• Journal of Korean Society for Atmospheric Environment
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• v.10 no.1
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• pp.24-31
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• 1994

Hourly variation of gaseous nitrous acid( HNO$_2$) concentration in Seoul air was monitored from Jan. 11 to SeP. 12, Nitrous acid concentration was determined by DS/IC over nine months of observation, HNO$_2$ range from 0.04 ppb to 5.5 ppb. Gor-tex tube as gaseous HNO$_2$generator in this study is thought to be more convenient and reproducible device than previous generator. As a result of NaOH instead of Na$_2$ CO$_3$/NaHCO$_3$ solution as the IC eluent, we could obtain more stable baseline. The concentration of the NaOH eluent was 15 mM . The limit of detection(3$\sigma$) of the liquid- Phase and gas phase nitrous acid of this method are 1.1ng/$m\ell$ , 0.04 n $\ell$ / $\ell$, respectively. The precisions evaluated by 10 replicate analysis of standard solution and standard gas generated are $\pm$1.59, $\pm$2. 89% RSD, respectively. Due to the lack of standard material for air, direct assessment of the accuracy was not possible. This study was applied to the analysis of Seoul ambient air and their results are reported herein.

• Journal of Korean Society for Atmospheric Environment
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• v.23 no.4
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• pp.466-477
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• 2007

To understand particle pollution phenomena caused by vehicles, black carbon (BC) concentrations were continuously monitored using an aethalometer at a roadside in Seoul during the period of May 79 to 25, 2005. The BC concentration was highly fluctuated for a short duration, responding to the traffic situation on the road. The lowest BC concentration was observed between 2 and 5 a.m. The local highest BC concentrations were observed during the periods of both morning and evening rush hours. Change in traffic volume accounts for the trend of hourly averaged BC concentrations from the late evening to the morning. Particularly, the slower increase of BC concentration on Sunday seems to respond directly the lower traffic volume in the morning rush hours. From the comparison with a previous work, it is concluded that the BC concentration around midday hours might be dependent on the distance from a road.

• Journal of Environmental Science International
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• v.13 no.1
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• pp.27-36
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• 2004

Present study analyzed the temporal and spatial characteristics of PM10 pollution in Metropolitan Daegu area based on air pollution monitoring station data and measurements of PM10 concentrations in background area in order to provide essential data for efficient PM10 pollution management. The significant variation of spatial and temporal PM10 concentrations in Daegu area was observed during the study years. The highest maximum PM10 concentration(332 $\mu\textrm{g}$/㎥), average concentration(88 $\mu\textrm{g}$/㎥) and frequency exceeding PM10 daily standard(150 $\mu\textrm{g}$/㎥) were all observed in Namsandong located near a major roadway. The hourly and weekly variations of PM10 concentrations had different pattern for the measurement sites. The monthly and seasonal concentrations exhibited a notable characteristic： the maximum concentration was obtained in spring season, most likely due to Yellow sand effects. Furthermore, this temporal variation of PM10 pollution varied with study site. Meanwhile, the PM10 values measured at the monitoring site, Manchondong, were comparable with those of a control site. The average PM10 concentration ranged from 23 $\mu\textrm{g}$/㎥ to 115 $\mu\textrm{g}$/㎥ with a mean value of 53 $\mu\textrm{g}$/㎥ in the former site and from 22 $\mu\textrm{g}$/㎥ to 91 $\mu\textrm{g}$/㎥ with a mean value of 45 $\mu\textrm{g}$/㎥ in the latter site.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.2
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• pp.259-266
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• 2006

