• KIEAE Journal
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• 제4권4호
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• pp.11-18
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• 2004

In this study, the measurement system was developed for the measurement of pollutants from building materials, and specimens were made with concrete, gypsum board, mortar and wall paper. Characteristics of VOCs and TVOC concentration and Emission Factor as a function of time were assessed, and the conclusion was drawn as follows. (1) From predicting TVOC concentration decrease of specimen 7 with the wall paper attached to the concrete, the graph may become linear by converting the value of y-axis into the log function, and the prediction equation can be expressed as $y=34906{\ast}e^{-0.0093{\ast}time}$. Moreover, chi-square value was 0.83 which is relatively high value, indicating that TVOC concentration can be properly predicted if the same materials are used indoors. (2) From predicting VOCs Emission Factor decrease of specimen 7, the prediction equation can be expressed as $EF=15111{\ast}e^{-0.0093{\ast}time}$, and chi-square value was 0.83. (3) From predicting TVOC concentration decrease of specimen 7, prediction equation can be considered to be $y=254323{\ast}(1-e^{-0.1046{\ast}time})$, and chi-square was 0.994 which is significantly high value, indicating that indoor TVOC concentration can be properly predicted if the same materials are used indoors. Furthermore, the prediction of concentration decrease using cumulative value of hourly measured concentration is considered to be more accurate than that using just hourly measured value directly. (4) From predicting Emission Factor decrease with cumulative hourly data of Emission Factor, chi-square appeared to be higher than that by just using hourly data of Emission Factor directly. Therefore, the prediction of Emission Factor with cumulative hourly data can provide more reliable prediction equation than the case by using just hourly concentration directly.

• 한국환경과학회지
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• 제14권11호
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• pp.1035-1047
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• 2005

By using hourly $NO_2$ concentration data$(1998\~2000)$ at the Busan Metropolitan City air qualify monitoring sites, characteristics of daily mean value of $NO_2$ concentration was discussed in space and time. The correlation between $NO_2$ concentration and other relating air pollutants was analyzed by using SAS program and meteorological parameters as well. After choosing representative 4 areas, this study used hourly concentration data$(1998\~2000)$ from air quality monitoring sites on $NO_2,\;NO,\;O_3,\;CO,\;SO_2\;and\;PM_{10}$. Typical metropolitan characteristics of two peaks in a day was shown in the variation of $NO_2$ concentration of Busan city.

• 한국대기환경학회지
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• 제5권2호
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• pp.55-71
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• 1989

This study was carried out to determine the ozone concentration to behaviour and the factors to be influenced the variation of its concentration in the ambient air in Seoul. Measurements of ozone concentrations were made at 10 monitoring station to take care of SIHE (Seoul Institute of Health & Environment) during December 1987 to November 1988, also measured the hourly average concentration of sulfur dioxide, total suspended particulate, nitrogen oxide $(NO & NO_2)$, carbon monoxide, hydro carbon $(n-CH_4 & THC)$ and meteorological factors, that is, temperature, humidity, wind velocity wind direction and ultraviolet intensity etc, for the same period at same place. The basis of the data obtained were analyzed statistically along with the various data. The results were as follows; 1. The annually arithmetic mean concentration of ozone for the 10 sites during one years was 10.0 ppb and ranged from 3.1 $\pm$ 4.5ppb at the Kuro industrial complex to 17.2 $\pm$ 18.7 ppb at the Ssangmun site. 2. The frequency of hours on which oxidant concentrations exceeded the present short term standard of ozone (100 ppb) were 78 times. 3. The diurnal patterns of hourly ozone concentrations in Seoul area was a typical bi-modal variation which have 4 to 5 a.m. peak and 3. to 4 p.m peak. 4. The time ozone of highest ozone concentration in a whole day and hight was 1 to 5 p.m and 90.9 percent of appearence rate. 5. The diurnal patterns of hourly ozone concentrations in Seoul were on the whole the order of daytime from 5.8ppb to 28.7 ppb evening from 1.7 to 18.7 ppb night time from 1.9 to 9.3 ppb daybreak from 1.4ppb according to measuring sites, and the highest that observed at the Ssangmun area while the lowest was the Kuro industrial complex monitor sites. 6. The weekly variation of ozone concentration was the higher level ozone concentration in the day of the week occured sunday-monday and weekend but the decrease were observed from wednesday to thursday.

• 한국환경과학회지
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• 제6권5호
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• pp.461-472
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• 1997

This study was carried out to investigate the characteristics of chemical components and precipitation at Kimhae area from March, 1992 to June, 1994. The pH values, concentration of soluble ions($Cl^-$, $NO_2^-}$ $NO_3^-}$, $NO_4^{2-}$-, $PO_4^{3-}$. $F^-$, $Mg^{2+}$, $Ca^{2+}$, $Mn^{2+}$, $K^+) and non-soluble metals(Cr.Si. Zn, Pb, Cu, Fe, Mn, Mg, Ad. V. Cal were measured by pH meter, IC (ion Chromatography) and ICP(Inductively Coupled Plasma). The data were analyzed by the dally. hourly distribution characteristics of acidity and chemical components, as well as the correlation between them. The results are as follows. 1. The pH range of precipitation was from 3.45 to 6.80 in Kimhae area. and average value was pH 4.62 and main chemical components were $SO_4^{2-}$, $Cl^-$, $NO_3^-$. The highest pH value and concentration appeared in initial rain, which might result from urbanlzation and industrialization in this area and long term transportation from China. 2. The hourly correction distribution of main anions related to pH value In the rainwater showed $SO_4^{2-}$ > $NO_3^-$ > $Cl^-$. Hourly concentration of heavy metal and each ion was highly correlated with pH in the precipitation.

