• 한국세라믹학회지
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• 제27권7호
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• pp.899-906
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• 1990

The cordierite powders were prepared from Mg(NO3)2.6H2O, Al(NO3)3.9H2O and colloidal silica by the coprecippitation method, and the sintering behavior of the powders were investigated. Two different methods were applied for producing the precursor powders. The one was to added the aqueous solution of Mg(NO3)2.6H2O and Al(NO3)3.9H2O to NH4OH to adjust pH at 10 where the colloidal silica of pH 10 was added. The other wa to add the aqueous solution of Mg(NO3)2.6H2O and Al(NO3)3.9H2O to the colloidal silica with NH4OH to control the final mixture to be at pH 10. It was confirmed that more homogeneous powders were obtained from the latter method. The firing linear shrinkage of the powder compacts fabricated from the calcined powder between 90$0^{\circ}C$ and 110$0^{\circ}C$ was found to be larger as the calcination temperature was low. But all of them stopped shrinking around 120$0^{\circ}C$. The powder compacts, fabricated using the calcined powders at 90$0^{\circ}C$ and 95$0^{\circ}C$ for 2hours and sintered at 142$0^{\circ}C$ for 2hours, showed relative density of 93-96%, 3-point bending strength of 81-83MPa, KIC of 1.9-2.4 MPam1/2 and thermal expansion coefficient of 0.213-0.732$\times$10-6$^{\circ}C$.

• 대한토목학회논문집
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• 제9권4호
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• pp.103-112
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• 1989

방사성 폐기물 처분장 주변의 지하수 유동 현상을 이해하기 위해 정상상태에서의 지하수 수치모델을 수립하였다. 지하수 수치모델은 절점과 부재로 구성된 network에 의해 균질, 비균질, 다층매질에서 지하수 흐름을 조사하는데 이용되었고 모델의 수치해는 해석해와 일치하는 결과를 가졌다. 또한 지하매질의 수리학적 특성과 균열지역의 영향에 의한 지하수 유동의 물리적 변화현상도 조사되었다. 처분장 주변의 지하매질에 대해 구성된 network과 계산된 지하수 속도의 방향을 이용하여 지하수의 가능한 이동경로를 산정하는 방법이 개발되어 방사성 폐기물 처분장에서 생태계로의 가능한 지하수의 이동속도 및 시간을 예측하였다.

• Bulletin of the Korean Chemical Society
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• 제35권7호
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• pp.2049-2056
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• 2014

A simple method for exfoliating pristine graphite to yield mono-, bi-, and multi-layers of graphene sheets as a highly concentrated (5.25 mg/mL) and yielded solution in an organic solvent was developed. Pre-thermal treatment of pristine graphite at $900^{\circ}C$ in a sealed stainless steel bath under high pressures, followed by sonication in 1-methyl-2-pyrrolidinone solvent at elevated temperatures, produced a homogeneous, well-dispersed, and non-oxidized graphene solution with a low defect density. The electrical conductivities of the graphene sheets were very high, up to 848 S/cm. These graphene sheets were used to fabricate graphene-polyimide nanocomposites, which displayed a higher electrical conductivity (1.37 S/m) with an improved tensile strength (95 MPa). The synthesized graphene sheets and nanocomposites were characterized by transmission electron microscopy, scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy, and Raman spectroscopy.

• 한국해양공학회지
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• 제19권6호통권67호
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• pp.58-63
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• 2005

The estimation of springing responses for recent ships is carried out, and application to a ship design is described. To this aim, springing effects on hull girder were re-evaluated, including non-linear wave excitations and torsional vibrations of the hull. The Timoshenko beam model was used to calculate stress distribution on the hull girder, using the superposition method. The quadratic strip method was employed to calculate the hydrodynamic forces and moments on the hull. In order to remove the irregular frequencies, we adopted 'rigid lid' on the hull free surface level, and addedasymptotic interpolation along the high frequency range. Several applications were carried out on the following existing ships: The Bishop and Price's container ship, S-175 container ship, large container, VLCC, and ore carrier. One of them is compared with the ship measurement result, while another with that of the model test. The comparison between the analytical solution and the numerical solution for a homogeneous beam-type artificial ship shows good agreement. It is found that Most springing energy comesfrom high frequency waves for the ships having low natural frequency and North Atlantic route etc. Therefore, the high frequency tail of the wave spectrum should be increased by $\omega$$\^{-3}$ instead of $\omega$$\^{-4}$ or $\omega$$\^{-5}$ for the springing calculation.

• 대한전자공학회논문지SD
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• 제42권6호
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• pp.49-58
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• 2005

본 논문에서는 멀티프로세서 설계를 위한 동질적인 동기 데이터에 의해서 표현되는 LDFG(Linear Data-Flow Graph)의 최적화 ILP (Integer Linear Program)알고리즘을 제안하였다. 이 논문에서 제안된 연산들은 데이터의 종속적 의미를 담고 있지 않으며, 그러한 알고리즘을 위한 스케줄링은 시간 컴파일에 의해서 결정되어지며 충분한 정적 중첩 스케줄링이 고려된다. 제안된 중첩 스케줄링에서는 모두 선형의 동일한 스케줄링과 동일한 처리장치 할당한 것을 의미한다. 본 논문에서는 자원의 제약 하에서 스케줄링을 하였으며, 멀티프로세서 설계를 위한 LDFG의 최적화를 위하여 문제를 ILP 공식화하여 해법을 제공하였다. 벤치 마크 실험 결과들은 제안된 스케줄링 방법의 효율성을 검증하였다.

