• Title/Summary/Keyword: Hole Injection

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NiOx-based hole injection layer for organic light-emitting diodes (유기발광소자에 적용 가능한 NiOx 기반의 정공주입층 연구)

  • Kim, Junmo;Gim, Yejin;Lee, Wonho;Lee, Donggu
    • Journal of Sensor Science and Technology
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    • v.30 no.5
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    • pp.309-313
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    • 2021
  • Organic semiconductors have received tremendous attention for their research because of their tunable electrical and optical properties that can be achieved by changing their molecular structure. However, organic materials are inherently unstable in the presence of oxygen and moisture. Therefore, it is necessary to develop moisture and air stable semiconducting materials that can replace conventional organic semiconductors. In this study, we developed a NiOx thin film through a solution process. The electrical characteristics of the NiOx thin film, depending on the thermal annealing temperature and UV-ozone treatment, were determined by applying them to the hole injection layer of an organic light-emitting diode. A high annealing temperature of 500 ℃ and UV-ozone treatment enhanced the conductivity of the NiOx thin films. The optimized NiOx exhibited beneficial hole injection properties comparable those of 1,4,5,8,9,11-hexaazatriphenylene hexacarbonitrile (HAT-CN), a conventional organic hole injection layer. As a result, both devices exhibited similar power efficiencies and the comparable electroluminescent spectra. We believe that NiOx could be a potential solution which can provide robustness to conventional organic semiconductors.

Effect of Injection Conditions on the Spray Behaviors of the Multi-hole GDI Injector (분사 조건이 다공형 GDI 인젝터의 분무 거동에 미치는 영향)

  • Park, Jeong-Hwan;Park, Su-Han;Lee, Chang-Sik;Park, Sung-Wook
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.2
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    • pp.116-122
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    • 2012
  • The purpose of this study is to investigate the overall spray behavior characteristics for various injection conditions in a gasoline direct injection(GDI) injector with multi-hole. The spray characteristics, such as the spray penetration, the spray angle, and the injection quantity, were studied through the change of the injection pressure, the ambient pressure, and the energizing duration in a high-pressure chamber with a constant volume. The n-heptane with 99.5% purity was used as the test fuel. In a constant volume chamber, the injected spray was visualized by the spray visualization system, which consisted of the high-speed camera, the metal-halide lamp, the injector control device, and the image analysis system with the image processing program. It was revealed that the injection quantity was mainly affected by the difference between the injection pressure and the ambient pressure. For low injection pressure conditions, the injection quantity was decreased by the increase of the ambient pressure, while it nearly maintained regardless of the ambient pressure at high injection pressure. According to the increase of the ambient pressure in the constant volume chamber, the spray development became slow, consequently, the spray tip penetration decreased, and the spray area increased. In additions, the circular cone area decreased, and the vortex area increased.

The Study of Luminescence Efficiency by change of OLED's Hole Transport Layer

  • Lee, Jung-Ho
    • International Journal of Precision Engineering and Manufacturing
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    • v.7 no.2
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    • pp.52-55
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    • 2006
  • The OLEDs(Organic Light-Emitting Diodes) structure organizes the bottom layer using glass, ITO(indium thin oxide), hole injection layer, hole transport layer, emitting material layer, electron transport layer, electron injection layer and cathode using metal. OLED has various advantages. OLEDs research has been divided into structural side and emitting material side. The amount of emitting light and luminescence efficiency has been improved by continuing effort for emitting material layer. The emitting light mechanism of OLEDs consists of electrons and holes injected from cathode and anode recombination in emitting material layer. The mobilities of injected electrons and holes are different. The mobility of holes is faster than that of electrons. In order to get high luminescence efficiency by recombine electrons and holes, the balance of their mobility must be set. The more complex thin film structure of OLED becomes, the more understanding about physical phenomenon in each interface is needed. This paper observed what the thickness change of hole transport layer has an affection through the below experiments. Moreover, this paper uses numerical analysis about carrier transport layer thickness change on the basis of these experimental results that agree with simulation results.

