• Korean Journal of Materials Research
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• 제14권7호
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• pp.511-515
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• 2004

Fe nano powders were synthesized by plasma arc discharge (PAD) process and studied by means of X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM) and X-ray Photoelectron Spectroscopy (XPS). Pure Fe rod($99.9\%$) was used as a source of metallic vapor under argon and hydrogen mixed atmosphere. The synthesized Fe nano powders had nearly spherical shapes and core-shell type structures. The influence of process parameters on the structure and size was investigated. The powder size increased with increasing of the chamber pressure and input current. High hydrogen gas ratio in chamber atmosphere affected the particle size and amount of Fe nanopowder.

• Environmental Engineering Research
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• 제14권3호
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• pp.158-163
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• 2009

It is difficult for a burner to achieve an increase in combustibility and a reduction of NOx emission, simultaneously. The reason is because thermal NOx could be reduced at low temperature, while the combustibility should be decreased. To solve this problem, an externally oscillated staging burner was developed, and experiment was conducted according to effective parameters. The combustibility could be improved through the accelerated transfer of heat, mass and momentum obtained by external oscillation. Also, NO is reduced by the decrease of residence time of burning gas in the local highest-temperature spot, which is decreased by the external oscillation and fuel staging. Experiments on variables were conducted to determine the reference flame, and the flame generating the lowest NO concentration was selected. The conditions of reference flame were oscillation frequency 250 Hz, sound pressure 1 VPP, and air ratio 1.1, and NO and CO concentrations were 1ppm and 20 ppm, respectively.

• Applied Chemistry for Engineering
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• 제8권1호
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• pp.84-91
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• 1997

Diamond film was deposited on Mo substrate at atmospheric pressure using a combustion flame apparatus with the addition of $H_2$. With the substrate temperature, the nucleation density of the substrate was increased. At temperatures above $1000^{\circ}C$, some of diamond was partly converted into graphite and etched by hydrogen atoms. With an increase of the $C_2H_2/O_2$ ratio, the nucleation density was increased. But crystals were cauliflower-shaped and a large number of amorphous carbon were deposited. With the addition of $H_2$, the nucleation density of diamond was increased by the improvement of surface activity. Diamond film of high crystallinity was deposited by etching amorphous carbon. With an increase of deposition time, the thickness of diamond film was increased.

• Journal of Hydrogen and New Energy
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• 제29권2호
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• pp.148-154
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• 2018

This paper presents a comparative analysis of thermodynamic performance of ammonia-water Rankine cycles with and without regeneration and Kalina cycle for recovery of low-temperature heat source. Special attention is paid to the effect of system parameters such as ammonia mass fraction and turbine inlet pressure on the characteristics of the system. Results show that maximum net power can be obtained in the regenerative Rankine cycle for high turbine inlet pressures. However, Kalina cycle shows better net power and thermal efficiency for low turbine inlet pressures, and the optimum ammonia mass fractions of Kalina cycle are lower than Rankine cycles.

• Journal of Hydrogen and New Energy
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• 제29권4호
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• pp.393-400
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• 2018

To confirm the operating range of two oxygen carriers for chemical looping combustion system, the effects of operating variables on solid circulation rate were measured and discussed using a two-interconnected circulating fluidized bed system at ambient temperature and pressure. Moreover, suitable operating ranges to avoid choking of the fast fluidized bed (air reactor) were confirmed for two oxygen carriers. A continuous long-term operation of steady-state solid circulation more than 24 hours was also demonstrated within the operating windows. Finally we could confirm that those two oxygen carriers are suitable for chemical looping combustion system with high solid circulation rate and smooth solid circulation.

• Journal of Hydrogen and New Energy
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• 제26권4호
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• pp.357-362
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• 2015

There is potential method to utilize the liquid carbon dioxide ($LCO_2$) in coal gasification plants. The $LCO_2$ could be used to effectively transport coal particles instead of conventional carrier such as liquid water ($H_2O$) particularly in wet-fed gasifier. However, there is a lack of fundamental study on the atomization behavior of $LCO_2$ coal slurry under high pressure condition. In this study, the flashing spray characteristics of a coal mixture with $LCO_2$ was examined during a throttling process by using a flow visualization system. The spray of coal water slurry which is in the Rayleigh-type break up mode was significantly different. This difference indicates that the coal water slurry did not effectively transport the coal, as compared to $LCO_2$ coal slurry.

