• Journal of the Korea Concrete Institute
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• v.27 no.2
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• pp.95-102
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• 2015

In this paper, the effects of sodium hydroxide (NaOH) and aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) dosage on strength properties were investigated. For evaluating the property related to the dosage of alkali activator, sodium hydroxide (NaOH) of 4% (N1 series) and 8% (N2 series) was added to 1~5% (K1~K5) dosage of aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) and 1% (C1) and 2% (C2) dosage of calcium oxide (CaO). W/B ratio was 0.5 and binder/ fine aggregate ratio was 0.5, respectively. Test result clearly showed that the compressive strength development of alkali-activated slag cement (AASC) mortars were significantly dependent on the dosage of NaOH and $AlK(SO_4)_2{\cdot}12H_2O$. The result of XRD analysis indicated that the main hydration product of $NaOH+AlK (SO_4)_2{\cdot}12H_2O$ activated slag was ettringite and CSH. But at early ages, ettringite and sulfate coated the surface of unhydrated slag grains and inhibited the hydration reaction of slag in high dosage of $NaOH+AlK(SO_4)_2{\cdot}12H_2O$. The $SO_4{^{-2}}$ ions from $AlK(SO_4)_2{\cdot}12H_2O$ reacts with CaO in blast furnace slag or added CaO to form gypsum ($CaSO_4{\cdot}2H_2O$), which reacts with CaO and $Al_2O_3$ to from ettringite in $NaOH+AlK(SO_4)_2{\cdot}12H_2O$ activated slag cement system. Therefore, blast furnace slag can be activated by $NaOH+AlK(SO_4)_2{\cdot}12H_2O$.

• International Journal of Highway Engineering
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• v.1 no.1
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• pp.107-119
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• 1999

The joints in the jointed concrete pavement provide a control against transverse or longitudinal cracking at slab, which may be caused by temperature or moisture variation during or after hydration. Without control of cracking, random cracks cause more serious distresses and result in structural or functional failure of pavement system. However, joints nay cause distresses due to its inherent weakness in structural integrity. Thus, the evaluation at joint is very important. and the joint-related distresses should be evaluated reasonably for economic rehabilitation. The purpose of this paper was to develop an evaluation system at joints of jointed concrete pavement using finite element analysis program, ILLI-SLAB, and nondestructive testing device. FWD. To develop an evaluation system for JCP, a sensitivity analysis was performed using ILLI-SLAB program with a selected variables which might affect fairly to on the performance of transverse joints. The most significant variables were selected from precise analysis. An evaluation charts were made for jointed concrete pavement by adopting the field FWD data. It was concluded that the variables which most significantly affect to pavement deflections are the modulus of subgrade reaction(K) and the modulus of dowel/concrete interaction(G), and limiting criteria on the performance of joints at JCP are 300pci. 500,000 lb/in. respectively. Using these variables and FWD test, a charts of load transfer ratio versus surface deflection at joints were made in order to evaluate the performance of JCP. Practically, Chungbu highway was evaluated by these evaluation charts and FWD field data for jointed concrete pavement. For Chungbu highway, only one joint showed smaller value than limiting criterion of the modulus of dowel/concrete interaction(G). The rest joints showed larger values than limiting criteria of the modulus of subgrade reaction(K) and the modulus of dowel/concrete interaction(G).

• Journal of the Korean Recycled Construction Resources Institute
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• v.2 no.4
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• pp.360-366
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• 2014

In this study, effect of types and replacement ratio of alkali activator on compressive strength of ground granulated blast furnace slag mortar has been reviewed. Types of alkali activator are NaOH, $Ca(OH)_2$, $Na_2SO_4$, and KOH. Replacement ratio of alkali activator is 7.5, 10, 12.5, and 15%, respectively. As results, under high temperature curing condition, 1 day compressive strength development with NaOH and KOH was higher than that of $Ca(OH)_2$ and $Na_2SO_4$. Regardless of types of alkali activator, compressive strength increased with increasing pH. This can be explained by the fact that impermeable film on the surface of slag which is generated when slag contacts water has been destroyed by alkali activator, and this promotes hydration reaction. Also, 1 day age compressive strength of specimen with high temperature curing was higher than that of specimen with standard curing. 28 days age compressive strength of specimen with high temperature curing was less than or equal to that of specimen with standard curing.

