• Title/Summary/Keyword: Homogeneous liquid

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Formation of a Carbon Interphase Layer on SiC Fibers Using Electrophoretic Deposition and Infiltration Methods

  • Fitriani, Pipit;Sharma, Amit Siddharth;Lee, Sungho;Yoon, Dang-Hyok
    • Journal of the Korean Ceramic Society
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    • v.52 no.4
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    • pp.284-289
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    • 2015
  • This study examined carbon layer coating on silicon carbide (SiC) fibers by utilizing solid-state and wet chemistry routes to confer toughness to the fiber-reinforced ceramic matrix composites, as an alternative to the conventional pyrolytic carbon (PyC) interphase layer. Electrophoretic deposition (EPD) of carbon black nanoparticles using both AC and DC current sources, and the vacuum infiltration of phenolic resin followed by pyrolysis were tested. Because of the use of a liquid phase, the vacuum infiltration resulted in more uniform and denser carbon coating than the EPD routes with solid carbon black particles. Thereafter, vacuum infiltration with controlled variation in phenolic resin concentration, as well as the iterations of infiltration steps, was improvised to produce a homogeneous carbon coating having a thickness of several hundred nanometers on the SiC fiber. Conclusively, it was demonstrated that the carbon coating on the SiC fiber could be achieved using a simpler method than the conventional chemical vapor deposition technique.

A Study on the Injection Characteristics of Direct Injection CNG Fuel (직접분사 CNG 연료의 분사특성에 관한 연구)

  • Lee, S.W.;Rogers, T.;Petersen, P.;Kim, I.G.;Kang, H.I.
    • Journal of Hydrogen and New Energy
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    • v.25 no.6
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    • pp.643-647
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    • 2014
  • Two types of fuel supply method ar used in CNG vehicles. One is premixed ignition and the other is gas-jet ignition. In premixed ignition, the fuel is introduced with intake air so that homogeneous air-fuel mixture may form. The ignitability of this method depends on the global equivalence ratio. In gas-jet ignition, CNG is introduced directly into the engine combustion chamber. The overall mixture is stratified by retarded fuel injection. In this study, a visualization technique was employed to obtain fundamental properties regarding overall mixture formation of direct injected CNG fuel inside a constant volume chamber. Jet angles, penetrations and projected jet area with respect to ambient pressure are investigated. The penetration decreases apparently and the time reaching the CVC wall was delayed as the chamber pressure increases. This is caused by the higher inertia of the fluid elements that the injected fluid must accelerate and push aside. It is same to liquid fuel such as diesel and gasoline, but this phenomenon is far more prominent for the gaseous fuel.

Comparison of Morphology of Deposits on SiC Filaments with LIF Image in Propane/Air Laminar Diffusion Flames in an Oxidizer Deficient Environment (산화제 결핍 상태의 프로판 층류 확산화염에서 LIF 이미지와 SiC 필라멘트 부착물의 형태 비교)

  • Shim, Sung-Hoon;Yoo, Chang-Jong;Shin, Hyun-Dong
    • Journal of the Korean Society of Combustion
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    • v.7 no.4
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    • pp.1-9
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    • 2002
  • The morphology of deposits on $15-{\mu}m$ thin SiC filaments has been investigated with SEM and compared with UV-excited laser induced broadband fluorescences in co-flowing, propane laminar diffusion flames in a reduced oxidizer environment. The homogeneous morphology of droplet-like deposits inner flame zone and the agglomeration of condensed-phase deposits and the transition to soots from grown up droplet-like precursors with approaching the flame surface can be observed in a barely sooting flame. The average size of the mature soots deposited in the luminous flame edge is scarcely dependent on their axial position in a confined flame under reduced oxidizer condition. A double structure of PAH fluorescence is observed in near-extinction flames with further decreasing of oxidizer. A comparison of the PAH fluorescence with the morphologies of deposits indicates that appearance of the "dark" hollow zone is caused by a decreased number density of developed liquid-phase large molecules and the outer weak fluorescence zone is caused by the diffusion of gas-phase small molecules.

