• Title/Summary/Keyword: Hollow carbon

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Synthesis of Core-Shell Silica Nanoparticles with Hierarchically Bimodal Pore Structures

  • Yun, Seok-Bon;Park, Dae-Geun;Yun, Wan-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.467-467
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    • 2011
  • Reflecting the growing importance of nanomaterials in science and technology, controlling the porosity combined with well-defined structural properties has been an ever-demanding pursuit in the related fields of frontier researches. A number of reports have focused on the synthesis of various nanoporous materials so far and, recently, the nanomaterials with multimodal porosity are getting an emerging importance due to their improved material properties compared with the mono porous materials. However, most of those materials are obtained in bulk phases while the spherical nanoparticles are one of the most practical platforms in a great number of applications. Here, we report on the synthesis of the core-shell silica nanoparticles with double mesoporous shells (DMSs). The DMS nsnoparticles are spherical and monodispersive and have two different mesoporous shells, i.e., the bimodal porosity. It is the first example of the core-shell silica nanoparticles with the different mesopores coexisting in the individual nanoparticles. Furthermore, the carbon and silica hollow capsules were also fabricated via a serial replication process.

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A Study on the Collapse Characteristics of Al/CFRP Square Structural Member for Light Weight (경량화용 Al/CFRP 사각 구조부재의 압궤 특성에 관한 연구)

  • Hwang, Woo-Chae;Sim, Jae-Ki;Yang, In-Young
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.3
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    • pp.219-224
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    • 2011
  • Aluminum or CFRP is representative one of the lightweight materials. Collapse behavior of Al/CFRP square structural member was evaluated in this study based on the respective collapse behavior of aluminum and CFRP member. Al/CFRP square structural members were manufactured by wrapping CFRP prepreg sheets outside the aluminum hollow members in the autoclave. Because the CFRP is an anisotropic material with mechanical properties, The Al/CFRP square structural members stacked at different angles(${\pm}15^{\circ}$, ${\pm}45^{\circ}$, ${\pm}90^{\circ}$, $90^{\circ}/0^{\circ}$ and $0^{\circ}/90^{\circ}$ where the direction on $0^{\circ}$ coincides with the axis of the member) and interface numbers(2, 3, 4, 6 and 7). The axial impact collapse tests were carried out for each section members. Collapse mode and energy absorption characteristics of the each member were analyzed.

Mechanical Characteristics of Hybrid Fiber Reinforced Composite Rebar (하이브리드 섬유강화 복합재료 리바의 기계적 특성)

  • HAW GIL-YOUNG;AHN DONG-GUE;LEE DONG-GI
    • Journal of Ocean Engineering and Technology
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    • v.19 no.1 s.62
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    • pp.57-63
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    • 2005
  • The objective of this research is to investigate the mechanical characteristics of the hybrid fiber reinforced composite rebar, which is manufactured from a braidtrusion process. Braidtrusion is a direct composite fabrication technique, utilizing in-line brading and the pultrusion process. hz order to obtain the mechanical behavior of the glass fiber, carbon fiber, and kevlar fiber, the tensile tests are carried out. The results of the fibers are compared with that of steel. Hybrid rebar specimens with various diameters, ranging from model size (3 mm) to full-scale size (9.5 mm), and various cross sections, such as solid and hollow shape, have been manufactured from the braidtrusion process. The tensile and bending tests for the case of the hybrid rebar, the conventional GFRP rebar, and the steel bar have been carried out. The results of the experiments show that the hybrid rebar is superior to the conventional GFRP rebar and the steel bar, from the viewpoint of tensile and bending characteristics.