Change of Recombination Zone in Emission Layer by Characteristics of a Hole Injection Layer (정공 주입층 특성에 따른 발광층에서의 재결합 영역 변화)

  • 한우미;임은주;이정윤;김명식;이기진
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.8
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    • pp.675-678
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    • 2001
  • We fabricated the organic light emittign diodes (OLEDs) with ITO/Cu-Pc/triphenyl-diamine (TPD)/TPD+tris-(8-hydroxyquinoline) aluminum (Alq$_3$)/Al. The electrical properties of Cu-Pc thin film were studied as a hole injection layer. the energy gap of Cu-Pc thin films is decreased according to the substrate heat treatment temperature increased. It could be controlled the hole mobility by changing the heat treatment condition of Cu-Pc. The emission wavelengths could be controlled by changing hole mobility and recombination zone in emission layer.

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Design Optimization of a Cylindrical Film-Cooling Hole Using Neural Network Techniques (신경회로망기법을 사용한 원통형 막냉각 홀의 최적설계)

  • Lee, Ki-Don;Kim, Kwang-Yong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.12
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    • pp.954-962
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    • 2008
  • This study presents a numerical procedure to optimize the shape of cylindrical cooling hole to enhance film-cooling effectiveness. The RBNN method is used as an optimization technique with Reynolds-averaged Navier-Stokes analysis of fluid flow and heat transfer with shear stress transport turbulent model. The hole length-to-diameter ratio and injection angle are chosen as design variables and film-cooling effectiveness is considered as objective function which is to be maximized. Twelve training points are obtained by Latin Hypercube Sampling for two design variables. In the sensitivity analysis, it is found that the objective function is more sensitive to the injection angle of hole than the hole length-to diameter ratio. Optimum shape gives considerable increase in film-cooling effectiveness.

Effect of Nozzle Hole Number on Atomization Characteristics of DME Fuel Spray using High Pressure Injector (고압 인젝터의 노즐 홀 수가 DME 연료분무의 미립화 특성에 미치는 영향)

  • Lee, Jongtae;Lee, Sanghoon;Chon, Mun Soo
    • Journal of ILASS-Korea
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    • v.19 no.4
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    • pp.216-220
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    • 2014
  • This paper presents effect of nozzle hole number on atomization characteristic of DME fuel spray using three different type of injector having the hole number of 6, 7 and 8. For this study, PDPA(phase Doppler particle analyzer) experiment was performed in terms of $T_{ASOE}$ under various injection pressure. To compare general trend of atomization characteristic, the law data were ensemble averaged based on $T_{eng}$ of 0.2 ms. Results showed that the droplet diameter in terms of SMD(Sauter Mean Diameter) was reduced as increase in injection pressure. Increasing the number of hole lead to reduce in droplet diameter, but no significant reduction in diameter was observed between hole number of 7 and that of 8. In addition, increasing the number of hole resulted in decrease in droplet velocity which is considered as the effect of reduction in spray momentum due to decreasing of fuel quantity per each hole.

Injection Feature and Engine Performance Improvement of the Direct Diesel Fuel Injection System (직접 디젤 연료분사계의 분사 특성과 기관 성능 개선에 관한 연구)

  • Yoon, Cheon-Han;Kim, Kyung-Hoon
    • Journal of ILASS-Korea
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    • v.7 no.1
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    • pp.1-6
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    • 2002
  • This study has focused on using fuel injections as variables for measuring performance and reducing exhaust gas in turbo-charger diesel engine. In experiments, we changed nozzle hole diameter, diameter of an injection pipe, and injection timing as variable. The results show that torque. fuel consumption and smoke are reduced as nozzle hole diameter decreases, while NOx increases. When the diameter of injector is reduced, torque, fuel consumption and smoke are deteriorated, but NOx is decreased. In addition, when the time for injection is advanced. torque, fuel consumption and smoke are improved, but the density of NOx is increased.

