• Proceedings of the Korea Concrete Institute Conference
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• 1996.10a
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• pp.148-153
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• 1996

Concrete with ground granulated blast-furnace slag can be affected by frost attack because the reaction of hydration is slow at the early age. In this study, therefore, the freezing and thawing test has been carried out to investigate the freezing and thawing resistance on concrete with ground granulated blast-furnace slag. The freezing and thawing test has been performed on concrete a blended cement, which was substituted by ground granulated blast-furnace slag with 4 kinds of ratio (non-admixture, 20%, 40% and 60%). And also tested on concrete added the AE agents to the concrete of same mix proportion to search the improvement effects about the resistance. As a result, the freezing and thawing resistance showed a tendency of reduction in proportion to the increase of the substitution ratio. For non-AE concrete, resistances of the freezing and thawing were very poor as the durability index indicated less than 5.8%. For AE concrte, resistance of the freezing and thawing were excellent as the durability index indicated more than 80.9%.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10b
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• pp.1215-1220
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• 2000

Blast-Furnace Slag, a by-product of the iron or steel industry, has potential sa a cementitious material. The addition of a Blast-Furnace Slag generally reduces the heat of hydration and can confer significant improvements in resistance to sulfate attack and alkali-aggregate reaction, as well as increases in ultimate strength. But it also reduces early-age strength. In this study, for the purpose of improvement of early-age quality of Blast-Furnace Slag concrete, we choose blaine fineness of $6, 000~8, 000cm^2/g$ of Blast-Furnace Slag, and investigate the various properties of concrete. As a result, workability and early-age strength of Blast-Furnace Slag concrete were improved according to the increase of blaine fineness of Blast-Furnace Slag.

• Bulletin of the Korean Chemical Society
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• v.24 no.10
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• pp.1437-1443
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• 2003

Thermal decomposition of hydrated surface layer of $Mg(OH)_2$ at $500^{\circ}C$ in vacuum turned non-porous MgO into porous one with high surface area of around $270 m^2$/g. Most of its surface area, 74 %, was from micropores, and rest of it was from mesopores in wedge-shaped slits, exhibiting bimodal size distribution centered around 30 and 90${\AA}$. Rehydration followed by subsequent dehydration at $300 ^{\circ}C$ in dynamic vacuum further raised the surface area to 340 $m^2$/g. Fraction of microporous surface area was increased to 93%, and the shape of the mesopores was modified into parallel slits with a specific dimension of 32 ${\AA}$. Application of $Fe_2O_3$ over MgO via iron complex formation did not alter the pore characteristics of MgO core, except slightly increased pore dimension. Over the course of the modification, $Fe_2O_3$ stayed on the surface possibly via spill-over reaction.

• Bulletin of the Korean Chemical Society
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• v.25 no.6
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• pp.786-790
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• 2004

2-Aminoethanethiol (aet) has been used to make self-assembled monolayer (SAMs) on gold electrodes, which are subsequently modified with 3,4-dihydroxy phenylalanine (dpa). Such modified electrodes having various types of Au/aet-dpa were employed in the electrocatalytic oxidation of NADH. The purpose of this study to characterize the responses of such modified electrodes in terms of the immobilization procedure, pH of the solution and applied potential. The reaction of the surface immobilized dpa with NADH was studied using the rotating disk electrode technique and a value of $2.2{\times}10^4M^{-1}s^{-1}$ was obtained for the second-order rate constant in 0.1 M Tris/$NO_3^-$buffer (pH=8.0). The hydration behavior of the films was characterized by quartz crystal microbalance. When used as a NADH sensor, the Au/aet-dpa electrode exhibited good sensitivity and an excellent correlation (r ${\geq}$ 0.99) for NADH concentration which extended to $3.8{\times}10^{-3}$ M.

• Journal of the Korea Institute of Building Construction
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• v.2 no.4
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• pp.163-168
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• 2002

The object of this study is to define the characteristics of high performance concrete with varing compressive strength of concrete and curing temperature. The major test variables are 1) high strength concrete(500kg/$cm^2$) and ordinary strength concrete(240kg/$cm^2$) compressive strength, 2) curing temperature and condition, 3) concrete curing age, 4) three types of cement. From the test results were shown that curing temperature and curing conditions were also very effective for high strength concrete and ordinary strength concrete, and concrete were largely effected by cement type and temperature during the hydration reaction process. This paper describes the effect of curing temperature for strength and characteristics of high performance concrete.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.56-57
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• 2013

In this study, in regard to concrete considering variety of admixture content rate, we evaluated property of adiabatic temperature rise. By setting up high temperature history, we evaluated effect to compression strength property of high strength concrete by early high temperature history. As a result, early high temperature history accelerated Hydration reaction of cement and contribute early strength development but it didn't accomplish performance objective in long-term aged.

• Bulletin of the Korean Chemical Society
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• v.9 no.4
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• pp.240-243
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• 1988

Degradation of the 90 K superconductor $YBa_2Cu_3O_{7-{\delta}}$ in water and humid atmosphere were studied and its decomposition products were identified as $BaCO_3$, CuO, $Y_2(CO_3)_3{\cdot}3H_2O$ and $O_2$. XRD analysis, iodometric titration and IR-spectroscopy of the degraded samples suggest that the $YBa_2Cu_3O_{7-{\delta}}$ decomposes in three steps such as the reduction of $Cu^{3+}$ to $Cu^{2+}$, followed by the hydroxylation of $Ba^{2+}$ and $Y^{3+}$ via hydration and finally the formation of carbonates through the uptake of ambient $CO_2$.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.11a
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• pp.73-74
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• 2020

Predicting the compressive strength of concrete is important for shortening construction time and reducing construction costs. In this study, the coefficients required for maturity method and compressive strength prediction equation were calculated by measuring the cement hydration reaction rate, concrete setting time and ultimate strength. The experiment was conducted in an isothermal environment of 10℃, 20℃ and 30℃ using a normal Portland cement, and the experiment was conducted with a total of 9 levels of W/C (40%, 50%, 60%) of 3 levels for each temperature. As a result of comparing the predicted strength and the measured strength for each blend, only an error of less than 5% was found for all blending and curing periods.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.111-112
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• 2022

In this present study, the corrosion mitigation effect of conifer cone extract (CC) was examined in the cement mortar to improve the steel rebar (SR) corrosion resistance. The corrosion inhibition properties of the SR embedded in cement mortar (CM) admixed with different percentage (0, 0.5, 1.0, 1.5, 2.0 %) of CC was studied by open circuit potential (OCP) and electrochemical impedance spectroscopy (EIS) tests. This result confirms that the CM with 0.5% of CC added has better corrosion resistance than the blank specimen (0 % of CC). Although, the percentage of CC increase above 0.5%, the CC could yield a negative impact on CM properties in terms of reducing the corrosion resistance due to the reduction of cement hydration reaction. It was highlighted that the SR embedded in CM containing 0.5% of CC had increased corrosion resistance.

• Cement Symposium
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• s.49
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• pp.21-22
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• 2022

The purpose of this study is to reduce carbon dioxide emissions in the cement industry and to collect carbon dioxide generated in industrial facilities such as cement factories and thermal power plants, store and utilize it, and convert high-value-added resources. While conventional Ordinary Portland Cement is characterized by hardening through hydration reactions, basic research is underway to develop cement that reacts with carbon dioxide and converts it into carbonate mineralization.