• 한국터널지하공간학회 논문집
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• 제25권2호
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• pp.175-186
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• 2023

처분공 내에 위치한 완충재는 사용후핵연료로부터 발산된 고온의 붕괴열과 지하수에 노출되며, 이와 같은 가열-수화를 포함한 처분환경 하의 완충재의 열-수리-역학-화학적 상호작용은 완충재의 장기적 성능과 건전성에 핵심적으로 작용하는 것으로 알려져 있다. 따라서 본 연구에서는 처분환경 조건에서 완충재의 가열-수화 특성 및 지하수 지화학 조건을 고려한 벤토나이트의 열-수리-역학-화학적(Thermal-Hydraulic-Mechanical-Chemical, 이하 THMC) 복합거동 특성 규명을 위한 실험실 규모의 Lab.THMC 실험시스템을 개발하였다. 본 실험시스템은 스페인 CIEMAT의 열-수리-역학 복합거동 실험장치를 토대로 개발되었으며, 화학적 특성을 달리한 지하수 주입 조건에서 벤토나이트 완충재의 가열-수화 특성을 파악하고 응력 변화를 계측함으로써 열-수리-화학적 변화에 따른 역학적 성능 변화 특성을 규명하는 것을 목표로 한다. 본 기술논문에서는 개발된 Lab.THMC 실험시스템의 설계 및 구성을 간략하게 소개하고, 장치 검토 및 주요 변수설정을 위해 수행된 예비실험 결과와 차후 연구계획에 대해 정리하였다.

• Journal of Biosystems Engineering
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• 제42권1호
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• pp.56-61
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• 2017

Purpose: High energy requirement and long cooking time are limiting consumption of pigeon pea (Cajanus cajan), a nutritious food. This study was performed to estimate energy and time demand by different methods of cooking pigeon pea. Methods: Pigeon pea (150 g) was soaked in 2.0 L of water at ambient temperature ($29{\pm} 2^{\circ}C$) to determine hydration behavior. Cooking experiments were conducted using aluminum and pressure-cooking pots. Efficiency of cooking was evaluated using four types of cooking appliances (kerosene, liquefied petroleum gas (LPG), electric, and charcoal stoves). Normal (continuous heating until the food was satisfactorily cooked) and control (controlling the energy input to closely match the actual energy required) cooking were conducted. Energy requirement and duration of cooking were determined using standard procedures. Results: Soaking increased moisture content from 11.99 to 30.01% in 90 min, while water absorption rate decreased with soaking duration. In cooking 150 g of pigeon pea using kerosene stove, presoaked normal pressure-pot cooking method consumed the least energy (10 800 kJ) and time (205 min), while unsoaked normal cooking consumed the highest energy (18 450 kJ) and time (336 min). Using LPG stove, unsoaked normal cooking method required the highest energy (52 470 kJ), while presoaked control pressure-pot required the least energy (14 405 kJ). For electric stove, the lowest energy (15 560 kJ) and shortest duration (105 min) were recorded during control cooking of presoaked sample in the pressure-pot. Conclusions: Control cooking was not practicable using charcoal stove. Generally, kerosene stove consumed the least energy, while electric stove was found to have the shortest duration of cooking.

• 방사성폐기물학회지
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• 제18권3호
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• pp.407-414
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• 2020

Thermal decomposition of the uranyl phosphate mineral phase meta-ankoleite (KUO₂PO₄·3H₂O) has been considered in relation to high temperature thermal sintering for the immobilisation of a uranyl phosphate containing waste. Meta-ankoleite thermal decomposition was studied across the temperature range 25 - 1200℃ under an inert N₂ atmosphere at 1 atm. It is shown that the meta-ankoleite mineral phase undergoes a double de-hydration event at 56.90 and 125.85℃. Subsequently, synthetically produced pure meta-ankoleite remains stable until at least 1150℃ exhibiting no apparent phase changes. In contrast, when present in a mixed waste the meta-ankoleite phase is not identifiable after thermal treatment indicating incorporation within the bulk waste either as an amorphous phase and/or as uranium oxide. Visual inspection of the waste post thermal treatment showed evidence of self-sintering owing to the presence of glass former materials, namely, silica (SiO₂) and antimony(V) oxide (Sb₂O₅). Therefore, incorporation of the uranium phase into the waste as part of waste sentencing and immobilisation via high temperature sintering for the purpose of long-term disposal is deemed feasible.

• Bulletin of the Korean Chemical Society
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• 제29권2호
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• pp.363-371
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• 2008

As a computational method for the discovery of the effective agonists for PPARd, we address the usefulness of molecular dynamics free energy (MDFE) simulation with explicit solvent in terms of the accuracy and the computing cost. For this purpose, we establish an efficient computational protocol of thermodynamic integration (TI) that is superior to free energy perturbation (FEP) method in parallel computing environment. Using this protocol, the relative binding affinities of GW501516 and its derivatives for PPARd are calculated. The accuracy of our protocol was evaluated in two steps. First, we devise a thermodynamic cycle to calculate the absolute and relative hydration free energies of test molecules. This allows a self-consistent check for the accuracy of the calculation protocol. Second, the calculated relative binding affinities of the selected ligands are compared with experimental IC50 values. The average deviation of the calculated binding free energies from the experimental results amounts at the most to 1 kcal/mol. The computational efficiency of current protocol is also assessed by comparing its execution times with those of the sequential version of the TI protocol. The results show that the calculation can be accelerated by 4 times when compared to the sequential run. Based on the calculations with the parallel computational protocol, a new potential agonist of GW501516 derivative is proposed.