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Performance of Three-Layered Organic Light-Emitting Diodes Using the Hole-Transport and Injection Layer of TPD and Teflon-AF, and the Electron-Injection Layer of Li2CO3 and LiF

  • Shin, Jong Yeol;Kim, Tae Wan;Kim, Gwi Yeol;Lee, Su Min;Hong, Jin Woong
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.2
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    • pp.89-92
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    • 2017
  • The performance of three-layered organic light-emitting diodes (OLEDs) was investigated using TPD hole-transport and injection layers, Teflon-AF, and the electron-injection layer of $Li_2CO_3$ and LiF. The OLEDs were manufactured in a structure of TPD/$Alq_3$/LiF, TPD/$Alq_3$/$Li_2CO_3$, and AF/$Alq_3$/LiF using low-molecular organic materials. In three different three-layered OLEDs, it was found that the device with the TPD/$Alq_3$/LiF structure shows higher performance in maximum luminance, and maximum external quantum efficiency compared to those of the device with TPD/$Alq_3$/$Li_2CO_3$ and TPD/$Alq_3$/LiF by 35% and 17%, and 193% and 133%, respectively. It is thought that the combined LiF/Al cathode contributes to a reduced work function and improves an electrical conduction mechanism due to the electron injection rather than the hole transport, which then increases a recombination rate of charge carriers.

The Effect of Injection Angle and Nozzle Diameter on HCCI Combustion (분사각 및 분공 직경이 예혼합 압축착화 엔진 연소에 미치는 영향)

  • Kook, Sang-Hoon;Kong, Jang-Sik;Park, Se-Ik;Bae, Choong-Sik;Kim, Jang-Heon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.2
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    • pp.1-7
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    • 2007
  • The effect of injector geometries including the injection angle and number of nozzle holes on homogeneous charge compression ignition (HCCI) engine combustion has been investigated in an automotive-size single-cylinder diesel engine. The HCCI engine has advantages of simultaneous reduction of PM and NOx emissions by achieving the spatially homogenous distribution of diesel fuel and air mixture, which results in no fuel-rich zones and low combustion temperature. To make homogeneous mixture in a direct-injection diesel engine, the fuel is injected at early timing. The early injection guarantees long ignition delay period resulting in long mixing period to form a homogeneous mixture. The wall-impingement of the diesel spray is a serious problem in this type of application. The impingement occurs due to the low in-cylinder density and temperature as the spray penetrates too deep into the combustion chamber. A hole-type injector (5 holes) with smaller angle ($100^{\circ}$) than the conventional one ($150^{\circ}$) was applied to resolve this problem. The multi-hole injector (14 holes) was also tested to maximize the atomization of diesel fuel. The macroscopic spray structure was visualized in a spray chamber, and the spray penetration was analyzed. Moreover, the effect of injector geometries on the power output and exhaust gases was tested in a single-cylinder diesel engine. Results showed that the small injection angle minimizes the wall-impingement of diesel fuel that results in high power output and low PM emission. The multi-hole injector could not decrease the spray penetration at low in-cylinder pressure and temperature, but still showed the advantages in atomization and premixing.

The Effect of the Intake Flow on the Spray Structure of a High Pressure 11-Hole Fuel Injector in a DISI Engine (직접분사식 가솔린 기관에서 흡입유동이 고압 11공 연료분사기의 분무형상에 미치는 영향)

  • Kim, Seong-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.9
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    • pp.722-727
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    • 2009
  • The effect of the intake flow on the spray structure of a high pressure 11-hole fuel injector were examined in a single cylinder optical direct injection spark ignition (DISI) engine. The effects of injection timing and in-cylinder charge motion were investigated using the 2-dimensional Mie scattering technique. It was confirmed that in the homogeneous charge mode, the in-cylinder swirl charge motion played a major role in the fuel spray distribution during the induction stroke rather than the tumble flow. But, in the stratified charge mode, the effect of the in-cylinder charge was not so large that the injected spray pattern was nearly maintained and the increase of in-cylinder pressure by the upward moving piston reduced the fuel spray penetration.