• Journal of Hydrogen and New Energy
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• 제28권3호
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• pp.308-314
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• 2017

Jet pump in automotive fuel tank module is used to deliver fuel to fuel pump so that the pump is operated without aeration in suction side. In this study, three dimensional simulation model of jet pump is developed to understand performance variation over design parameters. Performance of jet pump is also investigated experimentally in terms of operating pressures. The experimental data is used to verify the three dimensional simulation model of jet pump. Verification results show that the three dimensional simulation model of jet pump is about 1% error with experiment. The simulations are conducted in terms of throat ratio and primary flow induction angle. As the throat ratio is increased, the flux ratio is trade-off at 3 times of throat diameter. On the other hand, as primary flow induction angle is increased, vapor pressure inside the nozzle is decreased. In summary, the results show that liquid jet pump has to be optimized over design parameters. Additionally, high velocity of induced flow is able to evolve cavitation phenomena inside the jet pump.

• Journal of Hydrogen and New Energy
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• 제13권2호
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• pp.119-126
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• 2002

The methanol partial oxidation using commercial $CuO/ZnO/Al_2O_3$ catalysts in a plug flow reactor was studied in the temperature range of $200{\sim}250^{\circ}C$ at atmospheric pressure, It was achieved the high activities by Cu-based catalysts and the selectivity of $CO_2$/$H_2$ was 100% when $O_2$ was fully convened. The reactivity changes and their hysteresis with increasing/decreasing temperatures were observed due to the chemical state differences between the oxidation and the reduction on the Cu surface, It was suggested as the two-step reaction: the complete oxidation and the following steam reforming for methanol, which was indicated by the distributions of final products vs. the residence time. In addition, the complete oxidation step was shown to be extremely fast and the total reaction rate can be controlled by the steam reforming reaction.

• Korean Journal of Materials Research
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• 제25권1호
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• pp.48-53
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• 2015

$TiH_2$ nanopowder was made by high energy ball milling. The milled $TiH_2$ and CNT powders were then simultaneously synthesized and consolidated using pulsed current activated sintering (PCAS) within one minute under an applied pressure of 80 MPa. The milling did not induce any reaction between the constituent powders. Meanwhile, PCAS of the $TiH_2$-CNT mixture produced a Ti-TiC composite according to the reaction ($0.92TiH_2+0.08CNT{\rightarrow}0.84Ti+0.08TiC+0.92H_2$, $0.84TiH_2+0.16CNT{\rightarrow}0.68Ti+0.16TiC+0.84H_2$). Highly dense nanocrystalline Ti-TiC composites with a relative density of up to 99.7% were obtained. The hardness and fracture toughness of the dense Ti-8 mole% TiC and Ti-16 mole% TiC produced by PCAS were also investigated. The hardness of the Ti-8 mole% TiC and Ti-16 mole% TiC composites was higher than that of Ti. The hardness value of the Ti-16 mole% TiC composite was higher than that of the Ti-8 mole% TiC composite without a decrease in fracture toughness.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• 제32권1호
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• pp.78-85
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• 2000

Due to environmental proessures there is increasing use of hydrogen peroxide as a total or partial substitute for chlorine based bleaching agents within ECF or TCF sequences. However, to aceive satifactory brightness using peroxide alone, stages having a combination of high temperature, pressure, pH or residence time are required. It may also have negative impact on fiber quality . Therefore, it would be of advantage if vertain means could be found to make hydrogen peroxide more effective in bleacing , via shortening treaction time and allevaiating the need for such forcing reaction conditions. This can be achieve by converting the peroxide in-situ to stronger oxidant through the use of 손 bleach activator. In this study to investigate the influence of additives, such as tetraacetylethylenediamine (TAED) and Molybdate (MO) . addition on peroxide bleaching were carried out. Under alkaline conditions the bleching additives. TAED and Mo. can react H2O2 to form peracetic acid and peroxomolybdate respectively and these generated activators can improve deliginification,. The activators make it possible to bleach the pulp efficiently at low temperature in the range 50 to 7$0^{\circ}C$. Also, addition of TAED and Mo is an environmentally friendly way of enhancing the performance of peroxide bleaching can be incorporated into TCF and ECF sequences.