CFRP strengthening of steel beam curved in plan

  • Keykha, Amir Hamzeh
    • Steel and Composite Structures
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    • v.41 no.5
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    • pp.637-648
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    • 2021
  • Nowadays, one of the practical, fast and easy ways to strengthen steel elements is the use of Carbon Fiber Reinforced Polymer (CFRP). Most previous research in the CFRP strengthening of steel members has carried out on straight steel members. The main difference between horizontal curved beams and straight beams under vertical load is the presence of torsional moment in the horizontal curved beams. In the other words, the horizontal curved beams are analyzed and designed for simultaneous internal forces included bending moment, torsional moment, and shear force. The horizontal curved steel beams are usually used in buildings, bridges, trusses, and others. This study explored the effect of the CFRP strengthening on the behavior of the horizontal curved square hollow section (SHS) steel beams. Four specimens were analyzed, one non-strengthened curved steel beam as a control column and three horizontal curved steel beams strengthened using CFRP sheets (under concentrated load and uniform distributed load). To analyze the horizontal curved steel beams, three dimensional (3D) modeling and nonlinear static analysis methods using ANSYS software were applied. The results indicated that application of CFRP sheets in some specific locations of the horizontal curved steel beams could increase the ultimate capacity of these beams, significantly. Also, the results indicated when the horizontal curved steel beams were under distributed load, the increase rate in the ultimate capacity was more than in the case when these beams were under concentrated load.

Preliminary Study of a New Extracorporeal Membrane Oxygenator Development When Using Pulsatile Flow

  • Lee, Sa-Ram;Lee, Kyung-Soo;Jung, Jae-Hoon;Mun, Cho-Hay;Min, Byoug-Goo
    • Journal of Biomedical Engineering Research
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    • v.28 no.3
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    • pp.387-391
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    • 2007
  • An oxygenator is a very important artificial organ and widely used for patients with lung failure or during open heart surgery. Although an oxygenator has been widely studied worldwide to enhance its efficiency, studies on oxygenators, in particular when using a pulsatile blood flow, are domestically limited. Therefore, a new oxygenator was developed in the lab and animal experimental results are described in the paper. The oxygenator is composed of polycarbonate housing and polypropylene hollow fibers. It has a total length of 400 mm and a surface area of $1.7 m^2$. The animal experiment lasted for 4 hours. The blood flow rate was set to 2 L/min and a pulsatile blood pump, T-PLS (Twin-Pulse Life Support), was used. Samples were drawn at the oxygenator's inlet and outlet. The total hemoglobin (Hb), saturation oxygen ($sO_2$), and partial oxygen pressure ($pO_2$), partial $CO_2$ pressure ($pCO_2$), and plasma bicarbonate ion concentration ($HCO_3^-$) were measured. The oxygen and carbon dioxide transfer rates were also calculated based on the experimental data in order to estimate the oxygenator's gas transfer efficiency. The oxygen and carbon dioxide transfer rates were $16.4{\pm}1.58$ and $165.7{\pm}10.96 mL/min$, respectively. The results showed a higher carbon dioxide transfer rate was achieved with the oxygenator. Also, the mean inlet and outlet blood pressures were 162.79 and 137.92 mmHg, respectively. The oxygenator has a low pressure drop between its inlet and outlet. The aim of own preliminary study was to make a new oxygenator and review its performance when applying a pulsatile blood pump thus, confirming the possibility of a new oxygenator suitable for pulsatile flow.

Life Cycle Assessment of the Carbon Emissions of MLE process and Denitrification Process Using Granular Sulfur (MLE공법과 황이용 탈질 프로세스의 전과정 탄소 배출량 평가)

