• Analytical Science and Technology
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• v.26 no.1
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• pp.42-50
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• 2013

This paper describes the electrocatalytic activity for the oxidation of small biomolecules on the surface of Pt-Ru nanoparticles supported by $TiO_2$-hollow sphere prepared for use in sensor applications or fuel cells. The $TiO_2$-hollow sphere supports were first prepared by sol-gel reaction of titanium tetraisopropoxide with poly(styrene-co-vinylphenylboronic acid), PSB used as a template. Pt-Ru nanoparticles were then deposited by chemical reduction of the $Pt^{4+}$ and $Ru^{3+}$ ions onto $TiO_2$-hollow sphere ($Pt-Ru@TiO_2-H$). The prepared $Pt-Ru@TiO_2-H$ nanocomposites were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and elemental analysis. The electrocatalytic efficiency of Pt-Ru nanoparticles was evaluated via ethanol, methanol, dopamine, ascorbic acid, formalin, and glucose oxidation. The cyclic voltammograms (CV) obtained during the oxidation studies revealed that the $Pt-Ru@TiO_2-H$ nanocomposites showed high electrocatalytic activity for the oxidation of biomolecules. As a result, the prepared Pt-Ru catalysts doped onto $TiO_2$-H sphere nanocomposites supports can be used for non-enzymatic biosensor or fuel cell anode electrode.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07a
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• pp.321-323
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• 2005

We report a microcapsule-based electronic ink display technique, containing hollow titania particles which were prepared via a complex coacervation method using gelatin and gum arabic. In order to reduce density mismatch between nanoparticels and dielectric medium, hollow titania particles were introduced. Microcapsules were then prepared using gelatin to improve the elasticity of the microcapsule wall and their electrophoretic characteristics were $investigated^1$

• Applied Chemistry for Engineering
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• v.32 no.6
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• pp.690-694
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• 2021

Carbon spheres (CS) were fabricated using glucose as a precursor in the hydrothermal method. Hollow TiO₂ (H-TiO₂) spheres with 200 nm, 500 nm, and 1,200 nm were synthesized by CS/TiO₂ core-shell particles via a sol-gel and calcination method. H-TiO₂ spheres with nano and micron sizes were characterized using FE-SEM, HR-TEM, and X-ray diffraction. The CIE color coordinate, solar reflectance, and heat shield temperatures of H-TiO₂/polyacrylate (PA) composite film were investigated using a UV-Vis-NIR spectrometer and homemade heat insulation temperature measuring device. H-TiO₂/PA composites exhibit excellent thermal insulation since the hollow structure filled with dry air has low thermal conductivity and near infrared light reflecting performance. The thermal insulation increased with increasing the hollow sphere (HS) size on H-TiO₂/PA composites. The PA composite film mixed with H-TiO₂ filled with 1200 nm HS reduced the heat shield temperature by 26 ℃ compared to that of the transparent glass counterpart.

• Journal of the Korea Concrete Institute
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• v.24 no.4
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• pp.391-398
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• 2012

This paper presents the shear capacities of biaxial hollow slab with donut type hollow sphere. Recently, various types of slab systems which can reduce self-weight of slabs have been studied for increasing constructions of taller and larger building structures. A biaxial hollow slab system is widely known as one of the effective slab system, which can reduce self-weight of slab. According to previous studies, the hollow slab has low shear strength, compared to solid slab. Also, the shear capacities of biaxial hollow slab are influenced by the shapes and materials of hollow spheres. However, the current code does not provide a clear computation method for the shear strength of hollow slab. To verify the shear capacities of this hollow slab, one-way shear tests were performed. Four test specimens were used for test parameters. One was conventional RC slab and others were hollow slabs. The test parameters included two different shapes and materials of plastic balls. The shape parameters were donut and non-donut forms and the material parameters were general plastic and glass fiber plastic. The results showed that the shear strengths varied depending on hollow shapes and materials used in the slab.