• Journal of the Korea Concrete Institute
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• v.18 no.1 s.91
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• pp.125-132
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• 2006

Recently, surface finishing and protection materials were developed to restore performance of the deteriorated concrete and inhibiting corrosion of the reinforcing-bar. For this purpose, surface protection agent as well as coatings are used. Coatings have the advantage of low Permeability of $CO_2,\;SO_2$ and water. However, for coatings such as epoxy, urethane and acryl, long-term adhesive strength is reduced and the formed membrane of those is blistered by various causes. Also when organic coatings are applied to the wet surface of concrete, those have a problem with adhesion. On the other hand, surface protection agent penetrates into pore structure in concrete through capillary and cm make a dense micro structure in concrete as a result of filling effect. Furthermore, the chemical reaction between silicate from surface protection agent and cement hydrates can also make a additional hydration product which is ideally compatible with concrete body. The aim of this study is to examine the effect of penetrative surface protection agent(SPA) by evaluating several concrete durability characteristics. The results show that the concrete penetrated surface protection agent exhibited higher durability characteristics for instance, carbonation velocity coefficient, resistance to chemical attack and chloride ion penetration than the plain concrete. These results due to formation of a discontinuous macro-pore system which inhibits deterioration factors of concrete by changed the pore structure(porosity and pore size distributions) of the concrete penetrated surface protection agent.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.33 no.1 s.60
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• pp.17-22
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• 2007

In this study, we investigated the effects of Sedum sarmentosum extract on the expression of hyaluronan synthase (HAS) genes and hyaluronan (HA) production in HaCaT keratinocytes. We also assessed water content (electrical capacitance) and transepidermal water loss (TEWL) in human skin after topical treatment with Sedum sarmentosum extract. Sedum sarmentosum extract increased expression of HAS-2 and HAS-3 genes in HaCaT cells, when assayed by real-time reverse-transcriptase polymerase chain reactions (RT-PCR). Sedum sarmentosum extract induced HA production in HaCaT cells, when determined by enzyme-linked immunosorbent assay (ELISA). Finally, treatment of Sedum sarmentosum extract on human skin increased the skin hydration and decreased TEWL when measured using Corneometer and Tewameter. Our study suggests that Sedum sarmentosum extract should be a very useful cosmetic ingredient, as a skin moisturizer.

• Journal of the Korea Institute of Building Construction
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• v.13 no.6
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• pp.602-608
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• 2013

The aim of this study is to investigate experimentally the effect of the combination of fine particle cement with high Blaine fineness (FC) and recycled aggregates on the engineering properties and micro structure of high volume blast furnace slag (BS) concrete with 75% BS and 21 MPa. FC manufactured by particle classification at the plant with Blaine fineness of more than $7000cm^2/g$ was used as additional alkali activator for high volume blast furnace slag concrete made with recycled fine and coarse aggregates. FC was replaced by 15, 20 and 25% OPC. Test results showed that the incorporation of FC resulted in an increase in the compressive strength compared to BS concrete without FC by as much as 30% due to accelerated hydration and associated latent hydraulic reaction. It was found that the use of FC and recycled aggregates played an important role in activating BS for high volume BS concrete by offering sufficient alkali.

• Journal of the Korea Concrete Institute
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• v.27 no.3
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• pp.237-244
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• 2015

Entering the 20th century since the industrial revolution, the cement has been widely used in the field of construction and civil engineering due to the remarkable development of construction industry. However, result from that development, each kind of industrial by-products and waste and the carbon dioxide generated in the process of cement production cause air pollution and environmental damage so earth is getting sick now slowly. Therefore, we have to recognize importance about this. It means that the time taking specific and long-term measures have come. In this research paper, as substitution of the cement generating environmental pollution, we investigate the hydration reaction of non-Sintered Cement mortar mixed with GBFS, active stimulant of alkaline and sulphate series by using SEM and XRD, mechanical and chemical properties according to the curing method. As a result of this experiment, NSC realized outstanding strength for water curing and steam curing. It means that it has a good possibility as substitution of cement. From now on, it can be used for structure satisfying specific standard. We expect to find a substitution of outstanding cement by progressing continuous research making the best use of pros and cons according to the curing method.