A dual-channel glass coil sampling technique was used to measure hourly formaldehyde concentration in the ambient air. The dual-channel coil sampling assembly consists of three parts; an all-pyrex 28-turn coil made of 0.2-cm internal diameter glass tubing for gas-liquid contact and scrubbing of soluble gases, an inlet section upstream of the coil for introducing sample air and scrubbing solution, and a widened glass section downstream of the coil for gas-liquid separation. The scrubbing solution used was a dilute aqueous DNPH (dinitrophenylhydrazine) solution. Hourly concentration of formaldehyde was determined at a Gwangju semi-urban site during two intensive studies between September and October using the dual channel glass-coil/DNPH sampling technique and HPLC (High Performance Liquid Chromatography) analysis. The mean concentration was 1.7($0.4{\sim}4.7$) and 3.0($0.5{\sim}19.1$) ppbv for the September and October intensives, respectively, which are considerably low, compared to those measured in polluted urban areas around the world including several urban areas of Korea. The diurnal variation showed significant increase of formaldehyde in the daytime suggesting the dominance of formation of formaldehyde due to photochemical oxidation of methane and other hydrocarbons. An increase in the formaldehyde sometimes in the night might be due to an increase in primary source, i.e. traffic emissions. It was also found that rapid increase in formaldehyde levels from 3.0 to 19.1 ppbv in the afternoon on October 20 was due to plumes from burning of agricultural wastes such as rice straw and stubble. It is expected from the measurement data that the constructed dual-channel glass coil sampling system can be utilized for measuring atmospheric concentration of the formaldehyde with high time resolution.

• Journal of the Korean Ceramic Society
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• v.43 no.12 s.295
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• pp.812-822
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• 2006

This study amis to investigate the functional analysis of anode and cathode materials in Anode supported Solid Oxide Fuel Cell. The concentration polarization of single cell was investigated with CFD (Computational Fluid Dynamics) method for the case of the different morphology by using four types of unit cell and discussed to reduce the concentration polarization. The concentration polarization at anode side effected the voltage loss in Anode supported Solid Oxide Fuel Cell and increased contact areas between fuel gas and anode side could reduce the concentration polarization. For intermediate temperature operation, Anode-supported single cells with thin electrolyte layer of YSZ (Yttria-Stabilized Zirconia) were fabricated and short stacks were built and evaluated. We also developed diesel and methane autothermal reforming (ATR) reactors in order to provide fuels to SOFC stacks. Influences of the $H_2O/C$ (steam to carbon ratio), $O_2/C$ (oxygen to carbon ratio) and GHSV (Gas Hourly Space Velocity) on performances of stacks have been investigated. Performance of the stack operated with a diesel reformer was lower than with using hydrogen as a fuel due to lower Nernst voltage and carbon formation at anode side. The stack operated with a natural gas reformer showed similar performances as with using hydrogen. Effects of various reformer parameters such as $H_2O/C$ and $O_2/C$ were carefully investigated. It is found that $O_2/C$ is a sensitive parameter to control stack performance.

• Proceedings of the Korea Water Resources Association Conference
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• 2015.05a
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• pp.221-221
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• 2015

Sustainable use of water resource and conservation of water quality are essential problems in the world. Especially, problems of water quality are serious one for human health as well as ecological system of all creatures on the earth. Recently, the importance of total effluent load as well as the concentrations of pollutant materials has been recognized not only for the conservation of water quality but also for sustainable water use in watersheds. However, the measurement or estimation of total effluent load from non-point source area such as farm lands or forests may be more difficult because both of concentration and discharge of the water are greatly changed depending on various factors especially metrological conditions such as rainfall, while the measurement from a point source area may be easy because the concentration of pollutant materials and amount of discharge water are relatively steady. Therefore, the total effluent load from a non-point source is often estimated by statistical relationships between concentration and discharge, which is called as L-Q equation. However, a lot of work and time are required to collect and analyze water samples and to get the accurate relationship or regressive equation. So, we proposed a new system for direct measurement of total effluent load of water quality from non-point source areas to solve the problem. In this system, the overflow depth at a hydraulic weir is measured with a pressure gage every hourly interval to calculate the amount of hourly discharge at first. Then, the operating time of a small electric pump to collect an amount of water which is proportional to the discharge is calculated to intake the water into a storage tank. The stored water is taken out a few days later in a case of storm event or several weeks later in a case of non-rainfall event and the concentrations of water quality such as total nitrogen and phosphorous are analyzed in a laboratory. Finally, total load of the water quality can be calculated by multiplying the concentration by the total volume of discharge. The system was installed in a small experimental forestry watershed to check the performance and know the total load of water quality from the forest. It was found that the system to collect a proportional amount of water to actual discharge operated perfectly and a total load of water quality was analyzed accurately. As the result, it was expected that the system will be very available to know the total load from a non-point source area.

