• 제목/요약/키워드: Hole concentration

검색결과 382건 처리시간 0.033초

전착법에 의한 p-형 SbxTey 박막 형성 및 열전특성 평가 (Electrodeposition and Characterization of p-type SbxTey Thermoelectric Thin Films)

  • 박미영;임재홍;임동찬;이규환
    • 한국재료학회지
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    • 제21권4호
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    • pp.192-195
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    • 2011
  • The electro-deposition of compound semiconductors has been attracting more attention because of its ability to rapidly deposit nanostructured materials and thin films with controlled morphology, dimensions, and crystallinity in a costeffective manner (1). In particular, low band-gap $A_2B_3$-type chalcogenides, such as $Sb_2Te_3$ and $Bi_2Te_3$, have been extensively studied because of their potential applications in thermoelectric power generator and cooler and phase change memory. Thermoelectric $Sb_xTe_y$ films were potentiostatically electrodeposited in aqueous nitric acid electrolyte solutions containing different ratios of $TeO_2$ to $Sb_2O_3$. The stoichiometric $Sb_xTe_y$ films were obtained at an applied voltage of -0.15V vs. SCE using a solution consisting of 2.4 mM $TeO_2$, 0.8 mM $Sb_2O_3$, 33 mM tartaric acid, and 1M $HNO_3$. The stoichiometric $Sb_xTe_y$ films had the rhombohedral structure with a preferred orientation along the [015] direction. The films featured hole concentration and mobility of $5.8{\times}10^{18}/cm^3$ and $54.8\;cm^2/V{\cdot}s$, respectively. More negative applied potential yielded more Sb content in the deposited $Sb_xTe_y$ films. In addition, the hole concentration and mobility decreased with more negative deposition potential and finally showed insulating property, possibly due to more defect formation. The Seebeck coefficient of as-deposited $Sb_2Te_3$ thin film deposited at -0.15V vs. SCE at room temperature was approximately 118 ${\mu}V/K$ at room temperature, which is similar to bulk counterparts.

Measurement of Carbon-14 Activity in Spent Ion-exchange Resin of Wolsong Nuclear Power Plant

  • Kim Kyoung-Doek;Choi Young-Ku;Kang Ki-Du;Yang Ho-Yeon
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2005년도 Proceedings of The 6th korea-china joint workshop on nuclear waste management
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    • pp.165-175
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    • 2005
  • Measurement of spent resin activity was initiated in 2004 in order to develop the C-14 removal technology for safe disposal. As part of this program, spent resins were sampled and measured in the in-station resin storage tank 2 at Wolsong Nuclear Power Plant Unit 1. At the time of sampling, the resins had been in storage tank from 3 to 23 years. Total 72 resin samples were sampled, which were collected from both man-hole (68 samples) and test-hole (4 samples) in the in-station resin storage tank 2. They were separated into liquid, activated carbon, zeolite, and spent resin. The spent resins were oxidized with sample oxidizer and analyzed for C-14. Ten of collected mixed resin samples were separated by density into cation and anion resins using a sugar solution. The C-14 concentration in anion exchange resin was approximately 2 times higher than in the mixed resin. The average concentration of C-14 in the cation/anion mixed exchange resin was $460\;GBq/m^3$ from test-hole and $53.1\;GBq/m^3$ from man-hole. We have found that concentration of C-14 in the spent resin is about from 0.4 to $1,321\;GBq/m^3$. So it could be a problem, when dispose of at a repository, since there is a disposal limit of $222\;GBq/m^3$. This means we should develop the C-14 removal technology.

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Via-hole 구조의 n-접합을 갖는 수직형 발광 다이오드 전극 설계에 관한 연구 (Study on the Electrode Design for an Advanced Structure of Vertical LED)

  • 박준범;박형조;정탁;강성주;하준석;임시종
    • 마이크로전자및패키징학회지
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    • 제22권4호
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    • pp.71-76
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    • 2015
  • 최근 Light Emitting Diode (LED)의 효율을 높이기 위한 연구가 활발히 진행 되고 있다. 특히 소자 측면에서는 수평형 LED, 수직형 LED, via-hole 구조의 수직형 LED 등의 다양한 구조가 제시되었다. 본 논문에서는 시뮬레이션을 통해 via-hole 구조의 수직형 LED의 새로운 전극 디자인을 제시하였다. 기존 Via-hole 구조의 수직형 LED의 n-contact hole 주변에 전류가 밀집되는 문제점을 해결하면서 유효 발광면적을 극대화 시켜 소자 전체에 균일한 전류를 주입할 수 있는 소자 디자인에 대해 평가하였다. 시뮬레이션 결과를 바탕으로 최적의 전극 디자인을 실제 디바이스로 제작하여 기존의 via-hole 구조의 수직형 LED와 비교 분석하였다. 최적화된 디자인이 적용된 via hole type 수직형 LED의 경우 기존 디자인에 비해 350 mA 주입시 약 0.2 V의 Forward Voltage 감소하였지만 광 출력은 비슷하여 최종적으로 4.2%의 WPE (Wall plug efficiency)가 향상됨을 보였다.