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High-rate growth $YBa_2$$Cu_3$$O_{7-x}$ thick films and thickness dependence of critical current density (Y$Ba_2$$Cu_3$$O_{7-x}$ 후막의 고속 증착과 임계 전류 밀도의 두께 의존성)

  • Jo W.
    • Progress in Superconductivity
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    • v.6 no.1
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    • pp.13-18
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    • 2004
  • High-.ate in-situ$ YBa_2$Cu$Cu_3$$O_{7-x}$ (YBCO) film growth was demonstrated by means of the electron beam co-evaporation. Even though our oxygen pressure is low, ∼$5 ${\times}$10^{-5}$ Torr, we can synthesize as-grown superconducting YBCO films at a deposition rate of around 10 nm/s. Relatively high temperatures of around 90$0^{\circ}C$ was necessary in this process so far, and it suggests that this temperature at a given oxygen activity allows a Ba-Cu-O liquid formation along with an YBCO epitaxy. Local critical current density shows a clear correlation with local resistivity. Homogeneous transport properties with a large critical current density ($4 ∼ 5 MA/\textrm{cm}^2$ at 77K, 0T) are observed in top faulted region while it is found that the bottom part carries little supercurrent with a large local resistivity. Therefore, it is possible that thickness dependence of critical current density is closely related with a topological variation of good superconducting paths and/or grains in the film bodies. The information derived from it may be useful in the characterization and optimization of superconducting films for electrical power and other applications.

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Experimental Study on HCCI Combustion Characteristics of n-heptane and iso-octane Fuel/air Mixture by using a Rapid Compression Machine (급속압축장치를 이용한 노말헵탄.이소옥탄 혼합연료의 HCCI 연소특성에 대한 연구)

  • Lim, Ock-Taeck
    • Journal of ILASS-Korea
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    • v.16 no.4
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    • pp.167-175
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    • 2011
  • The HCCI engines have been known with high efficiency and low pollution and can be actualized as the new internal combustion engines. However, As for(??) the ignition and combustion depend strongly on the oxidation reaction of the fuel, so it is difficult to control auto-ignition timing and combustion duration. Purpose of this paper is creating the database for development of multi-dimensional simulation and investigating the influence of different molecular structure. In this research, the effect of n-heptane mole ratio in fuel (XnH) on the ignition delay from homogeneous charge compression ignition(HCCI) has been investigated experimentally. By varying the XnH, it was possible to ascertain whether or not XnH is the main resource of ignition delay. Additionally, the information on equivalence ratio for varying XnH was obtained. The tests were performed on a RCM (Rapid Compression Machine) fueled with n-heptane and iso-octane. The results showed that decreasing XnH (100, 30, 20, 10,0), the ignition delays of low temperature reaction (tL) and high temperature reaction (tH) is longer. And the temperature of reaction increases by about 30K. n-heptane partial equivalence ratio (fnH) affect on tL.and TL. When ${\phi}$nH was increased as a certain value, tL was decreased and TL was increased.

The Effects of SiO2 Addition and Cooling Rate Change by Sol-gel Processing in Semiconducting BaTiO3 Ceramics (반도성 $BaTiO_3$ 세라믹스의 Sol-gel법에 의한 $SiO_2$ 첨가 및 냉각속도 효과)

  • 권오성;정용선;윤영호;이병하
    • Journal of the Korean Ceramic Society
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    • v.33 no.12
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    • pp.1301-1310
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    • 1996
  • Generally it requires high sintering temperatures more than 135$0^{\circ}C$ to make semiconductive BaTiO3 ceramics. Also it is very difficult to achieve a homogeneous mixing in solid-state reaction method. Therefore the liquid phase distributed to non-uniform dilute the characteristics of PTCR. In order to improve the uniformity this study is used the sol-gel coating method. Using this method we studied the new manufacturing process that had a high reproducibility and mass production capability. Tetraethyl orthosilicate (TEOS) was used as a source of Si. The semiconductive BaTiO3 ceramics which was produced by sol-gel method for the SiO2 addition and sintered between 124$0^{\circ}C$ and 130$0^{\circ}C$ showed almost same resistivity at room temperature among 125$0^{\circ}C$ and 130$0^{\circ}C$. As the results We could be sintered the semiconducting BaTiO3 ceramics at lower temperature even at 125$0^{\circ}C$ maintaining the same specific resistivity ratio ($\rho$max/$\rho$min) at 130$0^{\circ}C$. The specific resistivity both below and above the Curie temperature were increased by slow cooling and the steepness of the plots in the reasion of transition from low to high resistance increased as the cooling rate decreased.

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Research Status on the Carbon Nanotube Reinforced Nanocomposite (탄소나노튜브 강화 나노복합재료의 연구현황)

