• Title/Summary/Keyword: High-level radioactive wastes

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An Experimental Study on the Sorption Properties of Uranium(VI) onto Bentonite Colloids (벤토나이트 콜로이드에 대한 우라늄(VI) 수착특성에 대한 실험적 연구)

  • Baik Min-Hoon;Cho Won-Jin;Hahn Pil-Soo
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.239-247
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    • 2005
  • In this study, an experimental study on the sorption properties of uranium(VI) onto bentonite colloids generated from a domestic calcium bentonite (called as Gyeongju bentonite). Gyeongju bentonite has been considered as a potential candidate buffer material in the Korean disposal concept for high-level radioactive wastes. The size and concentration of the bentonite colloids used in the sorption experiment were measured by a filtration method. The result showed that the concentration of the synthesized bentonite colloid suspension was 5100ppm and the size of the most of bentonite colloids(over $98\%$) was in the range of 200-450nm in diameter. The amount of uranium lost by the sorption onto bottle walls, by precipitation, and by ultrafiltration or colloid formation was analyzed by carrying out some blank tests. The loss of uranium by the ultrafiltration was significant in the lower ionic strength(i.e., in the case of 0.001M $NaClO_4$) due to the cationic sorption effect onto the ultrafilter by a surface charge reversion. The distribution coefficient (or pseudo-colloid formation constant) for the sorption of uranium(VI) onto bentonite colloids was $10^4^{\sim}10^6$ mL/g depending upon pH and the distribution coefficient was highest in the neutral pH around 6.5.

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Thermohydromechanical Behavior Study on the Joints in the Vicinity of an Underground Disposal Cavern (심부 처분공동 주변 절리에서의 열수리역학적 거동변화)

  • Jhin wung Kim;Dae-seok Bae
    • The Journal of Engineering Geology
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    • v.13 no.2
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    • pp.171-191
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    • 2003
  • The objective of this present study is to understand long term(500 years) thermohydromechanical interaction behavior on joints adjacent to a repository cavern, when high level radioactive wastes are disposed of within discontinuous granitic rock masses, and then, to contribute this understanding to the development of a disposal concept. The model includes a saturated discontinuous granitic rock mass, PWR spent nuclear fuels in a disposal canister surrounded with compacted bentonite inside a deposition hole, and mixed bentonite backfilled in the rest of the space within a repository cavern. It is assumed that two joint sets exist within a model. Joint set 1 includes joints of $56^{\circ}$ dip angle, spaced 20m apart, and joint set 2 is in the perpendicular direction to joint set 1 and includes joints of $34^{\circ}$ dip angle, spaced 20m apart. The two dimensional distinct element code, UDEC is used for the analysis. To understand the joint behavior adjacent to the repository cavern, Barton-Bandis joint model is used. Effect of the decay heat from PWR spent fuels on the repository model has been analyzed, and a steady state flow algorithm is used for the hydraulic analysis.

Potential repository domain for A-KRS at KURT facility site (KURT 부지 조건에서 A-KRS 입지 영역 도출)

  • Kim, Kyung-Su;Park, Kyung-Woo;Kim, Geon-Young;Choi, Heui-Joo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.3
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    • pp.151-159
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    • 2012
  • The potential repository domains for A-KRS (Advanced Korean Reference Disposal System for High Level Wastes) in geological characteristics of KURT (KAERI Underground Research Tunnel) facility site were proposed to develop a repository system design and to perform the safety assessment. The host rock of KURT facility site is one of major Mesozoic plutonic rocks in Korean peninsula, two-mica granite, which was influenced by hydrothermal alteration. The topographical features control the flow lines of surface and groundwater toward south-easterly and all waters discharge to Geum River. Fracture zones distributed in study site are classified into order 2 magnitude and their dominant orientations are N-S and E-W strike. From the geological features and fracture zones, the potential repository domains for A-KRS were determined spatially based on the following conditions: (1) fracture zone must not cross the repository; and (2) the repository must stay away from the fracture zones greater than 50 m. The western region of the fracture zones in the N-S direction with a depth below 200 m from the surface was sufficient for A-KRS repository. Because most of the fracture zones in N-S direction were inclined toward the east, we expected to find a homogeneous rock mass in the western region rather than in the eastern region. The lower left domain of potential domains has more suitable geological and hydrogeological conditions for A-KRS repository.

Analysis of the Disposal Tunnel and Disposal Pit Spacing for the Spent Fuel Repository Layout (사용후핵연료 지하 처분장 배치를 위한 처분공 및 처분터널 간격 분석)

  • Lee, Jong-Youl;Lee, Yang;Choi, Heui-Joo;Choi, Jong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.4
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    • pp.393-400
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    • 2006
  • In design of a deep geological repository for the high level wastes, it is very important that the temperature of the bentonite block should not be over $100^{\circ}C$ to maintain the integrity of the bentonite buffer block from the decay heat. In this study, for the layout of the repository to meet the requirement, the analysis of the disposal tunnel and disposal pit spacing was carried out. To do this, based on the reference repository concept, several cases of cooling times and disposal tunnel and disposal pit spacing were compared. The thermal stabilities of the disposal systems were analyzed in terms of the cooling time and spacing. The results showed that it was more desirable to determine the layout of the repository in terms of disposal pit spacing than the disposal tunnel spacing. The results of these analyses can be used in the deep geological repository design. The detailed analyses with the exact site characteristics data will reduce the uncertainty of the results.

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