• Title/Summary/Keyword: Hydration effect

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Effect of Microorganism Sporosarcina pasteurii on the Hydration of Cement Paste

  • Lee, Jun Cheol;Lee, Chang Joon;Chun, Woo Young;Kim, Wha Jung;Chung, Chul-Woo
    • Journal of Microbiology and Biotechnology
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    • v.25 no.8
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    • pp.1328-1338
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    • 2015
  • Years of research have shown that the application of microorganisms increases the compressive strength of cement-based material when it is cured in a culture medium. Because the compressive strength is strongly affected by the hydration of cement paste, this research aimed to investigate the role of the microorganism Sporosarcina pasteurii in hydration of cement paste. The microorganism's role was investigated with and without the presence of a urea-CaCl2 culture medium (i.e., without curing the specimens in the culture medium). The results showed that S. pasteurii accelerated the early hydration of cement paste. The addition of the urea-CaCl2 culture medium also increased the speed of hydration. However, no clear evidence of microbially induced calcite precipitation appeared when the microorganisms were directly mixed with cement paste.

Characteristics of early strength development of blended cement according to the addition of C-S-H based Hardening acceleration (C-S-H계 조강제 첨가에 따른 혼합시멘트의 조기 강도 발현 특성)

  • An, Tae-Yun;Ra, Jeong-Min;Park, Jun-Hyung;Kim, Jin-Man
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2022.11a
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    • pp.127-128
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    • 2022
  • In order to realize carbon neutrality in the international society, research on supplementary cementitious materials(SCMs) has been actively conducted as a way to reduce carbon dioxide emissions in the cement industry. However, the use of SCMs causes problems of initial hydration delay and strength reduction due to the reduction of tricalcium silicate(C3S) in the cement clinker. Therefore, in this study, the initial hydration and basic characteristics of cement mortar were confirmed by adding a C-S-H based hardening acceleration to blended cement mixed with Portland cement, blast furnace slag, fly ash, and limestone power. As a result of the heat of hydration and compressive strength test, it was confirmed that when hardening acceleration was added, the initial reactivity was high, so the heat of hydration was promoted, and the initial strength was increased. It is considered to be due to C-S-H seeding effect. Therefore, it is judged that the use of C-S-H based hardening acceleration can supplement the problem of initial hydration delay of blended cement in Korea.

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Effect of TEA on Acceleration Shotcrete (숏크리트용 급결제에 미치는 트리에탄올아민의 영향)

  • Chun, Yong-Jin;Cho, Suk-Hyeong;Hong, Young-Ho;Lee, Gun-Jik
    • Applied Chemistry for Engineering
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    • v.10 no.8
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    • pp.1124-1128
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    • 1999
  • In this study the effect of organic additive, triethanolamine(TEA), and temperature change of accelerator for shotcrete was studied. Then the amount of accelerator, temperature and W/C were experimentally investigated. Effects of hydration time and hydration heat of concrete on organic additive amount were analysed by DSC, SEM and XRD. We found that the hydration heat was increased and hydration time was decreased with TEA(<5 wt %). The order of hydration rate of potassium accelerator was PA < PC-3 < PC-5 < PC-8.

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Production of Sphingolipids by Submerged Culture of Ganoderma lucidum and Cutaneous Hydration Effect (Ganoderma lucidum 균사체의 액체배양의 의한 sphingolipids의 생산 및 피부 보습 효과)

  • Ryu, Il-Hwan;Kim, Jung-Enn;Lee, Kap-Sang
    • Korean Journal of Food Science and Technology
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    • v.36 no.4
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    • pp.655-661
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    • 2004
  • Sphingolipid production was investigated through Ganoderma lucidum-submerged cultivation. Crude sphingolipid obtained from G. lucidum was purified by methanol precipitation, Dowex AG DW-X8 (H+ form) cation exchange chromatography, and preparative thin layer chromatography, Structure and functionalities of purified sphingolipid were elucidated including cutaneous hydration effect. Possibility of use as cosmetics material and new biomaterial was explored. Production was 0.4 g/L at 1% yield. Purified sphingolipid was identified as D-ribo-1,3,4-trihydroxy-2-aminoocta decan through UV/VIS, FT-IR, and $^1H-NMR$. Sphingolipids increased skinmate value for cutaneous hydration effect by 20% at $500\;{\mu}g/mL$ and decreased skin roughness at $100\;{\mu}g/mL$. Results suggest shingolipids from G. lucidum are effective for cutaneous hydration and improvement of skin roughness.

Effect of Defatting on Hydration of Akibare (Japonica) and Milyang 30 (J/lndica) Rice (탈지에 따른 아끼바레 및 밀양30호 쌀의 수화속도)

  • Kim, Soon-Mi;Kim, Kwang-Ok;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.18 no.2
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    • pp.110-113
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    • 1986
  • Effect of defatting on the hydration rate of Akibare (Japonica) and Milyang 30 (J/lndica) rice was investigated. Relative crystallinity of rice starch and width of the rice grain were decreased by defatting, which was more pronounced for Milyang 30. The moisture gain at $10^{\circ}{\sim}40^{\circ}C$ for 80 min and the hydration rate of the defatted Milyang 30 rice were lower and higher than those of the defatted Akibare rice, respectively. The activation energy for hydration of rice was not affected by defatting.