  • 차승일;김경태;이경호;모찬빈;홍순형
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.25-28
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    • 2003
  • Carbon nanotubes(CNTs), since their first discovery, have been considered as new promising materials in various fields of applications including field emission displays, memory devices, electrodes, NEMS constituents, hydrogen storages and reinforcements in composites due to their extra-ordinary properties. The carbon nanotube reinforced nanocomposites have attracted attention owing to their outstanding mechanical and electrical properties and are expected to overcome the limit of conventional materials. Various application areas are possible for carbon nanotube reinforced nanocomposites through the functionalization of carbon nanotubes. Carbon nanotube reinforced polymer matrix nanocomposites have been fabricated by liquid phase process including surface functionalization and dispersion of CNTs within organic solvent. In case of carbon nanotube reinforced polymer matrix nanocomposites, the mechanical strength and electrical conducting can be improved by more than an order of magnitude. The carbon nanotube reinforced polymer matrix nanocomposites can be applied to high strength polymers, conductive polymers, optical limiters and EMI materials. In spite of successful development of carbon nanotube reinforced polymer matrix nanocomposites, the researches on carbon nanotube reinforced inorganic matrix nanocomposites show limitations due to a difficulty in homogeneous distribution of carbon nanotubes within inorganic matrix. Therefore, the enhancement of carbon nanotube reinforced inorganic nanocomposites is under investigation to maximize the excellent properties of carbon nanotubes. To overcome the current limitations, novel processes, including intensive milling process, sol-gel process, in-situ process and spark plasma sintering of nanocomposite powders are being investigated. In this presentation, current research status on carbon nanotube reinforced nanocomposites with various matrices are reviewed.

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Vibration mode decomposition response analysis of large floating roof tank isolation considering swing effect

  • Sun, Jiangang;Cui, Lifu;Li, Xiang;Wang, Zhen;Liu, Weibing;Lv, Yuan
    • Earthquakes and Structures
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    • v.15 no.4
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    • pp.411-417
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    • 2018
  • To solve the seismic response problem of a vertical floating roof tank with base isolation, the floating roof is assumed to experience homogeneous rigid circular plate vibration, where the wave height of the vibration is linearly distributed along the radius, starting from the theory of fluid velocity potential; the potential function of the liquid movement and the corresponding theoretical expression of the base shear, overturning the moment, are then established. According to the equivalent principle of the shear and moment, a simplified mechanical model of a base isolation tank with a swinging effect is established, along with a motion equation of a vertical storage tank isolation system that considers the swinging effect based on the energy principle. At the same time, taking a 150,000 m 3 large-scale storage tank as an example, a numerical analysis of the dampening effect was conducted using a vibration mode decomposition response spectrum method, and a comparative analysis with a simplified mechanical model with no swinging effect was applied.

Effect of High Temperature and Pressure Conditions on the Combustion Characteristics of n-butanol and n-heptane Fuel (고온, 고압의 분위기 변화가 n-butanol 및 n-heptane 연료의 연소 특성에 미치는 영향)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of ILASS-Korea
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    • v.21 no.1
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    • pp.29-36
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    • 2016
  • The effect of high ambient temperature and pressure conditions on the combustion performance of n-butanol, n-heptane and its mixing fuel (BH 20) were studied in this work. To reveal this, the closed homogeneous reactor model applied and 1000-1200 K of the initial temperature, 20-30 atm of initial pressure and 1.0 of equivalence ratio were set to numerical analysis. It was found that the results of combustion temperature was increased and the ignition delay was decreased when the ambient conditions were elevated since the combustion reactivity increased at the high ambient conditions. On the contrary, under the low combustion temperature condition, the combustion pressure was more influenced by the ambient temperature in the same ambient conditions. In addition, the total mass and the mass density of tested fuels were influenced by the ambient pressure and temperature. Also, soot generation of mixing fuel was decreased than n-heptane fuel due to the oxygen content of n-butanol fuel.

Enhancement of the Critical Current Density of $MgB_2$ Prepared using Mechanically Milled and Glycerin Treated Boron Powder (기계적 밀링 및 글리세린 처리된 보론 분말을 사용하여 제조된 $MgB_2$의 임계전류밀도 향상)

  • Jun, Byung-Hyuk;Kim, Yi-Jeong;Kim, Chan-Joong
    • Progress in Superconductivity
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    • v.10 no.1
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    • pp.40-44
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    • 2008
  • A combined process of a mechanical ball milling and liquid glycerin ($C_{3}H_{8}O_3$) treatment of boron (B) powder has been conducted to enhance the superconducting properties of $MgB_2$. The individual aims of the mechanical milling and the glycerin treatment were to reduce the grain size of the $MgB_2$ and to achieve homogeneous carbon (C) incorporation into the $MgB_2$, respectively. Four kinds of B powders of as-received, glycerin treated, 2 h milled, and 2 h milled + glycerin treated were prepared. $MgB_2$ bulks were fabricated by in situ process using the prepared B powders. The mechanical ball milling was effective for a grain refinement, and a lattice disorder was easily achieved by glycerin addition. It was found that the critical current density ($J_c$) values were enhanced in the samples with milled B or glycerin treated B only. In the $MgB_2$ bulk prepared with both milled and glycerin treated B, the $J_c$ was further increased due to a higher grain boundary density and a greater C substitution.

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