• 한국재료학회지
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• 제12권12호
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• pp.947-954
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• 2002

HCl concentration and reaction time are the decisive factors in determining the structure of precipitates in the process of synthesis of $TiO_2$ particles from aqueous $TiOCl_2$ solution by precipitation and the volumetric proportion of brookite phase in $TiO_2$ particles can be controlled by these two factors. As reaction rate increases with increase of reaction temperature, the reaction time, at which maximum volumetric proportion of brookite phase in $TiO_2$ particles was obtained, was reduced. The brookite was transformed directly to rutile phase with only increase of reaction time. And precipitation was delayed with increase of HCl concentration because the amount of $H_2$O, which is necessary source of oxygen for conversion of $Ti^{+4}$ to $TiO_2$, was relatively reduced with increase of that. Brookite in the mixture phase powder was finally transformed to rutile phase via anatase through heat-treatment.

• Advances in materials Research
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• 제8권3호
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• pp.155-177
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• 2019

In this paper, a new displacement based high-order shear deformation theory is introduced for the static response of functionally graded sandwich plate with new definition of porosity distribution taking into account composition and the scheme of the sandwich plate. Unlike any other theory, the number of unknown functions involved is only four, as against five in case of other shear deformation theories. The theory presented is variationally consistent, has strong similarity with classical plate theory in many aspects, does not require shear correction factor, and gives rise to transverse shear stress variation such that the transverse shear stresses vary parabolically across the thickness satisfying shear stress free surface conditions. Material properties of FGM layers are assumed to vary continuously across the plate thickness according to either power-law or sigmoid function in terms of the volume fractions of the constituents. The face layers are considered to be FG across each face thickness while the core is made of a ceramic homogeneous layer. Governing equations are derived from the principle of virtual displacements. The closed-form solution of a simply supported rectangular plate subjected to sinusoidal loading has been obtained by using the Navier method. Numerical results are presented to show the effect of the material distribution, the sandwich plate geometry and the porosity on the deflections and stresses of FG sandwich plates. The validity of the present theory is investigated by comparing some of the present results with other published results.

• 한국세라믹학회지
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• 제43권9호
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• pp.564-568
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• 2006

AlO(OH) nano gel is used in precursor of ceramic material, coating material and catalyst. For use of these, not only physiochemical control for particle morphology, pore characteristic and peptization but also studies of synthetic method for preparation of advanced application products were required. In this study, AlO(OH) nano gel was prepared through the aging and drying process of aluminum hydroxides gel precipitated by the hydrolysis reaction of dilute NaOH solution and aluminum sulfate solution. In this process, optimum synthetic condition of AlO(OH) nano gel having excellent pore volume as studying the effect of water and aluminum sulfate mole ratio on gel precipitates has been studied. Water and aluminum sulfate mole ratio brought about numerous changes on crystal morphology, surface area, pore volume and pore size. Physiochemical properties were investigated as using XRD, TEM, TG/DTA, FT-IR, and $N_2$ BET method.

• 한국전기전자재료학회논문지
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• 제19권5호
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• pp.457-460
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• 2006

Y doped zinc oxide (YZO) thin films were deposited on F doped $SnO_2$ (FTO) glass substrate by sol-gel method using the spin-coating system. A homogeneous and stable solution was prepared by dissolving acetate in the solution added diethanolamine as sol-gel stabilizer. YZO films were obtained after preheated on the hot-plate for 5minute before each coating; the number of coating was 3 times. After the coating of last step, annealing of YZO films performed at $450^{\circ}C$ for 30 minute. In order to confirming of a ultraviolet ray interruption and down-conversion effects, optical properties of YZO films, transmission spectrum and fluorescent spectrum were used. Also, for understanding the obtained results by experiment, the elestronic state of YZO was calculated using the density functional theory The results obtained by experiment were compared with calculated structure. The detail of electronic structure was obtained by the discrete variational Xa (DV-Xa) method, which is a sort of molecular orbital full potential method. The density of state and energy levels of dopant element were shown and discussed in association with optical properties.

• Bulletin of the Korean Chemical Society
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• 제20권1호
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• pp.35-41
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• 1999

Stability characteristics of hyperbolic reaction-diffusion equations with a reversible Brusselator model are investigated as an extension of the previous work. Intensive stability analysis is performed for three important parameters, Nrd, β and Dx, where Nrd is the reaction-diffusion number which is a measure of hyperbolicity, β is a measure of reversibility of autocatalytic reaction and Dx is a diffusion coefficient of intermediate X. Especially, the dependence on Nrd of stability exhibits some interesting features, such as hyperbolicity in the small Nrd region and parabolicity in the large Nrd region. The hyperbolic reaction-diffusion equations are solved numerically by a spectral method which is modified and adjusted to hyperbolic partial differential equations. The numerical method gives good accuracy and efficiency even in a stiff region in the case of small Nrd, and it can be extended to a two-dimensional system. Four types of solution, spatially homogeneous, spatially oscillatory, spatio-temporally oscillatory and chaotic can be obtained. Entropy productions for reaction are also calculated to get some crucial information related to the bifurcation of the system. At the bifurcation point, entropy production changes discontinuously and it shows that different structures of the system have different modes in the dissipative process required to maintain the structure of the system. But it appears that magnitude of entropy production in each structure give no important information related for states of system itself.