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The Effect of the Structural State of Silica on the Pozzolanic Reactivity (Silica의 형태가 Pozzolan 반응성에 미치는 영향)

  • 한기성
    • Journal of the Korean Ceramic Society
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    • v.11 no.1
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    • pp.10-18
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    • 1974
  • The hydration at $23^{\circ}C$ between $Ca(OH)_2$ and siliceous materials with various compositions of silica gel and quartz were studied in paste state, and also diatomite was empolyed as another form of silica. The effect of the structural state of silica on the pozzolanic reactivity was investigated by X-ray, DTA, electron microscopy, and chemical analysis. The results obtained were as follows. (1) The molar ratio of $Ca(OH)_2$ to silica gel(C/Sg) being changed in 0.49, 0.81 and 1.22, the free $Ca(OH)_2$ was disappeared within six hours, three days and two weeks respectively and ill-crystallized CSH(I) was formed. However, in the case fo molar ratio of C/Sg=2.45, almost lime was remained uncombinedly after twenty four weeks yet. (2) Though the molar ratio C/Sg of diatomite was 0.71, the hydration was stabilized at three weeks and the result exhibited very peculiar characteristics from silica gel. (3) Pozzolanic reactivity of quartz was negligible, but $\alpha$-cristobalite in diatomite showed appreciable reactivity. (4) The thermal curves showed the exothermic peaks in the range 830 to $930^{\circ}C$ and lower broad peaks at high temperature in the initial steps of hydration, transfered to lower temperature with sharp peaks by proceeding of hydration. (5) The samples containing more silica gel exhibited higher pozzolanic reactivity and martar strength, but the diatomite gave remarkable result for them and they were matched to the strength development rate.

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Effect of Recirculation of Rotary Kiln Exhaust Gas for the Carbonation of Lime on the Combustion Conditions and the Amounts of NOx (생석회 탄산화를 위한 회전로 배가스 재순환이 연소 및 NOx 발생양에 미치는 영향)

  • Lee Man-Seung;Lee Si-Hyunh
    • Resources Recycling
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    • v.12 no.1
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    • pp.41-47
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    • 2003
  • In order to improve the hydration resistance of lime in the air at room temperature, carbonation and hydration experiments have been conducted. Carbonation of the surface of lime by about 6 wt% was needed to suppress the hydration of lime used in steel-making. The effect of recirculation of rotary kiln exhaust gas for the carbonation of lime on the combustion temperature and NOx concentration was analyzed by thermodynamics. From the thermodynamic calculation results, it was frond that the equi-librium combustion temperature and NOx concentration decreased with increasing volume percentage of exhaust gas.

The Effect of Water on the Interface Shear Strength between Geosynthetics (물이 토목섬유 사이의 접촉 전단강도에 미치는 영향)

  • 서민우;박준범;박인준
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.03a
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    • pp.321-328
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    • 2002
  • Various geosynthetics used as liners or the Protection layers are installed in the solid waste landfill. The interface shear strength between geosynthetics installed at the slope of the landfill is a very important variable for the safe design of bottom and cover systems in the solid waste landfill. The interface shear strengths between (1) Geomembrane(GM)/Geotexile(GT) and (2) Geomembrane(GM)/Geosynthetic Clay Liner(GCL) were estimated by a large direct shear test in this study and were evaluated by the Mohr-Coulomb failure criterion. Especially, this research is focused on the effect of water which exists between geosynthetics because interfaces become easily wet or hydrated by rain, leachate and groundwater beneath liners. The strength reduction at large displacement and the effects of the magnitude of normal stresses and GCL hydration methods also investigated. The test results showed that the interface shear strength and shear behavior varied depending upon the magnitude of normal stresses, water at the interface, and hydration methods. Summary of secant friction angles, which could be used as reference values at a site where similar geosynthetics are installed, together with normal stress and hydration condition are presented.

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Influences of Sodium Gluconate on the Physical Properties of Portland Cement Pastes and Mortars (포틀랜드 시멘트 페이스트 및 몰탈의 물성에 미치는 글루콘산 나트륨의 영향)

  • 김창은;이승헌;김원기;이경원
    • Journal of the Korean Ceramic Society
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    • v.24 no.3
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    • pp.289-295
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    • 1987
  • The changes of physical properties of portland cement pastes and mortars were investigated by addition of sodium gluconate. Flow table experiment and viscosity measurement were took in order to find dispersing effect, and time-dependent changesof viscosity and rates of hydration heat evolution were carried out for the sake of finding retardation effect of hydration. And changes of physical properties of cement pastes and mortars were discussed by setting time, compressive strength and porosity.

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A novel Fabry-Perot fiber optic temperature sensor for early age hydration heat study in Portland cement concrete

  • Zou, Xiaotian;Chao, Alice;Wu, Nan;Tian, Ye;Yu, Tzu-Yang;Wang, Xingwei
    • Smart Structures and Systems
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    • v.12 no.1
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    • pp.41-54
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    • 2013
  • Concrete is known as a heterogeneous product which is composed of complex chemical composition and reaction. The development of concrete thermal effect during early age is critical on its future structural health and long term durability. When cement is mixed with water, the exothermic chemical reaction generates hydration heat, which raises the temperature within the concrete. Consequently, cracking may occur if the concrete temperature rises too high or if there is a large temperature difference between the interior and the exterior of concrete structures during early age hydration. This paper describes the contribution of novel Fabry-Perot (FP) fiber optic temperature sensors to investigate the thermal effects of concrete hydration process. Concrete specimens were manufactured under various water-to-cement (w/c) ratios from 0.40 to 0.60. During the first 24 hours of concreting, two FP fiber optic temperature sensors were inserted into concrete specimens with the protection of copper tubing to monitor the surface and core temperature change. The experimental results revealed effects of w/c ratios on surface and core temperature developments during early age hydration, as well as demonstrating that FP fiber optic sensors are capable of capturing temperature variation in the concrete with reliable performance. Temperature profiles are used for calculating the apparent activation energy ($E_a$) and the heat of hydration (H(t)) of concrete, which can help us to better understand cement hydration.