced significantly and flow of the cement paste was increased.

• 대한환경공학회지
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• 제27권12호
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• pp.1327-1331
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• 2005

본 연구에서는 해안연약지반의 현장토(준설점토)를 차수층에 이용하기 위해 첨가되는 고화재에 의한 수화열을 저감하기 위한 방안을 모색하고자 산업부산물로 년간 다량 배출되는 고로슬래그를 이용하였다. 실험결과, 고로슬래그를 첨가한 준설혼합토(준설점토 95% w+시멘트 5% w)의 경우 고화재에 의한 초기수화반응열을 저감하는 것으로 나타났는데 이는 불투수성인 aluminosilicate 피막이 고로슬래그의 표면을 코팅하였기 때문으로 판단된다. 따라서 고화재의 수화반응에 따른 수화열에 의해 발생될 수 있는 매립지 차수층의 미세균열을 산업부산물인 고로슬래그가 저감해 줄 수 있을 것으로 판단된다.

• 한국세라믹학회지
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• 제42권3호
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• pp.198-204
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• 2005

본 연구에서는 규불화염, 가용성 실리카, 방향족계 고분자 축합물 그리고 잠열특성을 지닌 질산염계 무기화합물로 구성된 규불화염계 수화열 저감제를 시멘트 모르타르의 수화열 및 건조수축에 미치는 영향을 조사하였다. 규불화염계 수화열 저감제의 첨가로 시멘트 모르타르의 단열상승온도 및 건조수축에 의한 길이변화가 저감되는 특성을 나타내었다. 또한, 규불화염계 수화열 저감제가 첨가된 판상형 시멘트 모르타르 시험체의 균열 패턴을 측정한 결과, 수화열 저감과 건조수축에 의해 길이변화가 저감되는 복합적 효과를 통해 시멘트 모르타르의 균열저감성이 개선되는 것을 확인하였다.