• 한국세라믹학회지
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• 제53권6호
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• pp.676-681
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• 2016

For the purpose of reducing the amount of limestone, which is used as a desulfurization agent to absorbing $SO_X$ gas in thermal power plants, and to recycle limestone sludge generated from a steel mill, limestone sludge was utilized as a desulfurization agent. In this study, cement, made of flue gas desulfurization (FGD) gypsum obtained in a desulfurization process using limestone sludge, was manufactured then, experiments were conducted to identify the physical properties of the paste and mortar using the cement. The results of the crystal phase and microstructure analyses showed that the hydration product of the manufactured cement was similar to that of ordinary Portland cement. No significant decline of workability or compressive strength was observed for any of the specimens. From the results of the experiment, it was determined that FGD gypsum manufactured from limestone sludge did not influence the physical properties of the cement also, quality change did not occur with the use of limestone sludge in the flue gas desulfurization process.

• 한국수소및신에너지학회논문집
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• 제22권6호
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• pp.835-841
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• 2011

The humidification is essential for performance enhancement of the electrolysis of PEMFC because proton conductivity depends on hydration of the proton exchange membrane. In this study, the humidification experiment did about On/Off control the humidification and dew condensation for PEMFC by using of the membrane humidifiers. As the results, it was possible to approximation control of the humidity by using of the solenoid valve On/Off control on the membrane humidifier. Also the problem on the dew condensation was resolved by approximation humidity control through solenoid valve On/Off control and the removal of the dew condensation in the flow channel was verified through visualization experiment.

• 방사선산업학회지
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• 제5권2호
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• pp.151-157
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• 2011

Crosslinked SPEEK/PVDF membrane were prepared by EB radiation method with various contents of PVDF. The prepared membranes were subjected to a comparative study of proton exchange membranes for fuel cell appreciations. The crosslinked SPEEK/PVDF membranes were characterized by using DMA, DSC and SAXS. The DMA data indicate that the ionic modulus values and cluster $T_g$ decrease with increasing PVDF content. Thus, it was suggested that the number of clustering in the crosslinked membranes can be reduced with increasing PVDF content. The DSC results were shown that the degree of crystalline of the membrane increased with increasing PVDF content. The morphology of the crosslinkied membranes was shown that with increasing PVDF content, the number of crystalline domain of the SPEEK/PVDF membranes increased but ionic aggregation of the membranes decreased. The water uptake behavior, ionic exchange capacity (IEC) and proton conductivity were decreased with increasing PVDF content. The overall findings suggest that the crosslinked membranes offer the possibility for improving the performance of PEMFC, provided that the membranes have thermal and hydration stability.

• 방사선산업학회지
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• 제6권1호
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• pp.89-94
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• 2012

Three-dimensional network hydrogels were prepared by ${\gamma}$-irradiation of aqueous solutions of poly(vinyl alcohol) (PVA) and glycerol (Gly). Oven-drying was used to measure the gel fraction (G), hydration (H) or swelling behavior (S) of the prepared hydrogels. This study made a hypothesis that hydrogen bonds due to addition of glycerol and change of dry states such as freeze-drying (FD), room-drying (RD) and oven-drying (OD) acts on the G, H, and S. Interesting results on the hydrogen bonding effect in the prepared hydrogels are monitored at different drying conditions. The FD samples have a higher G values with increase in glycerol content as compared with the OD and RD samples. The formation of strong hydrogen bonding network among Gly molecules and hydrogel matrix was considered as the main driving force, resulting in the changes in the G, H, and S of the hydrogels under different drying conditions.

• 태양에너지
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• 제17권1호
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• pp.67-77
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• 1997

본 연구는 에너지 밀도와 승온효과가 큰 화학 열펌프시스템 개발을 위해 무기 수화물계인$Ca(OH)_2/CaO$ 원주형 충전층내 핀을 주입 전열 촉진한 경우에 있어서 반응촉진 효과의 이론적 평가를 행하였다. 그 결과 충전층내 수화 탈수 반응시 반응층내 시간에 따른 온도 분포변화 및 반응율 분포에 대한 수치 해석 결과 전열핀 주입에 따른 반응완결 시간이 절반이하로 줄일 수 있다고 한 실험결과와 잘 일치됨을 알 수 있었다. 또한 해석결과 열화학 반응은 주로 온도 및 농도에 의존하였고 경계조건과 입자 충전층의 열전도에 의해 크게 좌우됨을 알 수 있었다.

• 한국세라믹학회지
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• 제56권5호
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• pp.468-473
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• 2019

This study focused on manufacturing an inorganic insulation material set with various amounts of calcium-sulfoaluminate (CSA) (hauyne) content for enhancing both workability (demolding, handling) and the high thermal insulating property. To carry out the experiment, the amounts of CSA utilized were 5%, 10%, 15%, and 20%, with anhydrous gypsum added in equal proportion to produce a stable formation. As the content of CSA increased, a sinking phenomenon occurred because of the hydration reaction from the slurry, so it was difficult to utilize a retarder normally used in the cement manufacturing process. However, an RCOOM surfactant was able to solve the local clumping problem from cement and CSA and obtain a rapid retarding effect, so it was included in this process at 0.3%. Furthermore, the cement fineness was not 7000 ㎠/g but rather 3300 ~ 4000 ㎠/g to prevent a rapid temperature increase in the slurry. The specific gravity of the sample manufactured with 20% CSA was approximately 0.11 g/㎤, and its thermal conductivity was 0.041 W/m·K, providing an excellent insulating property.