• Journal of the Korea Concrete Institute
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• v.28 no.3
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• pp.299-308
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• 2016

This paper presents an investigation of the mechanical and microstructural properties on hardened samples that were synthesized using blended binder(fly ash(FA) and blast furnace slag cement(BFSC)), alkali activator and sea water or distilled water. Binders were prepared by mixing the FA and BFSC in different blend weight ratios of 6:4, 7:3 and 8:2. Sodium hydroxide and sodium silicate were used 5 wt% of binder, respectively, as an alkaline activator. The compressive strength and absorption were measured at the age of 3, 7 and 28 days, and the XRD, TGA and MIP tests were performed at the age of 28 days. An increase in the content of BFSC leads to an increase in the quantities of ettringite and C-S-H formed, regardless of the type of mixing water. And it also shows higher strength due to the reduction of pores larger than ~50 nm. All hardened samples in this study have common hydration products of C-S-H, $Ca(OH)_2$ and calcite. Hydrocalumite of all reaction products formed was only present in hardened sample mixed with sea water. For each FA/BFSC mixing ratio, the compressive strength of hardened sample mixed with sea water was similar to that mixed with distilled water. It is proposed that the slight increase of strength of samples mixed with sea water is mainly due to the presence of hydrocalumite phase containing chlorine ion, contributing to the change of total porosity and pore size distribution in samples.

• Journal of the Korea Concrete Institute
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• v.19 no.3
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• pp.359-366
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• 2007

Recently, analysis researches on durability are focused on chloride attack and carbonation due to increased social and engineering significance. Generally, chloride penetration and carbonation occur simultaneously except for in submerged condition and chloride behavior in carbonated concrete is evaluated to be different from that in normal concrete. Furthermore, if unavoidable crack occurs in concrete, it influences not only single attack but also coupled deterioration more severely. This is a study on analysis technique with system dynamics for chloride penetration in concrete structures exposed to coupled chloride attack and carbonation through chloride diffusion, permeation, and carbonation reaction. For the purpose, a modeling for chloride behavior considering diffusion and permeation is performed through previous models for early-aged concrete such as MCHHM (multi component hydration heat model) and MPSFM (micro pore structure formation). Then model for combined deterioration is developed considering changed characteristics such as pore distribution, saturation and dissociation of bound chloride content under carbonation. The developed model is verified through comparison with previous experimental data. Additionally, simulation for combined deterioration in cracked concrete is carried out through utilizing previously developed models for chloride penetration and carbonation in cracked concrete. From the simulated results, CCTZ (chloride-carbonation transition zone) for evaluating combined deterioration is proposed. It is numerically verified that concrete with slag has better resistance to combined deterioration than concrete with OPC in sound and cracked concrete.

• Journal of the Korean Chemical Society
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• v.45 no.2
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• pp.116-120
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• 2001

In order to know the physicochemical properties of magnetized water, the experimental methods of column assay, crystalization of saltsand gypsom have been explored to elucidate the effects of magnetized water on the solubility speed of salts, crystal pattern from salt squeous solutions, and gypsom crystal pattern, respectively. In the column assay for salt solubility the magnetized water showed the decreased initial solubility speed of NaCl and slightly increased initial solubility spped of KCI, however, the maximum solugilities of NaCl and KCI in the magnetized aster were almost same in the double distilled water, respectively. The column assay also indicated that the magnetized water showed the decreased initial solubility speed of urea (CH$_4$N$_2$O), sodium citrate (HOC(CO$_2$Na)-(CH$_2$CO$_2$Na)$_2$-2H$_2$O) and (NH$_4$)$_2$compared to the double distilled water, while slightly increased solubility speed of glycine (NH$_2$CH$_2$COOH), boric acid (H$_3$BO$_3$), MgSO$_4$. Crystalization of 1% or 5% salt aqueous solutions by rapid evaporation disclosed that the magnetized water produced more condensed and bigger crystal structure than the control water. The pattern of gypsom crystal formation also indicated that the magntized water enhanced the crystal formation in the hydration reaction of gypsom plaster compared to the double distilled water. Taken together, it was presumed that the magnetized water showed the different physicochemical properties in the interaction with various salts, especially showed the contrast results between NaCl and KCI.