  • Moon, Jin-young;Hwang, Yong-woo
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.5
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    • pp.619-627
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    • 2012
  • In order to determine reduction of greenhouse gas emissions (GHGs) when the submerged membrane bioreactor with granular sulfur (MBR-GS) is used in wastewater treatment plant (WTP), the amount of GHGs was compared and analyzed in the advanced treatment process of P wastewater treatment plant (WTP). The amount of GHGs was estimated by classifying as construction and operation phase in WTP. The amount of GHGs in construction phase was evaluated from multiplying raw materials by using carbon emission factors. Also the amount of GHGs in operating phase was calculated by using total electricity consumption and carbon emission factor. The construction of anoxic tank and secondary settling tank is unnecessary, because the MBR-GS conducts simultaneously the nitrification and denitrification in aeration tank and filtration by hollow fiber membrane. The amount of $CO_2$, $CH_4$, and $N_2O$ emitted by constructing the MBR-GS was 6.44E+06 kg, 8.16E+03 kg and 1.38E+01 kg, respectively. The result shows that the GHGs was reduced about 47 % as compared with the construction in the MLE process. In operating the MBR-GS, the electricity is not required in the biological reactor and secondary setting tank. Thus, the amount of $CO_2$, $CH_4$, and $N_2O$ emitted by operating in the MBR-GS was 7.39E+05 kg/yr, 5.80E+02 kg/yr and 2.44E+00 kg/yr, respectively. The result shows that the GHGs were reduced about 37 % as compared with the operation in the MLE process. Also, $LCCO_2$(Life Cycle $CO_2$) was compared and analyzed between MLE process and MBR-GS. The amount of $LCCO_2 $emitted from the MLE process and MBR-GS was 3.56E+04 ton $CO_2$ and 2.12E+04 ton $CO_2$, respectively. The result shows that the GHGs in MBR-GS were reduced to about 40 % as compared in the MLE process during life cycle. As a result, sulfur-utilizing autotrophic denitrification process (SADP) is expected to be utilized as the cost-effective advanced treatment process, owing to not only high nitrogen removal efficiency but also the GHGs reduction in construction and operation stage.

A Study on Fouling Characteristics and Applicability of Fouling Reducer in Submerged MBR Process (침지형 MBR공정에서 파울링 특성과 파울링 완화제의 적용성에 관한 연구)

  • Park, Jun Won;Park, Hong June;Kim, Min Ho;Oh, Yong Keol;Park, Chul Hwi
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.5
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    • pp.371-380
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    • 2013
  • Though MBR process has many advantages, the greatest risk factors in operating MBR process are occurrence of membrane fouling and decrease of flux. It is very difficult to find exact mechanism due to complex influence by many effects, although there have been recently many studies of membrane fouling. The purposes of this study are firstly evaluating bioreactor of lab-scale and micro-filtration hollow fiber membrane, secondly investigating correlation between foulants affecting membrane performance and membrane fouling, and lastly evaluating various parameters affecting fouling and applicability of membrane fouling reducer. This study found that TMP was increasing rapidly and showed 0.32 bar and the average of flux was 88 LMH. EPS concentration tends not to change much above MLSS concentration (6,000 mg/L). However, EPS concentration variation is wide below MLSS concentration (6,000 mg/L). Also, from results of membrane surface condition and element analysis using SEM/EDX, carbon and fluorine were founded to be the highest percentage in membrane because of characteristics of membrane material. In operating continuously, inorganic fouling was generated by increase of these inorganic substances such as $Al^{3+}$ and $Mg^{2+}$. Lastly, the best filtration performance was obtained for 0.03 mg MFR/mg MLSS by results of particle size, zeta potential, $SCOD_{cr}$, EPS and MLSS concentration.

$H_{2}S$ Removal and $CO_{2}/CH_{4}$ Separation of Ternary Mixtures Using Polyimide Hollow Fiber Membrane (폴리이미드 중공사막을 이용한 혼합기체로부터 $H_{2}S$ 제거 및 $CO_{2}/CH_{4}$ 분리에 관한 연구)