• Journal of Environmental Impact Assessment
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• v.30 no.4
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• pp.237-246
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• 2021

The similarity of hourly PM₁₀ and PM_2.5 concentration profiles of the atmospheric monitoring stations in Gyeonggi-do was evaluated through the multilateral analysis between stations. The existing category for most stations in the regions shows relatively low Pearson correlation values of 0.68 and 0.7 for PM₁₀ and PM_2.5 on average respectively, and some monitoring stations revealed high relationships over 0.8 to other regions. Since the current regions are mainly categorized by cluster analysis based on the number of occurrence of high concentration events and geological factors, it is necessary to reclassify them by concentration characteristics for precise fine dust management. In accordance, multi-dimensional scaling being able to visualize could categorize the regions based on regional emission contribution rate and hourly fine dust concentration. As a result of the current analysis, PM₁₀ and PM_2.5 could be reclassified into five regions and fourregions, respectively.

• Kosin Medical Journal
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• v.33 no.2
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• pp.171-180
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• 2018

Objectives: We investigated whether asthma attacks in asthmatic children were caused by short-term exposure to particulate $matter(PM)_{2.5}$. Methods: Subjects were 411 patients who received inhalation therapy in National Fukuoka Hospital, from March to May 2013. All subjects were outpatients. We surveyed the air quality measurement results in the stations closest to the address of the patients. Data were used from the City of Fukuoka website data on air pollution. We carried out a case-crossover study and compared $PM_{2.5}$ concentration between 7 days after asthma attack occurred and the day asthma attack occurred and 1, 2 and 3 days before asthma attack occurred. Results: Highest hourly concentration of the day (OR 1.013, 95%CI 1.000-1.025) showed a significant association with 1 day before $PM_{2.5}$ concentration statistically. And 0-1 year-old infants were more vulnerable to the highest concentration of 1 day before $PM_{2.5}$ concentration(P < 0.05). Average concentration of $NO_2$ and $O_3$ and asthma attack also showed a significant association. Conclusions: Maximal daily $PM_{2.5}$ concentrations within 24 hours prior to the attack affect asthma exacerbation. 0-1 year-old infants are particularly vulnerable to $PM_{2.5}$ concentration. Asthma exacerbation is aggravated by $NO_2$ and $O_3$ concentration on the day of the asthma attack.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.5
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• pp.515-528
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• 2003

The characteristics of one year observation aerosol data in Seoul, 200 I was studied using an OPC (Optical Particle Counter). The size resolved aerosol number concentrations of 0.3 ∼ 25 11m were measured. The results were compared with PM$_{10}$ mass concentration data under various meteorological conditions including dust and precipitation events. For fine particles whose diameter is less than 2.23 ${\mu}{\textrm}{m}$, the number concentration increases in the early morning which is considered due to transportation. while the coarse mode particles increase during daytime. This increase can be explained as local sources and human activities near sampling site. Hourly averaged data show that there exists diurnal variation. Generally, PM$_{10}$ data showed a similar tendency with OPC data. The size resolved OPC data showed that the particles of 0.5 ∼ 3.67 ${\mu}{\textrm}{m}$ are positively correlated with PM$_{10}$ data. The accumulated volume fraction of size resolved aerosol concentration in 0.5 ∼ 10 ${\mu}{\textrm}{m}$ showed that 0.5 ∼ 2.23 ${\mu}{\textrm}{m}$ particles occupied 59.2% of total aerosol volume of 0.5 ∼ 10 ${\mu}{\textrm}{m}$./TEX>.

• Journal of Korean Society for Atmospheric Environment
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• v.10 no.4
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• pp.252-259
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• 1994

A ground station has been established at Kosan, Cheju Island, since January of 1992 for the monitoring of background air Pollutant levels in Korea. Anthropogenic pollutant sources and meteorological conditions of Kosan were surveyed. Concentrations of SO$_2$, NO, NO$_{y}$ and $O_3$, were measured and analyzed for the period of February through December, 1992. The annual means of NO and SO$_2$, levels were very low in comparison to other urban's levels and similiar to other country's background levels. The annual mean of $O_3$, level was higher than urban's but comparable to other coastal region's. The NO concentration showed a distinct seasonal and diurnal variations. Summer peak was detected in the monthly means of NO and smooth peak around noon was found in the annual means of hourly data. Diurnal variation of the SO$_2$ concentration was barely detected but a slice increase in winter was detected. The $O_3$, concentration data, however, showed seasonal and diurnal variations similar to the urban's.an's.