광탄성법(光彈性法)에 의한 로터리 경운날의 파괴요인(破壞要因)에 대한 해석(解析) -정하중(靜荷重)에 의한 응력집중(應力集中)- (Analysis of the Breaking Factor of Rotary Blade by Photo elastic Method -A Stress Concentration by Static Load-)

  • 최상인;김진현;김창수;김재열
    • Journal of Biosystems Engineering
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    • 제15권3호
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    • pp.177-185
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    • 1990
  • The break of rotary blade is occured from a stress concentration of the inside of blade by the outside impulsive load. In order to examine its inside stress and stress concentration of rotary blade, a epoxy plate which is suitable to applicate by photoelastic system is used to experiment. These results are summarized as follow. 1. Refer to the existence of bolt hole and a size of its of rotary blade, a stress concentration which cause the break of rotary blade is not exposed. 2. It is expected to be break to section of hold of rotary blade and the break of this is due to that there are concentrated by shearing force, bending moment and bending stress. 3. When the crack which caused from processing are set up to any location, the stress concentration taken to the creak point. 4. Without regard to the location of the reaction points of rotary blade, the bending stress which is greated than the bending moment is occured within about 6 em toward the center line of bolt hole and it was possible to break that section.

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Powder Mixed ECDM (Electro-Chemical Discharge Machining)을 이용한 미세구멍가공의 정밀도 개선 (Improvement of Hole Geometric Accuracy by Powder Mixed Electro-chemical Discharge Machining Process)

  • 한민섭;민병권;이상조
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2004년도 추계학술대회 논문집
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    • pp.42-45
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    • 2004
  • Electrochemical discharge machining (ECDM) has been found to be suitable for the micro-hole machining of nonconductive materials such as ceramics or glass compared with existing conventional and also non-conventional machining methods. However this machining process has some problems such as low geometric accuracy and low machining efficiency due to the random spark generation at the end of the electrode. This paper proposes the methods to improve the geometric accuracy of micro-hole using powder mixed ECDM process. The experimental results show the effects of powder producing improved geometric accuracy of machined hole and decreased concentration of spark energy.

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Electrical Properties of the Molybdenum oxide doped Hole transport layer

  • Yun, Jin-Young;Lee, Chang-Hee;Song, Won-Jun;Sung, Yeun-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.691-693
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    • 2007
  • We report on a highly conductive and stable hole transporting layer comprising of N,N'-di(1- naphthyl)-N,N'-diphenylbenzidine $({\alpha}\;-NPD)$ doped with molybdenum oxide $(MoO_3)$. Compared to the reference device, the device with $MoO_3-doped$ hole transporting material exhibits higher conductivity and thermal stability. The temperature dependence of the current-voltage characteristics are studied for various $(MoO_3)$ doping concentration.

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용액 공정 처리된 구리(I) 티오시아네이트(CuSCN) 필름의 정공 주입 특성 연구 (The Study of Hole Injection Characteristics in Solution-Processed Copper (I) Thiocyanate (CuSCN) Film)

  • 장은정;성백상;권성민;최윤석;이종희;이재현
    • 공업화학
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    • 제35권1호
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    • pp.61-65
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    • 2024
  • 대면적 유기 발광 다이오드, 유기 태양 전지, 박막 트렌지스터의 정공 주입층으로써 CuSCN의 효과가 많이 입증되었다. 따라서 본 연구에서는 용액 공정 조건에 따라 CuSCN의 표면과 광학적, 전기적 분석을 하여 최적화된 필름의 조건을 제시하였다. 다양한 CuSCN 용액의 농도를 제작하여 필름 표면 특성을 확인하였고, 필름의 표면이 소자의 전기적 성능에 영향을 미치는지 확인하였다. CuSCN의 용액의 농도가 낮을 때는 CuSCN의 필름이 형성되지 않고 island 형태로 코팅되었고, 용액의 농도가 증가할수록 CuSCN의 필름이 균일하게 형성하였고 이는 소자의 전도도 향상에 기여하였다. 또한 hole only device를 제작하여 CuSCN의 정공 수송 층으로써의 역할을 입증하였다.