  • Park, Bo-Ryoung;Kim, Dae-Hoon;Jo, Hang-Dae;Seo, Yong-Seog;Hwang, Taek-Sung;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.49 no.2
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    • pp.250-255
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    • 2011
  • In this study, by using the polymeric membrane separation process, the $CO_{2}/CH_{4}$ separation and $H_{2}S$ removal from biogas were performed in order to $CH_{4}$ purification and enrichment for the fuel cell energy source application. Fibers were spun by dry/wet phase inversion method. The module was manufactured by fabricating fibers after surface coating with silicone elastomer. The scanning electron microscopy(SEM) studies showed that the produced fibers typically had an asymmetric structure; a dense top layer supported by a porous, sponge substructure. The permeance of $CO_{2}$ and $CO_{2}/CH_{4}$ selectivity increased with pressure and temperature. Mixture gas with increasing pressure and temperature, removal efficiency of the $CO_{2}$ and $H_{2}S$ were decreased while concentration of $CH_{4}$ was increased up to 100%. When retentate flow rate was increased with the decreasing of pressure and temperature the $CH_{4}$ recovery ratio in retentate side was increased while the $CH_{4}$ purity in retentate side was decreased.

Studies on the Combustion of Anthracite (I). Combustion of Carbon Monoxide and the Furface (無燃炭 燃燒에 關한 硏究 (第 1 報). 一酸化炭素 燃燒反應 및 燃燒裝置)

  • Shin Byoung Sik;Shin Sei Kun
    • Journal of the Korean Chemical Society
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    • v.19 no.3
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    • pp.186-192
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    • 1975
  • In the course of anthracite briquet combustion, air draft is usually controlled to continue burning of definite amount of briquet in the conventional hollow clay cylinder with air inlet hole open for given time, so that a large amount of CO tends to be produced. Therefore, it is necessary to establish an improved combustion process to depress the yielding rate of CO and for this purpose, we performed a basic experiment in which combustion rate of CO was measured in the mixture of $N_2, O_2 $and CO gas with or without the presence charcoal at the various temperature. The observed results showed that the burning temperature of CO is about 680${\sim}700^{\circ}C$, further burning rate of it was increased with increasing the amount of draft. From these facts, longer combustion time and low CO generation are thus contradictory to each other and it has been long desired to make those two compatible somehow. The purpose of the present investigation lies in designing an effective new briquet stove to meet the above requirements. The essential feature of the new briquet stove consisted in the use of two hollow iron cylinders with different inside diameter. A cylindrical air jacket thus formed served as a path through which small amount of secondary air run from the bottom of the stove to the upper vent holes. Heat exchange occurred between the upgoing secondary air and the burning briquet, which lowered the combustion temperature of the briquet. The results observed were selfevident as anticipated. It was confirmed that the combustion time was increased tolerably due to the heat loss from the combustion zone and that CO in the flue gas was reoxidized at the upper portion of the stove by the upgoing hot secondary air. By this reoxidation reaction the concentration of CO in the flue gas was found to be about 1/20 of that in case the conventional clay cylinder was used as briquet jacket.

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Suitability of Counter-current Model for Biogas Separation Processes using Cellulose Acetate Hollow Fiber Membrane (셀룰로오스 아세테이트 중공사 분리막을 이용한 바이오가스 분리에 대한 향류 흐름 모델의 적용성)

  • Jung, Sang-Chul;Kwon, Ki-Wook;Jeon, Mi-Jin;Jeon, Yong-Woo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.28 no.4
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    • pp.43-52
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    • 2020
  • As the membrane gas separation technology grows, various models were developed by numerous researchers to describe the separation process. In this work, the counter-current model was compared thoroughly with experimental data. Experimentally, hollow fiber membrane using CA module was prepared for the separation of biogas. The pure gas permeation properties of membrane module for methane, nitrogen, oxygen, and carbon dioxide were measured. The permeance of CO2 and CH4 were 25.82 GPU and 0.65 GPU, respectively. The high CO2/CH4 selectivity of 39.7 was obtained. the separation test for three different simulated mixed gases were carried out after pure gas test, and the gas concentration of the permeate at various stage-cut were measured from CA membrane module. Results showed that the experimental data agreed with the numerical simulation. A mathematical model has implemented in this study for the separation of biogas using a membrane module. The finite difference method (FDM) is applied to calculate the membrane biogas separation behaviors. Futhermore, the counter-current model can be considered as a convenient model for biogas separation process.