• Journal of the Korean Electrochemical Society
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• v.14 no.3
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• pp.184-190
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• 2011

$LiMn_2O_4$ with mesoporous hollow sphere shape was synthesized by precipitation method with silica template. The synthesized $LiMn_2O_4$ has nanosized first particle and mesoporous hollow sphere shape. Silica template was removed by chemical etching method using NaOH solution. When the concentration of NaOH solution was increased, first particle size of manganese oxide was decrease and confirmed mesoporous hollow shpere shape. X-ray diffraction(XRD) patterns revealed that the synthesized samples has spinel structure with Fd3m space group. In case the ratio of silica and maganese salt increased, the size of first particles was decreased. The tetragoanal $LiMn_2O_4$ with micron size was synthesized at ratio of silica and manganese salt over 1 : 9. The prepared samples were assembled as cathode materials of Li-ion battery with 2032 type coin cell and their electrochemical properties are examined by charge-discharge and cyclic performance. Electrochemical measurements show that the nano-size particles had lower capacity than micron-size particles. But, cyclic performance of nano-size particles had better than that of micron-size particles.

• Journal of the Korea Concrete Institute
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• v.25 no.2
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• pp.155-163
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• 2013

This study investigated the bond characteristics of embedded deformed steel bar in donut type biaxial hollow slabs. The donut type hollow sphere make concrete inner cover formed between steel bar and hollow sphere due to the hollow shape and arrangement. Generally, inner cover was thinner than outer cover, and some part of donut type biaxial hollow slab has smaller inner cover thickness than $2.5d_b$. It was affected to the bond condition of deformed bar. Furthermore, inner cover thickness changes along the longitudinal deformed bar due to hollow shape. Therefore, donut type hollow slab was divided 3 regions according to the hollow shape such as insufficient region, transition region, sufficient region. Pull-out test were performed to find out the effect of bond condition by the region. Main parameters are inner cover thickness, embedded length and bond location. Bond characteristics of donut type biaxial hollow slab were confirmed through comparison of bond stress-slip relationship, maximum bond strength and bond stress distribution of each regions. And the calculation method of bond strength of donut type biaxial hollow slab was suggested based on the test results.

• Macromolecular Research
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• v.11 no.6
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• pp.518-522
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• 2003

We fabricated polymeric hollow spheres having macropores, which combine the advantageous properties of porous materials and hollow spheres. To fabricate such spheres, a polystyrene/methylmethacrylate solution was dispersed in water by vigorously stirring and then the suspension was quenched using liquid nitrogen. Water and methyl methacrylate present in the quenched suspension were readily sublimated by freeze-drying. Conclusively, the hollow-sphere structure and the macropores of its shell were created by the processes of liquid nitrogen-quenching and sublimation of methyl methacrylate domains within the shell, respectively.

• Journal of Powder Materials
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• v.27 no.2
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• pp.132-138
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• 2020

A facile one-pot wet chemical process to prepare pure anatase TiO₂ hollow structures using ammonium hexafluorotitanate as a precursor is developed. By defining the formic acid ratio, we fabricate TiO₂ hollow structures containing fluorine on the surface. The TiO₂ hollow sphere is composed of an anatase phase containing fluorine by various analytical techniques. A possible formation mechanism for the obtained hollow samples by self-transformation and Ostwald ripening is proposed. The TiO₂ hollow structures containing fluorine exhibits 1.2 - 2.7 times higher performance than their counterparts in photocatalytic activity. The enhanced photocatalytic activity of the TiO₂ hollow structures is attributed to the combined effects of high crystallinity, specific surface area (62 ㎡g^-1), and the advantage of surface fluorine ions (at 8%) having strong electron-withdrawing ability of the surface ≡ Ti-F groups reduces the recombination of photogenerated electrons and holes.

• Proceedings of the Korean Ceranic Society Conference
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• 2003.10a
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• pp.122.1-122
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• 2003

• Journal of the Korea Institute of Building Construction
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• v.15 no.2
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• pp.177-183
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• 2015

In this study, the thermal conductivity, physical and mechanical properties of lightweight aggregate concretes with hollow micro sphere(HMS) are experimentally examined as a basic research for the development of structural insulation concrete. As the results of this experiment, in the case of concrete mixed with HMS, the value of slump has been reduced, so it is found that the dosage of superplasticizer should be increased. As the replacement ratio of HMS increases, it has shown that the compressive strength is somewhat decreased due to the low interfacial adhesion strength of HMS. But the thermal conductivity is found to be greatly improved with the replacement ratio of HMS increases, the thermal conductivity of HMS shows the lower value of 68% at lightweight aggregate concrete and 32% of normal concrete. Also it is found that the compressive strength is decreased and thermal conductivity is increased as the water-cement ratio increases. The most outstanding for insulation performance is observed when using 20% of HMS and 50% of water-cement ratio.