부분 관통 구멍이 있는 인장판의 주응력 분포 차이 해석 (Analysis of Principal Stress Distribution Difference of Tensile Plate with Partial Through-hole)

  • 박상현;김영철;김명수;백태현
    • 예술인문사회 융합 멀티미디어 논문지
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    • 제7권2호
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    • pp.437-444
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    • 2017
  • 기계구조물 부재의 단면에 구멍이나 또는 단면이 급격히 변화할 경우, 불연속 부분 주위에서 응력집중이 일어나며 파손이 발생하는 주요 원인이 된다. 그 이유는 부재에 작용하는 평균 응력보다 응력집중 부분에서 훨씬 큰 응력이 작용하기 때문이다. 본 논문에서는 시편의 부분 관통 구멍 주위에서 응력해석을 수행하여 구멍을 통과하는 선상의 주응력 차 값을 구하였다. 광탄성에서 최대주응력과 최소주응력의 차이는 등색프린지 차수와 재료의 프린지 상수를 곱한 값을 빛이 통과한 거리 즉, 시편의 두께로 나눈 값과 같다. 즉, 주응력의 차이는 광탄성 프린지 차수와 비례관계가 있으므로 유한요소해석에 의한 주응력 차이의 분포를 광탄성 실험결과에 비교할 수 있다. 유한요소 범용 소프트웨어인 ANSYS Workbench를 이용하였으며 유한요소법으로 해석된 값을 광탄성 실험으로부터 측정된 값과 비교한 결과 유사한 결과를 얻었다. 이로서 유한요소해석 결과는 실험결과와의 비교를 통해 타당성이 입증될 수 있었다. 또한 구멍깊이 변화에 따라 나타나는 응력분포를 사용하여 응력집중계수를 구하였다. 구멍깊이가 증가할수록 응력집중계수는 증가함을 나타냈다.

축산폐수 전처리를 위한 암모니아 탈기공정의 운전조건이 암모니아 제거에 미치는 영향 (Effect of Operating Condition of Stripping Process on Ammonia Removal for Pre-treatment of Swine Wastewater)

  • 황규대;조영무
    • 한국물환경학회지
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    • 제20권1호
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    • pp.86-92
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    • 2004
  • Lab-scale experiments have been carried out to investigate ammonia stripping with a modified spray tower for removing ammonia nitrogen from swine wastewater. The operating conditions such as initial pH, temperature, air flow, hole size of distributor determining the diameter of water drops, and influent solids concentration were closely examined focusing on removal efficiency of ammonia. As a result of the experiment, in order to achieve high rate of ammonia removal by the air stripping system, the air flow rate must be supplied at high rate with sufficiently high initial pH, temperature. The optimum operating condition to meet the residual ammonia concentration of 300 mg/L was the initial pH of 11.0 at $35^{\circ}C$ with the air flow rate of 20 L/min. It also showed that the smaller hole size is, the higher removal rate of ammonia is expected. However, when used a small sized distributor (2 mm), the flooding problem at the upper column occurred due to clogging of the hole. With regard to the influent solids concentration, it was showed that the lower concentration of solids, the higher removal rate of ammonia. The removal of particulate materials in influent led to improve the removal efficiency of ammonia, rather than to control the operating condition including initial pH, temperature, and air flow. The empirical correlation between KLa and operating parameters would be driven as, $K_{La}=(0.0003T-0.0047){\cdot}G^{0.3926}{\cdot}L^{-0.5169}{\cdot}C^{-0. 1849}$. The calculated $K_{La}$ from proposed formula can be used effectively to estimate the optimum reaction time and to calculate the volume of modified spray tower system.

보강(補强)된 원형(圓形)구멍을 가진 평판(平板)의 이축하중하(二軸荷重下)에서의 응력분포(應力分布) (The Stress Distribution in a Flat Plate with a Reinforced Circular Hole under Biaxial Loading)

  • 임상전
    • 대한조선학회지
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    • 제8권1호
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    • pp.53-66
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    • 1971
  • The effect of reinforced circular hole in a flat plate under general biaxial loading conditions is considered. The reinforcement is achieved by attaching a circular ring of uniform rectangular cross section along the boundary of the hole. This investigation includes a theoretical solution and an experimental conformation. In the theoretical analysis, Gurney's method is used to obtain a solution for the stress distribution and the solution is expressed in a general form, so that it can be applicable to the case of general biaxial loading and general values of Poisson's ratios. In the experimental work a systematic series of photoelastic models, as shown in Fig.5 and Table 1, were analyzed on polariscope. The experimental results were in good agreement with the theoretical ones, as shown in Fig.8 and 9. The conclusions derived are as follows: 1) The theoretical results, given in Eq. $(1){\sim}(5)$, are sufficient in accuracy for the engineering design purpose. 2) The stress concentration factor decreases as the ratio n increases, but not significant beyond n=3. 3) The stress concentration factor increase as the ratio m increases, but not significant below m=0.7.

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