• 한국환경과학회지
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• 제12권10호
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• pp.1033-1041
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• 2003

Hourly data of PM10 concentration collected from nine automatic air quality monitoring stations in Busan from 1999 to 2002 were analyzed to evaluate the spatio-temporal variation and meteorological characteristics of PM10 episodes in Busan metropolitan area. Mean concentrations ranged from 47$\mu\textrm{g}$/㎥ to 77$\mu\textrm{g}$/㎥. For most stations, mean seasonal hourly concentrations are lowest in summer and highest in spring. PM10 episode above daily mean standard(150$\mu\textrm{g}$/㎥) exhibited a maximum frequency at Gamjeondong and a minimum at Dongsamdong, and a maximum in March and a minimum in July and August. The diurnal variation of PM10 episode days is strongly influenced by traffic loads and meteorological conditions.

• 한국대기환경학회지
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• 제17권3호
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• pp.277-288
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• 2001

Continuous atmospheric CO$_2$measurements measured during the 1 year(1998.8∼1999.8) at Korea Global Atmosphere Watch Observatory (KGAWO) in Anmyeon-do are analyzed by the selecting method which is recommended by WDCGG to get background CO$_2$. This method can reject data based on two criteria: the instability of CO$_2$ concentration within 1 hour from hourly standard deviation (hourly variability$\leq$ 0.6 ppm first selection) and the large changes in the CO$_2$ concentration from one hour to the nex(∼$\leq$0.3 ppm, second selection). We could obtain hourly background CO$_2$ of 37% in first selection and 20% in second selection during the l year. That are a little less than those of Ryori station in Japan. especially, the cases of background CO$_2$ which is selected were few during the summer. That is caused by affection of vegetation and anthropogenic source. After the selecting methods are applied, the cases which is selected for easterly wind decrease remarkably according to the analysis of wind direction about continuous CO$_2$ .That was affected by anthropogenic source from the east area.

• 한국수소및신에너지학회논문집
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• 제30권6호
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• pp.601-607
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• 2019

Ammonia would be formed in natural gas containing small amount of nitrogen reforming process in the process natural gas, which might damage the Pt catalyst and Prox catalyst. In the article, the effect of nitrogen contents on the formation of ammonia in the reforming process has been studied. In the experiments, Ru based and Ni based catalysts were used and the concentration of ammonia in the reformate gas at various gas hourly space velocity was measured. Experimental result shows that relatively higher ammonia concentration was measured with Ru based catalyst than with Ni based catalyst. It also shows that the concentration of ammonia increased rapidly after most of the methane converted into hydrogen. Based on the experimental results to reduce ammonia concentration it might be better to finish methane conversion at the exit position of the reforming reactor to minimize the contact time of catalyst and nitrogen with high concentration of hydrogen.

• 대기
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• 제25권2호
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• pp.221-233
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• 2015

Pollen is closely related to health issues such as allergenic rhinitis and asthma as well as intensifying atopic syndrome. Information on current and future spatio-temporal distribution of allergenic pollen is needed to address such issues. In this study, the Community Multiscale Air Quality Modeling (CMAQ) was utilized as a base modeling system to forecast pollen dispersal from oak trees. Pollen emission is one of the most important parts in the dispersal modeling system. Areal emission factor was determined from gridded areal fraction of oak trees, which was produced by the analysis of the tree type maps (1:5000) obtained from the Korea Forest Service. Daily total pollen production was estimated by a robust multiple regression model of weather conditions and pollen concentration. Hourly emission factor was determined from wind speed and friction velocity. Hourly pollen emission was then calculated by multiplying areal emission factor, daily total pollen production, and hourly emission factor. Forecast data from the KMA UM LDAPS (Korea Meteorological Administration Unified Model Local Data Assimilation and Prediction System) was utilized as input. For the verification of the model, daily observed pollen concentration from 12 sites in Korea during the pollen season of 2014. Although the model showed a tendency of over-estimation in terms of the seasonal and daily mean concentrations, overall concentration was similar to the observation. Comparison at the hourly output showed distinctive delay of the peak hours by the model at the 'Pocheon' site. It was speculated that the constant release of hourly number of pollen in the modeling framework caused the delay.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2004년도 추계학술대회 논문집
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• pp.365-366
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• 2004

• Bulletin of the Korean Chemical Society
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• 제35권10호
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• pp.2995-3000
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• 2014

A sensitive concentration method utilising modified gas-purge microsyringe extraction (GP-MSE) was developed. Concentration (reduction in volume) to a microlitre volume was achieved. PAHs were utilised as semivolatile analytes to optimise the various parameters that affect the concentration efficiency. The injection rate and temperature were the key factors that affected the concentration efficiency. An efficient concentration (75.0-96.1%) of PAHs was obtained under the optimised conditions. The method exhibited good reproducibility (RSD values that ranged from 1.5 to 9.0%). The GP-MSE concentration method enhances the volume reduction (concentration factor), leading to a low method detection limit ($0.5-15ngL^{-1}$). Furthermore, this method offers the advantage of small-volume sampling, enabling even the detection of diurnal hourly changes in the concentration of PAHs in ambient air. Utilising this method in combination with GC-MS, the diurnal hourly flux of PAHs from the gas phase of ambient air was measured. Indeed, the proposed technique is a simple, fast, low-cost and environmentally friendly.